Artículo
Marzocca, A.J.; Cerveny, S.; Raimondo, R.B. "Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model" (1997) Journal of Applied Polymer Science. 66(6):1085-1092
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Abstract:
The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, network parameters can be calculated. The crosslink level of the material was changed using different times and temperatures of cure. The change in the molecular parameters of the model with the degree of cure was estimated. The present research is useful for the precise determination of the chemical crosslink density of the NR network. The values were compared with those obtained by means of equilibrium volume swelling measurement. © 1997 John Wiley & Sons, Inc.
Registro:
| Documento: | Artículo |
| Título: | Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model |
| Autor: | Marzocca, A.J.; Cerveny, S.; Raimondo, R.B. |
| Filiación: | Universidad de Buenos Aires, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires (1428), Argentina FATE SAICI, Research Group, Av. Blanco Encalada 3003, Prov. Buenos Aires (1644), Argentina |
| Palabras clave: | Crosslink density; NR vulcanizates; Swelling; Tube model; Conformations; Crosslinking; Curing; Density (specific gravity); Elasticity; Mathematical models; Molecular structure; Strain measurement; Swelling; Vulcanization; Conformation tube model; Rubber |
| Año: | 1997 |
| Volumen: | 66 |
| Número: | 6 |
| Página de inicio: | 1085 |
| Página de fin: | 1092 |
| Título revista: | Journal of Applied Polymer Science |
| Título revista abreviado: | J. Appl. Polym. Sci. |
| ISSN: | 00218995 |
| CODEN: | JAPNA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca |
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Citas:
---------- APA ----------
Marzocca, A.J., Cerveny, S. & Raimondo, R.B. (1997) . Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model. Journal of Applied Polymer Science, 66(6), 1085-1092.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca [ ]
---------- CHICAGO ----------
Marzocca, A.J., Cerveny, S., Raimondo, R.B. "Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model" . Journal of Applied Polymer Science 66, no. 6 (1997) : 1085-1092.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca [ ]
---------- MLA ----------
Marzocca, A.J., Cerveny, S., Raimondo, R.B. "Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model" . Journal of Applied Polymer Science, vol. 66, no. 6, 1997, pp. 1085-1092.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca [ ]
---------- VANCOUVER ----------
Marzocca, A.J., Cerveny, S., Raimondo, R.B. Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model. J. Appl. Polym. Sci. 1997;66(6):1085-1092.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca [ ]
