Artículo

Di Paola-Naranjo, R.D.; Baroni, M.V.; Podio, N.S.; Rubinstein, H.R.; Fabani, M.P.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gallegos, E.; Gautier, E.; Peral-García, P.; Hoogewerff, J.; Wunderlin, D.A. "Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics" (2011) Journal of Agricultural and Food Chemistry. 59(14):7854-7865
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Abstract:

Our main goal was to investigate if robust chemical fingerprints could be developed for three Argentinean red wines based on organic, inorganic, and isotopic patterns, in relation to the regional soil composition. Soils and wines from three regions (Mendoza, San Juan, and Córdoba) and three varieties (Cabernet Sauvignon, Malbec, and Syrah) were collected. The phenolic profile was determined by HPLC-MS/MS and multielemental composition by ICP-MS; 87Sr/ 86Sr and δ 13C were determined by TIMS and IRMS, respectively. Chemometrics allowed robust differentiation between regions, wine varieties, and the same variety from different regions. Among phenolic compounds, resveratrol concentration was the most useful marker for wine differentiation, whereas Mg, K/Rb, Ca/Sr, and 87Sr/ 86Sr were the main inorganic and isotopic parameters selected. Generalized Procrustes analysis (GPA) using two studied matrices (wine and soil) shows consensus between them and clear differences between studied areas. Finally, we applied a canonical correlation analysis, demonstrating significant correlation (r = 0.99; p < 0.001) between soil and wine composition. To our knowledge this is the first report combining independent variables, constructing a fingerprint including elemental composition, isotopic, and polyphenol patterns to differentiate wines, matching part of this fingerprint with the soil provenance. © 2011 American Chemical Society.

Registro:

Documento: Artículo
Título:Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics
Autor:Di Paola-Naranjo, R.D.; Baroni, M.V.; Podio, N.S.; Rubinstein, H.R.; Fabani, M.P.; Badini, R.G.; Inga, M.; Ostera, H.A.; Cagnoni, M.; Gallegos, E.; Gautier, E.; Peral-García, P.; Hoogewerff, J.; Wunderlin, D.A.
Filiación:Facultad de Ciencias Químicas-CIBICI, SECyT-ISIDSA/ICYTAC, Universidad Nacional de Córdoba-CONICET, 5000 Córdoba, Argentina
Facultad de Ingeniería-IBT, Universidad Nacional de San Juan-CONICET, Av. Libertador 1109 (O), San Juan, Argentina
Ministerio de Ciencia y Tecnología Provincia de Córdoba-CEPROCOR, Santa María de Punilla, Córdoba, Argentina
Facultad de Ciencias Exactas y Naturales, Dto. Ciencias Geológicas-INGEIS, Universidad de Buenos Aires-CONICET, Buenos Aires, Argentina
Comisión de Energía Atómica, Gerencia Química, Centro Atómico Constituyentes, San Martín, Buenos Aires, Argentina
Facultad de Ciencias Veterinarias-IGEVET, Universidad Nacional de la Plata-CONICET, Ciudad Universitaria, La Plata, Argentina
School of Chemistry, University of East Anglia, Norwich NR4 7TJ, United Kingdom
Palabras clave:elements; geographical origin; isotopic ratio; phenolics; varietals; Wine fingerprint; Cabernet-Sauvignon; Canonical correlation analysis; Chemical fingerprint; Chemometrics; Elemental compositions; Generalized procrustes analysis; Geographical origins; HPLC-MS/MS; Independent variables; Isotopic analysis; Isotopic parameters; Isotopic pattern; isotopic ratio; Phenolic compounds; Phenolics; Polyphenols; Red wine; Resveratrol; Soil composition; Terroir; varietals; Wine composition; Chemical analysis; Geographical regions; Phenols; Soils; Wine; Isotopes; inorganic compound; isotope; organic compound; Argentina; chemistry; conference paper; grape; quality control; soil; wine; Argentina; Inorganic Chemicals; Isotopes; Organic Chemicals; Quality Control; Soil; Vitis; Wine
Año:2011
Volumen:59
Número:14
Página de inicio:7854
Página de fin:7865
DOI: http://dx.doi.org/10.1021/jf2007419
Título revista:Journal of Agricultural and Food Chemistry
Título revista abreviado:J. Agric. Food Chem.
ISSN:00218561
CODEN:JAFCA
CAS:Inorganic Chemicals; Isotopes; Organic Chemicals; Soil
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218561_v59_n14_p7854_DiPaolaNaranjo

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Citas:

---------- APA ----------
Di Paola-Naranjo, R.D., Baroni, M.V., Podio, N.S., Rubinstein, H.R., Fabani, M.P., Badini, R.G., Inga, M.,..., Wunderlin, D.A. (2011) . Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics. Journal of Agricultural and Food Chemistry, 59(14), 7854-7865.
http://dx.doi.org/10.1021/jf2007419
---------- CHICAGO ----------
Di Paola-Naranjo, R.D., Baroni, M.V., Podio, N.S., Rubinstein, H.R., Fabani, M.P., Badini, R.G., et al. "Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics" . Journal of Agricultural and Food Chemistry 59, no. 14 (2011) : 7854-7865.
http://dx.doi.org/10.1021/jf2007419
---------- MLA ----------
Di Paola-Naranjo, R.D., Baroni, M.V., Podio, N.S., Rubinstein, H.R., Fabani, M.P., Badini, R.G., et al. "Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics" . Journal of Agricultural and Food Chemistry, vol. 59, no. 14, 2011, pp. 7854-7865.
http://dx.doi.org/10.1021/jf2007419
---------- VANCOUVER ----------
Di Paola-Naranjo, R.D., Baroni, M.V., Podio, N.S., Rubinstein, H.R., Fabani, M.P., Badini, R.G., et al. Fingerprints for main varieties of argentinean wines: Terroir differentiation by inorganic, organic, and stable isotopic analyses coupled to chemometrics. J. Agric. Food Chem. 2011;59(14):7854-7865.
http://dx.doi.org/10.1021/jf2007419