Artículo
Marzocca, J.; Goyanes, S. "An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR" (2004) Journal of Applied Polymer Science. 91(4):2601-2609
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Abstract:
Vulcanized styrene butadiene rubber (SBR) with different cure systems was prepared and analyzed by using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. Samples with several ratio accelerators to sulfur, Λ, between 0.22 and 3.0 cured at 433 K were studied. The network chain density and the crosslink density of the samples were evaluated. By means of normalized rheometer curves, the kinetics of cure of these samples were evaluated by considering the model of isothermal curing proposed by Kamal and Sourour. In this frame, the parameters of the kinetics model were obtained. A correlation between the order of the kinetic equation, n, and the network chain density of the cure samples was established.
Registro:
| Documento: | Artículo |
| Título: | An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR |
| Autor: | Marzocca, J.; Goyanes, S. |
| Filiación: | Universidad de Buenos Aires, Facultad Ciencias Exactas Naturales, Depto. de Fis., LPMPyMC, Pabellón 1, Buenos Aires (1428), Argentina CONICET, Argentina |
| Palabras clave: | Crosslink density; Cure reaction; SBR vulcanizates; Tube model; Crosslinking; Curing; Density (specific gravity); Elasticity; Mathematical models; Mechanical variables measurement; Reaction kinetics; Rheometers; Strain; Stresses; Sulfur; Vulcanization; Isothermal curing; Network chain density; Styrene butadiene rubber; Uniaxial stress strain behavior; Rubber; spectrophotometry |
| Año: | 2004 |
| Volumen: | 91 |
| Número: | 4 |
| Página de inicio: | 2601 |
| Página de fin: | 2609 |
| DOI: | http://dx.doi.org/10.1002/app.13463 |
| Título revista: | Journal of Applied Polymer Science |
| Título revista abreviado: | J. Appl. Polym. Sci. |
| ISSN: | 00218995 |
| CODEN: | JAPNA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v91_n4_p2601_Marzocca |
Referencias:
- Heinrich, G., Straube, E., Helmis, G., (1988) Adv Polym Sci, 85, p. 33
- Straube, E., Heinrich, G., (1991) Kautsch Gummi Kunstst, 44, p. 734
- Heinrich, G., Vilgis, T.A., (1993) Macromolecules, 26, p. 1109
- Marzocca, A.J., (1995) J Appl Polym Sci, 58, p. 1839
- Marzocca, A.J., Cerveny, S., Raimondo, R.B., (1997) J Appl Polym Sci, 66, p. 1085
- Cerveny, S., Marzocca, A.J., (1999) J Appl Polym Sci, 74, p. 2747
- Doi, M., Edwards, S.F., (1978) J Chem Soc, Faraday Trans 2, 85, p. 57
- Doi, M., Edwards, S.F., (1989) The Theory of Polymer Dynamics, , Oxford Univ. Press: Oxford, UK
- Marzocca, A.J., Cerveny, S., Mendez, J.M., (2000) Polym Int, 49, p. 216
- Kamal, M.R., Sourour, S., (1973) Polym Eng Sci, 13, p. 59
- Kaliske, M., Heinrich, G., (1999) Rubber Chem Technol, 72, p. 602
- Wu, S., (1989) J Polym Sci, Part B: Polym Chem, 27, p. 723
- Richter, D., Farago, B., Fetters, L.J., Huang, J.S., Ewen, B., Lartigue, C., (1990) Phys Rev Lett, 64, p. 1389
- Richter, D., Butera, R., Fetters, L.J., Huang, J.S., Farago, B., Ewen, B., (1992) Macromolecules, 25, p. 6156
- Matzen, P., Straube, E., (1992) Colloid Polym Sci, 270, p. 1
- Akiba, M., Hashim, S., (1997) Prog Polym Sci, 223, p. 475
- Quirk, R.P., (1988) Prog Plast Technol, 4, p. 31
- Heinrich, G., (1992) Prog Colloid Polym Sci, 90, p. 16
- Isayev, A.I., Deng, J.S., (1988) Rubber Chem Technol, 61, p. 340
- Heinrich, G., Straube, E., (1984) Acta Polym, 25, p. 115
- Gronski, W., Hoffmann, V., Simon, G., Wutzler, A., Straube, E., (1991) Rubber Chem Technol, 65, p. 63
Citas:
---------- APA ----------
Marzocca, J. & Goyanes, S. (2004) . An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR. Journal of Applied Polymer Science, 91(4), 2601-2609.http://dx.doi.org/10.1002/app.13463
---------- CHICAGO ----------
Marzocca, J., Goyanes, S. "An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR" . Journal of Applied Polymer Science 91, no. 4 (2004) : 2601-2609.http://dx.doi.org/10.1002/app.13463
---------- MLA ----------
Marzocca, J., Goyanes, S. "An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR" . Journal of Applied Polymer Science, vol. 91, no. 4, 2004, pp. 2601-2609.http://dx.doi.org/10.1002/app.13463
---------- VANCOUVER ----------
Marzocca, J., Goyanes, S. An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR. J. Appl. Polym. Sci. 2004;91(4):2601-2609.http://dx.doi.org/10.1002/app.13463
