Artículo

Podio, N.S.; Baroni, M.V.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gautier, E.A.; García, P.P.; Hoogewerff, J.; Wunderlin, D.A. "Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance" (2013) Journal of Agricultural and Food Chemistry. 61(16):3763-3773
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Abstract:

The aim of this study was to investigate if elemental and isotopic signatures of Argentinean wheat can be used to develop a reliable fingerprint to assess its geographical provenance. For this pilot study we used wheat cultivated at three different regions (Buenos Aires, Córdoba, and Entre Ríos), together with matching soil and water. Elemental composition was determined by ICP-MS. δ 13 C and δ 15 N were measured by isotopic ratio mass spectrometry, while 87 Sr/ 86 Sr ratio was determined using thermal ionization mass spectrometry. Wheat samples from three sampling sites were differentiated by the combination of 11 key variables (K/Rb, Ca/Sr, Ba, 87 Sr/ 86 Sr, Co, Mo, Zn, Mn, Eu, δ 13 C, and Na), demonstrating differences among the three studied regions. The application of generalized Procrustes analysis showed 99.2% consensus between cultivation soil, irrigation water, and wheat samples, in addition to clear differences between studied areas. Furthermore, canonical correlation analysis showed significant correlation between the elemental and isotopic profiles of wheat and those corresponding to both soil and water (r 2 = 0.97, p < 0.001 and r 2 = 0.96, p < 0.001, respectively). To our knowledge, this is the first report demonstrating the correspondence between soil, water, and wheat samples using different statistical methods, showing that wheat elemental and isotopic compositions are mainly related to soil and irrigation water characteristics of the site of growth. © 2013 American Chemical Society.

Registro:

Documento: Artículo
Título:Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance
Autor:Podio, N.S.; Baroni, M.V.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gautier, E.A.; García, P.P.; Hoogewerff, J.; Wunderlin, D.A.
Filiación:Facultad de Cs. Químicas-ICYTAC, Universidad Nacional de Córdoba-CONICET, Ciudad Universitaria, 5000 Córdoba, Argentina
Ministerio de Ciencia y Tecnología Provincia de Córdoba-CEPROCOR, Santa María de Punilla, Córdoba, Argentina
Facultad de Ciencias Exactas y Naturales-INGEIS, Universidad de Buenos Aires-CONICET, Ciudad Universitaria, Buenos Aires, Argentina
Comisión Nacional de Energía Atómica, Gerencia Química, Centro Atómico Constituyentes, San Martín, Buenos Aires, Argentina
Facultad de Ciencias Veterinarias-IGEVET, Universidad Nacional de la Plata-CONICET, Ciudad Universitaria, La Plata, Argentina
Department of Chemistry, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand
Palabras clave:food authenticity; geographical origin; isotopes; multielement composition; wheat; Canonical correlation analysis; Food authenticity; Generalized procrustes analysis; Geographical origins; Geographical provenances; Multi-element; Thermal ionization mass spectrometry; wheat; Irrigation; Isotopes; Mass spectrometry; Water supply; Soils; carbon; element; isotope; nitrogen; strontium; water; Argentina; article; chemistry; classification; soil; wheat; Argentina; Carbon Isotopes; Elements; Isotopes; Nitrogen Isotopes; Soil; Strontium Isotopes; Triticum; Water; Triticum aestivum
Año:2013
Volumen:61
Número:16
Página de inicio:3763
Página de fin:3773
DOI: http://dx.doi.org/10.1021/jf305258r
Título revista:Journal of Agricultural and Food Chemistry
Título revista abreviado:J. Agric. Food Chem.
ISSN:00218561
CODEN:JAFCA
CAS:carbon, 7440-44-0; nitrogen, 7727-37-9; strontium, 7440-24-6; water, 7732-18-5; Carbon Isotopes; Elements; Isotopes; Nitrogen Isotopes; Soil; Strontium Isotopes; Water, 059QF0KO0R
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218561_v61_n16_p3763_Podio

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Citas:

---------- APA ----------
Podio, N.S., Baroni, M.V., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., Gautier, E.A.,..., Wunderlin, D.A. (2013) . Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance. Journal of Agricultural and Food Chemistry, 61(16), 3763-3773.
http://dx.doi.org/10.1021/jf305258r
---------- CHICAGO ----------
Podio, N.S., Baroni, M.V., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. "Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance" . Journal of Agricultural and Food Chemistry 61, no. 16 (2013) : 3763-3773.
http://dx.doi.org/10.1021/jf305258r
---------- MLA ----------
Podio, N.S., Baroni, M.V., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. "Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance" . Journal of Agricultural and Food Chemistry, vol. 61, no. 16, 2013, pp. 3763-3773.
http://dx.doi.org/10.1021/jf305258r
---------- VANCOUVER ----------
Podio, N.S., Baroni, M.V., Badini, R.G., Inga, M., Ostera, H.A., Cagnoni, M., et al. Elemental and isotopic fingerprint of argentinean wheat. Matching soil, water, and crop composition to differentiate provenance. J. Agric. Food Chem. 2013;61(16):3763-3773.
http://dx.doi.org/10.1021/jf305258r