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Abstract:

The ABX3 spin system is studied as a function of applied magnetic field. A method for the determination of the relative signs of J AX and JBX, together with the relative chemical shifts and coupling constants is described. The results are applied to the cis crotonic acid, the trans crotonic acid, its methyl ester, and N-methylformamide. In the latter case it is shown that the relative chemical shift of the A and B protons can be estimated from the field behavior of the X3 group of lines.

Registro:

Documento: Artículo
Título:Nuclear magnetic resonance spectra of the ABX3 type: Field dependence and relative signs of spin-spin coupling constants
Autor:Kowalewski, V.J.; DeKowalewski, D.G.
Filiación:Institute of Physics, University of Uppsala, Uppsala, Sweden
Facultad de Ciencias Exactas, Universidad de Buenos Aires, Argentina
Año:1960
Volumen:33
Número:6
Página de inicio:1794
Página de fin:1798
DOI: http://dx.doi.org/10.1063/1.1731505
Título revista:The Journal of Chemical Physics
ISSN:00219606
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v33_n6_p1794_Kowalewski

Citas:

---------- APA ----------
Kowalewski, V.J. & DeKowalewski, D.G. (1960) . Nuclear magnetic resonance spectra of the ABX3 type: Field dependence and relative signs of spin-spin coupling constants. The Journal of Chemical Physics, 33(6), 1794-1798.
http://dx.doi.org/10.1063/1.1731505
---------- CHICAGO ----------
Kowalewski, V.J., DeKowalewski, D.G. "Nuclear magnetic resonance spectra of the ABX3 type: Field dependence and relative signs of spin-spin coupling constants" . The Journal of Chemical Physics 33, no. 6 (1960) : 1794-1798.
http://dx.doi.org/10.1063/1.1731505
---------- MLA ----------
Kowalewski, V.J., DeKowalewski, D.G. "Nuclear magnetic resonance spectra of the ABX3 type: Field dependence and relative signs of spin-spin coupling constants" . The Journal of Chemical Physics, vol. 33, no. 6, 1960, pp. 1794-1798.
http://dx.doi.org/10.1063/1.1731505
---------- VANCOUVER ----------
Kowalewski, V.J., DeKowalewski, D.G. Nuclear magnetic resonance spectra of the ABX3 type: Field dependence and relative signs of spin-spin coupling constants. 1960;33(6):1794-1798.
http://dx.doi.org/10.1063/1.1731505