Boyd's model for the calculation of the friction constant due to dielectric relaxation is extended to deal with solutions of finite concentrations. The first-order effect of concentration on the friction constant is calculated using the Debye-Hilckel potential for the moving ion. It is found that the concentration-dependent ionic mobility due to dielectric relaxation contains no terms of order smaller than c 1/2.
| Documento: | Artículo |
| Título: | Effect of dielectric relaxation on the mobility of ions in solutions at finite concentrations |
| Autor: | Fernández-Prini, R. |
| Filiación: | Departamento de Qulmica Inorgánica, Analítica y Química Física, Facultad de Cs. Exactas y Naturales, Buenos Aires, Argentina |
| Año: | 1966 |
| Volumen: | 45 |
| Número: | 2 |
| Página de inicio: | 431 |
| Página de fin: | 433 |
| DOI: | http://dx.doi.org/10.1063/1.1727584 |
| Título revista: | The Journal of Chemical Physics |
| ISSN: | 00219606 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v45_n2_p431_FernandezPrini |
