Artículo
Gutkowski, K.; Japas, M.L.; Fernández-Prini, R. "Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide" (1997) Journal of Chemical Thermodynamics. 29(10):1077-1086
Estamos trabajando para incorporar este artículo al repositorio
Consulte la política de Acceso Abierto del editor
Abstract:
The solubilities of CHI3(s) in supercritical C2H6 and CO2 have been determined spectrophotometrically close to the solvents' critical points at temperatures of 312.90 K and 327.00 K in C2H6, and 312.73 K and 326.95 K in CO2, over a range of fluid densities. Isothermal solubilities show the sharp change with pressure characteristic of near-critical behaviour. Solubilities are almost twice as large in CO2 than in C2H6 over the whole reduced density range. Enhancement factors E were calculated and compared to those of CHI3(s) in C2H4, CHF3, and SF6. The differences observed in E correlate well with the charge distribution, and hence multi-pole moments, of the solvent molecules. © 1997 Academic Press Limited.
Registro:
| Documento: | Artículo |
| Título: | Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide |
| Autor: | Gutkowski, K.; Japas, M.L.; Fernández-Prini, R. |
| Filiación: | Inst. de Quim. Fis. de Materiales, Universidad de Buenos Aires, Cd. Universitaria Pabellón II, 1428-Capital Federal, Argentina Unidad de Actividad Química, Comn. Nacional de Energia Atomica, Av. Libertador 8250, 1429-Capital Federal, Argentina |
| Palabras clave: | Near-critical fluid; Solubility; Triiodomethane |
| Año: | 1997 |
| Volumen: | 29 |
| Número: | 10 |
| Página de inicio: | 1077 |
| Página de fin: | 1086 |
| DOI: | http://dx.doi.org/10.1006/jcht.1997.0228 |
| Título revista: | Journal of Chemical Thermodynamics |
| Título revista abreviado: | J Chem Thermodyn |
| ISSN: | 00219614 |
| CODEN: | JCTDA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v29_n10_p1077_Gutkowski |
Referencias:
- Carlier, C., Randolph, T.W., (1993) AIChE J., 39, pp. 876-884
- Fernández-Prini, R., Japas, M.L., (1994) Chem. Soc. Rev., 23, pp. 155-163
- Bennet, G.E., Rossky, P.J., Johnston, K.P., (1995) J. Phys. Chem., 99, pp. 16136-16143
- Fernández, D.P., Fernández-Prini, R., (1992) J. Chem. Thermodynamics, 24, pp. 377-386
- Marceca, E., Fernández-Prini, R., (1993) J. Chem. Thermodynamics, 25, pp. 237-247
- Marceca, E., Fernández-Prini, R., (1993) J. Chem. Thermodynamics, 25, pp. 719-728
- Marceca, E., Fernández-Prini, R., (1994) J. Chem. Thermodynamics, 26, pp. 651-661
- Orgel, L.E., Mulliken, R.S., (1957) J. Am. Chem. Soc., 79, pp. 4839-4846
- Danten, Y., Guillot, B., Guissani, Y., (1992) J. Chem. Phys., 96, pp. 3782-3794
- Lemmon, E.W., Jacobsen, R.T., Pensonelle, S.G., Beyerlein, S.W., (1993) Report 93-1, , Center of Applied Thermodynamic Studies, University of Idaho
- Lide, D.R., (1995) Handbook of Chemistry and Physics, pp. 3-208. , CRC Press: Boca Raton. 75th edition
- Morita, A., Kajimoto, O., (1990) J. Phys. Chem., 94, pp. 6420-6425
- Dymond, J.H., Smith, E.B., (1980) The Virial Coefficients of Pure Gases and Mixtures, , Clarendon Press: Oxford
- Hirschfelder, J.O., Curtiss, C.F., Bird, R.B., (1996) Molecular Theory of Gases and Liquids, , J. Wiley and Sons: New York
- Reed, T.M., Gubbins, K.E., (1973) Applied Statistical Mechanics, , McGraw Hill Kagakusho: Tokyo
- Reynolds, L., Gardecki, J.A., Frankland, S.J.V., Horng, M.L., Maroncelli, M., (1996) J. Phys. Chem., 100, pp. 10337-10357
- Breneman, C.M., Wiberg, K.B., (1990) J. Comp. Chem., 11, pp. 361-370
- Estrin, D.A., Paglieri, L., Corongiu, G., (1994) J. Phys. Chem., 98, pp. 5653-5660
- Gray, C.G., Gubbins, K.E., (1984) Theory of Molecular Fluids, 1. , Clarenden Press: Oxford
Citas:
---------- APA ----------
Gutkowski, K., Japas, M.L. & Fernández-Prini, R. (1997) . Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide. Journal of Chemical Thermodynamics, 29(10), 1077-1086.http://dx.doi.org/10.1006/jcht.1997.0228
---------- CHICAGO ----------
Gutkowski, K., Japas, M.L., Fernández-Prini, R. "Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide" . Journal of Chemical Thermodynamics 29, no. 10 (1997) : 1077-1086.http://dx.doi.org/10.1006/jcht.1997.0228
---------- MLA ----------
Gutkowski, K., Japas, M.L., Fernández-Prini, R. "Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide" . Journal of Chemical Thermodynamics, vol. 29, no. 10, 1997, pp. 1077-1086.http://dx.doi.org/10.1006/jcht.1997.0228
---------- VANCOUVER ----------
Gutkowski, K., Japas, M.L., Fernández-Prini, R. Solubility of solids in near-critical fluids V. CHI3 in ethane and in carbon dioxide. J Chem Thermodyn. 1997;29(10):1077-1086.http://dx.doi.org/10.1006/jcht.1997.0228
