Artículo

Escola, N.; Bikiel, D.E.; Baggio, R.; Di Salvo, F.; Doctorovich, F. "NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-" (2011) Inorganica Chimica Acta. 374(1):528-539
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Abstract:

Pentachloronitrosyliridate(III) ([IrCl5(NO)]-), the most electrophilic NO+ known to date, can be reduced chemically and/or electrochemically by one or two electrons to produce the NO • and HNO/NO- forms. The nitroxyl complex can be formed either by hydride attack to the NO+ in organic solvent, or by decomposition of iridium-coordinated nitrosothiols in aqueous solutions, while NO• is produced electrochemically or by reduction of [IrCl 5(NO)]- with H2O2. Both NO • and HNO/NO- complexes are stable under certain conditions but tend to labilize the trans chloride and even the cis ones after long periods of time. As expected, the NO+ is practically linear, although the IrNO moiety is affected by the counterions due to dramatic changes in the solid state arrangement. The other two nitrosyl redox states comprise bent structures. © 2011 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-
Autor:Escola, N.; Bikiel, D.E.; Baggio, R.; Di Salvo, F.; Doctorovich, F.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Pabellón. 2, C1428EHA Buenos Aires, Argentina
Comisión Nacional de Energía Atómica, Avenida Gral Paz 1499, 1650 San Martín, Buenos Aires, Argentina
Palabras clave:HNO/NO-; Iridium(III) complexes; Nitrosyl; Nitroxyl; NO•
Año:2011
Volumen:374
Número:1
Página de inicio:528
Página de fin:539
DOI: http://dx.doi.org/10.1016/j.ica.2011.02.063
Título revista:Inorganica Chimica Acta
Título revista abreviado:Inorg. Chim. Acta
ISSN:00201693
CODEN:ICHAA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v374_n1_p528_Escola

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Citas:

---------- APA ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F. & Doctorovich, F. (2011) . NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-. Inorganica Chimica Acta, 374(1), 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063
---------- CHICAGO ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F. "NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-" . Inorganica Chimica Acta 374, no. 1 (2011) : 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063
---------- MLA ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F. "NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-" . Inorganica Chimica Acta, vol. 374, no. 1, 2011, pp. 528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063
---------- VANCOUVER ----------
Escola, N., Bikiel, D.E., Baggio, R., Di Salvo, F., Doctorovich, F. NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-. Inorg. Chim. Acta. 2011;374(1):528-539.
http://dx.doi.org/10.1016/j.ica.2011.02.063