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Abstract:

High resolution spectra in polarized light of oriented crystalline films of chloroform at 77°K were obtained. The ratio of intensities of Davydov components for different angles of polarization were also determined. Comparison with the oriented gas model approximation allowed the assignment of components to the proper representations of the D 2h factor group : all bands were assigned to the infrared active factor group symmetry species B 1u, B 2u, and B 3u corresponding to vibrations along a, b, and c crystallographic axes. Comparison with results of measurements in solid solutions in argon made by King allowed the distinction between crystallographic effect and isotopic shifts.

Registro:

Documento: Artículo
Título:Infrared spectra in polarized light of crystalline chloroform
Autor:D'Alessio, E.A.; Dodero, E.; Pomposiello, C.
Filiación:Comision National de Energia Atomica, Avenida del Libertador 8250, Buenos Aires, Argentina
Consejo Nacional de Investigaciones Cientificas y Tecnicas
Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires
Idioma: Inglés
Año:1972
Volumen:57
Número:10
Página de inicio:4136
Página de fin:4142
Título revista:The Journal of Chemical Physics
ISSN:00219606
PDF:https://bibliotecadigital.exactas.uba.ar/download/paper/paper_00219606_v57_n10_p4136_DAlessio.pdf
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v57_n10_p4136_DAlessio

Citas:

---------- APA ----------
D'Alessio, E.A., Dodero, E. & Pomposiello, C. (1972) . Infrared spectra in polarized light of crystalline chloroform. The Journal of Chemical Physics, 57(10), 4136-4142.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v57_n10_p4136_DAlessio [ ]
---------- CHICAGO ----------
D'Alessio, E.A., Dodero, E., Pomposiello, C. "Infrared spectra in polarized light of crystalline chloroform" . The Journal of Chemical Physics 57, no. 10 (1972) : 4136-4142.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v57_n10_p4136_DAlessio [ ]
---------- MLA ----------
D'Alessio, E.A., Dodero, E., Pomposiello, C. "Infrared spectra in polarized light of crystalline chloroform" . The Journal of Chemical Physics, vol. 57, no. 10, 1972, pp. 4136-4142.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v57_n10_p4136_DAlessio [ ]
---------- VANCOUVER ----------
D'Alessio, E.A., Dodero, E., Pomposiello, C. Infrared spectra in polarized light of crystalline chloroform. 1972;57(10):4136-4142.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v57_n10_p4136_DAlessio [ ]