Abstract:
Pentachloronitrosyliridate(III) ([IrCl5(NO)]-), the most electrophilic NO+ known to date, can be reduced chemically and/or electrochemically by one or two electrons to produce the NO • and HNO/NO- forms. The nitroxyl complex can be formed either by hydride attack to the NO+ in organic solvent, or by decomposition of iridium-coordinated nitrosothiols in aqueous solutions, while NO• is produced electrochemically or by reduction of [IrCl 5(NO)]- with H2O2. Both NO • and HNO/NO- complexes are stable under certain conditions but tend to labilize the trans chloride and even the cis ones after long periods of time. As expected, the NO+ is practically linear, although the IrNO moiety is affected by the counterions due to dramatic changes in the solid state arrangement. The other two nitrosyl redox states comprise bent structures. © 2011 Elsevier B.V. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]- |
Autor: | Escola, N.; Bikiel, D.E.; Baggio, R.; Di Salvo, F.; Doctorovich, F. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Pabellón. 2, C1428EHA Buenos Aires, Argentina Comisión Nacional de Energía Atómica, Avenida Gral Paz 1499, 1650 San Martín, Buenos Aires, Argentina
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Palabras clave: | HNO/NO-; Iridium(III) complexes; Nitrosyl; Nitroxyl; NO• |
Año: | 2011
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Volumen: | 374
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Número: | 1
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Página de inicio: | 528
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Página de fin: | 539
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DOI: |
http://dx.doi.org/10.1016/j.ica.2011.02.063 |
Título revista: | Inorganica Chimica Acta
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Título revista abreviado: | Inorg. Chim. Acta
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ISSN: | 00201693
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CODEN: | ICHAA
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v374_n1_p528_Escola |
Referencias:
- McCleverty, J.A., (1979) Chem. Rev., 79, p. 53
- Roncaroli, F., Ruggiero, M.E., Franco, D.W., Estiu, G.L., Olabe, J.A., (2002) Inorg. Chem., 41, p. 5760
- Doctorovich, F., Di Salvo, F., (2007) Acc. Chem. Res., 40, p. 985. , references therein
- Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L., (2005) Organometallics, 24, p. 4707
- Di Salvo, F., Leitus, D.A.G., Doctorovich, F., (2008) Organometallics, 27, p. 1985
- Finneman, J.I., Fishbein, J.C., (1994) J. Org. Chem., 59, p. 6251
- Perissinotti, L.L., Leitus, G., Estrin, D.A., Doctorovich, F., (2006) J. Am. Chem. Soc., 128, p. 2512
- Perissinotti, L.L., Leitus, G., Shimon, L., Estrin, D.A., Doctorovich, F., (2008) Inorg. Chem., 47, p. 4723
- Szacilowski, K., Wanat, A., Barbieri, A., Wasielewska, E., Witko, M., Stochel, G., Stasicka, Z., (2002) New J. Chem., 26, p. 1495
- Grossi, L., Montevecchi, P.C., Strazzari, G., (2001) Eur. J. Org. Chem., p. 131
- Pilato, R.S., McGettigan, C., Geoffroy, G.L., Rheingold, A.L., Geib, S.J., (1990) Organometallics, 9, p. 312
- Mansuy, D., Battioni, P., Chottard, J.-C., Riche, C., Chiaroni, A., (1983) J. Am. Chem. Soc., 105, p. 455
- Weiner, W.P., Bergman, R.G., (1983) J. Am. Chem. Soc., 105, p. 3922
- Weiner, W.P., White, M.A., Bergman, R.G., (1981) J. Am. Chem. Soc., 103, p. 3612
- Chang, J., Seidler, M.D., Bergman, R.G., (1989) J. Am. Chem. Soc., 111, p. 3258
- Mansuy, D., Dreme, M., Chottard, J.C., Guilhem, J., (1978) J. Organomet. Chem., 161, p. 207
- Mansuy, D., Dreme, M., Chottard, J.C., Girault, J.-P., Guilhem, J., (1980) J. Am. Chem. Soc., 102, p. 844
- Sohl, C.D., Lee, J., Alguindigue, S.S., Khan, M.M.A., Richter-Addo, G.B., (2004) J. Inorg. Biochem., 98, p. 1238
- Enemark, J.H., Feltham, R.D., (1974) Coord. Chem. Rev., 13, p. 339. , In the Enemark-Felthan notation a mononitrosyl complex is described as {MNO}n, were n is the total number of electrons in the metal d and NO π* orbitals so, {MNO}6 depicts a complex bearing a d 6 metal like Ir(III) and NO+
- Bottomley, J.F., (1975) Dalton Trans., 23, p. 2538
- Di Salvo, F., Escola, N., Scherlis, D.A., Estrin, D.A., Bondía, C., Murgida, D.H., Ramallo López, J.M., Doctorovich, F., (2007) Eur. J., 13, p. 8428
- Paul, P., (2002) Cryst. Eng., 5, p. 3
- Ye, X., Li, Z., Wang, W., Fan, K., Xu, W., Hua, Z., (2004) Chem. Phys. Lett., 397, p. 56
