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Baroni, M.V.; Podio, N.S.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gautier, E.A.; García, P.P.; Hoogewerff, J.; Wunderlin, D.A. "Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses" (2015) Journal of Agricultural and Food Chemistry. 63(18):4638-4645
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Abstract:

The objective of this research was to investigate the development of a reliable fingerprint from elemental and isotopic signatures of Argentinean honey to assess its geographical provenance. Honey, soil, and water from three regions (Córdoba, Buenos Aires, and Entre Rĺos) were collected. The multielemental composition was determined by ICP-MS. δ13C was measured by isotopic ratio mass spectrometry, whereas the 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. The data were analyzed by chemometrics looking for the association between the elements, stable isotopes, and honey samples from the three studied areas. Honey samples were differentiated by classification trees and discriminant analysis using a combination of eight key variables (Rb, K/Rb, B, U, 87Sr/86Sr, Na, La, and Zn) presenting differences among the studied regions. The application of canonical correlation analysis and generalized procrustes analysis showed 91.5% consensus between soil, water, and honey samples, in addition to clear differences between studied areas. To the authors knowledge, this is the first report demonstrating the correspondence between soil, water, and honey samples using different statistical methods, showing that elemental and isotopic honey compositions are related to soil and water characteristics of the site of origin. © 2015 American Chemical Society.

Registro:

Documento: Artículo
Título:Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses
Autor:Baroni, M.V.; Podio, N.S.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gautier, E.A.; García, P.P.; Hoogewerff, J.; Wunderlin, D.A.
Filiación:ICYTAC, Instituto de Ciencia y Tecnologĺa de Alimentos Córdoba, Universidad Nacional de Córdoba, Córdoba, 5000, Argentina
Ministerio de Ciencia y Tecnologĺa Provincia de Córdoba-CEPROCOR, Santa Marĺa de Punilla, Córdoba, Argentina
Facultad de Ciencias Exactas y Naturales-INGEIS, Universidad de Buenos Aires-CONICET, Ciudad Universitaria, Buenos Aires, Argentina
Comisión Nacional de Energía Atómica, Gerencia Quĺmica, Centro Atómico Constituyentes, San Martĺn, Buenos Aires, Argentina
Facultad de Ciencias Veterinarias-IGEVET, Universidad Nacional de la Plata-CONICET, Ciudad Universitaria, La Plata, Argentina
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin, 9054, New Zealand
Palabras clave:authenticity; fingerprint; geographical origin; honey; isotopic composition; trace elements; traceability; Discriminant analysis; Isotopes; Mass spectrometers; Mass spectrometry; Soils; Spectrometry; Trace elements; authenticity; fingerprint; Geographical origins; honey; Isotopic composition; traceability; Food products; carbon; soil; trace element; water; analysis; Argentina; chemistry; discriminant analysis; evaluation study; geography; honey; mass spectrometry; procedures; soil; Argentina; Carbon Isotopes; Discriminant Analysis; Geography; Honey; Mass Spectrometry; Soil; Trace Elements; Water
Año:2015
Volumen:63
Número:18
Página de inicio:4638
Página de fin:4645
DOI: http://dx.doi.org/10.1021/jf5060112
Título revista:Journal of Agricultural and Food Chemistry
Título revista abreviado:J. Agric. Food Chem.
ISSN:00218561
CODEN:JAFCA
CAS:carbon, 7440-44-0; water, 7732-18-5; Carbon Isotopes; Soil; Trace Elements; Water
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218561_v63_n18_p4638_Baroni

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Citas:

---------- APA ----------
Baroni, M.V., Podio, N.S., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., Gautier, E.A.,..., Wunderlin, D.A. (2015) . Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses. Journal of Agricultural and Food Chemistry, 63(18), 4638-4645.
http://dx.doi.org/10.1021/jf5060112
---------- CHICAGO ----------
Baroni, M.V., Podio, N.S., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. "Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses" . Journal of Agricultural and Food Chemistry 63, no. 18 (2015) : 4638-4645.
http://dx.doi.org/10.1021/jf5060112
---------- MLA ----------
Baroni, M.V., Podio, N.S., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. "Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses" . Journal of Agricultural and Food Chemistry, vol. 63, no. 18, 2015, pp. 4638-4645.
http://dx.doi.org/10.1021/jf5060112
---------- VANCOUVER ----------
Baroni, M.V., Podio, N.S., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. Linking soil, water, and honey composition to assess the geographical origin of Argentinean honey by multielemental and isotopic analyses. J. Agric. Food Chem. 2015;63(18):4638-4645.
http://dx.doi.org/10.1021/jf5060112