Artículo
Barja, B.; Baggio, R.; Calvo, R.; Garland, M.T.; Perec, M.; Rizzi, A. "Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization" (2006) Inorganica Chimica Acta. 359(12):3921-3926
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Abstract:
Two lanthanide(III) complexes with l-glutamate ligands [{Ln2(l-Glu)2(H2O)8} · 4(ClO4) · 2.5H2O]n (Ln = Gd (1), Eu (2)) have been prepared and characterized by single-crystal X-ray diffraction. The compounds are isomorphous with infinite cationic 2D layers stacked together by secondary bonds. The building blocks are slightly different non-centrosymmetric dinuclear units placed in alternating layers, the resulting structures thus containing four non-equivalent Ln metal sites. The dinuclear units contain a fourfold bridge, two in the η1:η1:μ2 and two in the η2:η1:μ2 modes, from two α- and two γ-carboxylates of four different l-Glu residues, respectively. © 2006 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization |
| Autor: | Barja, B.; Baggio, R.; Calvo, R.; Garland, M.T.; Perec, M.; Rizzi, A. |
| Filiación: | Departamento de Química Inorgánica Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina Departamento de Física, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, 1650 San Martín, Buenos Aires, Argentina Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Av. Blanco Encalada 2008, Casilla 483, Santiago, Chile |
| Palabras clave: | Europium; Gadolinium; l-Glutamic acid; Spectroscopy; X-ray structures |
| Año: | 2006 |
| Volumen: | 359 |
| Número: | 12 |
| Página de inicio: | 3921 |
| Página de fin: | 3926 |
| DOI: | http://dx.doi.org/10.1016/j.ica.2006.04.046 |
| Título revista: | Inorganica Chimica Acta |
| Título revista abreviado: | Inorg. Chim. Acta |
| ISSN: | 00201693 |
| CODEN: | ICHAA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v359_n12_p3921_Barja |
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Citas:
---------- APA ----------
Barja, B., Baggio, R., Calvo, R., Garland, M.T., Perec, M. & Rizzi, A. (2006) . Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization. Inorganica Chimica Acta, 359(12), 3921-3926.http://dx.doi.org/10.1016/j.ica.2006.04.046
---------- CHICAGO ----------
Barja, B., Baggio, R., Calvo, R., Garland, M.T., Perec, M., Rizzi, A. "Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization" . Inorganica Chimica Acta 359, no. 12 (2006) : 3921-3926.http://dx.doi.org/10.1016/j.ica.2006.04.046
---------- MLA ----------
Barja, B., Baggio, R., Calvo, R., Garland, M.T., Perec, M., Rizzi, A. "Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization" . Inorganica Chimica Acta, vol. 359, no. 12, 2006, pp. 3921-3926.http://dx.doi.org/10.1016/j.ica.2006.04.046
---------- VANCOUVER ----------
Barja, B., Baggio, R., Calvo, R., Garland, M.T., Perec, M., Rizzi, A. Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization. Inorg. Chim. Acta. 2006;359(12):3921-3926.http://dx.doi.org/10.1016/j.ica.2006.04.046