- Estrin, D.A., Baraldo, L.M., Slep, L.D., Barja, B.C., Olabe, J.A., Paglieri, L., Corongiu, G., (1996) Inorg. Chem., 35, p. 3897. , references therein
- Gutmann, V., (1980) The Donor-Acceptor Approach to Molecular Interactions, , Plenum New York
- Gutmann, V., (1976) Electrochim. Acta, 21, p. 661
- Gutmann, V., (1977) Mon. für Chem., 108, p. 429
- De Witt Horrocks Jr., W., Mann, R.H., (1965) Spectrochim. Acta, 21, p. 399
- Sieger, M., Sarkar, B., Zálfs, S., Fiedler, J., Escola, N., Doctorovich, F., Olabe, J.A., Kaim, W., (2004) Dalton Trans., p. 1797
- Johanek, V., Schauermann, S., Laurin, M., Libuda, J., Freund, H.-J., (2003) Angew. Chem., 115, p. 3147
- Johanek, V., Schauermann, S., Laurin, M., Libuda, J., Freund, H.-J., (2003) Angew. Chem., Int. Ed. Engl., 42, p. 3035
- Farmer, J., Sulc, F., (2005) J. Inorg. Biochem., 99, p. 166
- Wilson, R.D., Ibers, J.A., (1979) Inorg. Chem., 18, p. 336
- Melenkivitz, R., Hillhouse, G.L., (2002) Chem. Commun., p. 660
- Sellmann, D., Gottschalk-Gaudig, T., Hussinger, D., Heinemann, F.W., Hess, B.A., (2001) Chem. Eur. J., 7, p. 2099
- Montenegro, A.C., Amorebieta, V.T., Slep, L.D., Martín, D.F., Roncaroli, F., Murgida, D.H., Bari, S.E., Olabe, J.A., (2009) Angew. Chem., Int. Ed., 48, p. 4213
- Kazhdan, D., Perissinotti, L.L., Watanabe, B., Eberlin, M.N., Milagre, H., Vaz, B.G., Estrin, D.A., Doctorovich, F., (2011) Inorg. Chim. Acta, 366, p. 85
- Wang, P.G., Xian, M., Tang, X., Wu, X., Wen, Z., Cai, T., Janczuk, A.J., (2002) Chem. Rev., 102, p. 1091
- Evans, W.J., Kiesz, M.D., Fang, M., Bates, J.E., Zink, J.I., (2010) Nat. Chem., 2, p. 644
- (2009) CrysAlis Pro 171.33.42, , Oxford Diffraction Ltd
- Farrugia, L.J., (1999) J. Appl. Crystallogr., 32, p. 837
- Coppens, P., Leiserowitz, L., Rabinovich, D., (1965) Acta Crystallogr., 18, p. 1035
- Sheldrick, G.M., (1997) SHELXTL97, , University of Göttingen Göttingen, Germany
- Frisch, M.J., Trucks, G.W., Schlega, H.B., Scuseria, G.E., Robb, M.A., Cheesman, J.R., Zakrzewski, V.G., Pople, J.A., (1988) Gaussian 98 Rev. B, 37, p. 785
- Bikiel, D.E., Ramallo-López, J.M., Requejo, F.G., Oña, O.B., Ferraro, M.B., Facelli, J.C., Doctorovich, F., (2011) Polyhedron, 30, p. 221
- Becke, A.D., (1988) Phys. Rev. A, 38, p. 3098
- Hay, P.J., Wadt, R.R., (1985) J. Chem. Phys., 82, p. 270
- Wadt, W.R., Hay, P.J., (1985) J. Chem. Phys., 82, p. 284
- Hay, P.J., Wadt, W.R., (1985) J. Chem. Phys., 82, p. 299
- Ling, Y., Mills, C., Weber, R., Yang, L., Zhang, Y., (2010) J. Am. Chem. Soc., 132, p. 1583
- Adamo, C., Barone, V., (1998) J. Chem. Phys., 108, p. 664
- Vosko, S.H., Wilk, L., Nusair, M., (1980) Can. J. Phys., 58, p. 1200
- McLean, A.D., Chandler, G.S., (1980) J. Chem. Phys., 72, p. 5639
- Raghavachari, K., Binkley, J.S., Seeger, R., Pople, J.A., (1980) J. Chem. Phys., 72, p. 650
- Clark, T., Chandrasekhar, J., Spitznagel, G.W., Schleyer, V.P.R., (1983) J. Comp. Chem., 4, p. 294
- Frisch, M.J., Pople, J.A., Binkley, J.S., (1984) J. Chem. Phys., 80, p. 3265
- Handy, N.C., Cohen, A.J., (2001) Mol. Phys., 99, p. 403
- Hoe, W.-M., Cohen, A., Handy, N.C., (2001) Chem. Phys. Lett., 341, p. 319
- Perdew, J.P., (1986) Phys. Rev. B, 33, p. 8822
- Reed, A.E., Curtis, L.A., Weinhold, F., (1988) Chem. Rev., 88, p. 899
- Wong, M.W., Wiberg, K.B., Frisch, M.J., (1992) J. Am. Chem. Soc., 114, p. 1645
- Paglieri, L., Corongiu, G., Estrin, D.A., (1995) Int. J. Quantum Chem., 56, p. 615
- Cossi, M., Barone, V., Cammi, R., Tomasi, J., (1996) J. Chem. Phys. Lett., 255, p. 327
Citas:
---------- APA ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F. & Doctorovich, F.
(2011)
. NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-. Inorganica Chimica Acta, 374(1), 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063---------- CHICAGO ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F.
"NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-"
. Inorganica Chimica Acta 374, no. 1
(2011) : 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063---------- MLA ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F.
"NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-"
. Inorganica Chimica Acta, vol. 374, no. 1, 2011, pp. 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063---------- VANCOUVER ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F. NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-. Inorg. Chim. Acta. 2011;374(1):528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063