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Abstract:

The observed color of a material is due to interaction between light and matter. This interaction is more easily understood for transparent media than for solid opaque media. The theoretical aspects of the spectroscopy of solids are presented to explain the physical principles involved in such observations. First, a qualitative description of the color-change problem is given to rationalize what happens from a simple physical picture. Second, focus is given on the quantitative dependence of diffuse reflectance on particle size. Finally, color changes in nanoparticles are discussed.

Registro:

Documento: Artículo
Título:Why do marbles become paler on grinding? Reflectance, spectroscopy, color, and particle size
Autor:Lagorio, M.G.
Filiación:INQUIMAE, Depto. de Quimica Inorganica, Analítica y Quimica Fisica, Buenos Aires, Argentina
Palabras clave:Color; Light absorption; Light reflection; Light scattering; Nanostructured materials; Particle size analysis; Refractive index; Solids; Ultraviolet spectroscopy; Absorption index; Color change; Marbles; Nanoparticles; Physical properties
Año:2004
Volumen:81
Número:11
Página de inicio:1607
Página de fin:1611
Título revista:Journal of Chemical Education
Título revista abreviado:J Chem Educ
ISSN:00219584
CODEN:JCEDA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219584_v81_n11_p1607_Lagorio

Referencias:

  • Wendlandt, W.W., Hecht, H.G., (1966) Reflectance Spectroscopy, , Interscience Publishers: New York
  • Lagorio, M.G., (1999) J. Chem. Educ., 76, p. 1551
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  • Baba, K., Kasai, H., Okada, S., Oikawa, H., Nakanishi, H., (2003) Optical Materials, 21, p. 591
  • Kasai, H., Nalwa, H.S., Okada, S., Oikawa, H., Nakanishi, H., (1999) Handbook of Nanostructured Materials and Nanotechnology, 5, p. 433. , Hari Singh Nalwa, Ed.; Academic Press Publisher: New York
  • Nakanishi, H., Katagi, H., (1998) Supermol. Sci., 5, p. 289
  • Gaponenko, S.V., (1998) Optical Properties of Semiconductor Nanocrystals, , Cambridge University Press: Cambridge
  • Kittel, C., (1996) Introduction to Solid State Physics, p. 209. , 7th ed.; Wiley: New York, Chapter 8
  • Kippeny, T., Swafford, L.A., Rosenthal, S.J., (2002) J. Chem. Educ., 79, p. 1094
  • Rao, C.N.R., Kulkarni, G.U., Thomas, P.J., Edwards, P.P., (2002) Chem. Eur. J., 8, p. 29
  • Bawendi, M.G., Steigerwald, M.L., Brus, L.E., (1990) Ann. Rev. Phys. Chem., 41, p. 477
  • Lippens, P.E., Lannoo, M., (1989) Phys. Rev. B, 39, p. 10935
  • Alvarez, M.M., Khoury, J.T., Schaaff, G., Shafigullin, M.N., Vezmar, I., Whetten, R.L., (1997) J. Phys. Chem. B, 101, p. 3706
  • Mie, G., (1908) Ann. Phys., 25, p. 377
  • Van de Hulst, H.C., (1957) Light Scattering By Small Particles, , John Wiley and Sons: New York
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Citas:

---------- APA ----------
(2004) . Why do marbles become paler on grinding? Reflectance, spectroscopy, color, and particle size. Journal of Chemical Education, 81(11), 1607-1611.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219584_v81_n11_p1607_Lagorio [ ]
---------- CHICAGO ----------
Lagorio, M.G. "Why do marbles become paler on grinding? Reflectance, spectroscopy, color, and particle size" . Journal of Chemical Education 81, no. 11 (2004) : 1607-1611.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219584_v81_n11_p1607_Lagorio [ ]
---------- MLA ----------
Lagorio, M.G. "Why do marbles become paler on grinding? Reflectance, spectroscopy, color, and particle size" . Journal of Chemical Education, vol. 81, no. 11, 2004, pp. 1607-1611.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219584_v81_n11_p1607_Lagorio [ ]
---------- VANCOUVER ----------
Lagorio, M.G. Why do marbles become paler on grinding? Reflectance, spectroscopy, color, and particle size. J Chem Educ. 2004;81(11):1607-1611.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219584_v81_n11_p1607_Lagorio [ ]