Artículo
Barja, B.; Aramendia, P.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. "Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties" (2003) Inorganica Chimica Acta. 355:183-190
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Abstract:
Homometallic europium(III) and terbium(III) trans-2-butenoate polymers, chemical formulas [{Eu3(MeCH=CHCO2)9(H 2O)4}·H2O·EtOH]n (1) and [{Tb(MeCH=CHCO2)3(H2O)}·MeCH= CHCO2H]n (2) and their dimeric 1,10-phenanthroline derivatives [Ln2(MeCH=CHCO2)6(phen) 2]·2H2O, with Ln=Eu (3) and Tb (4), were prepared and characterized by single-crystal X-ray diffraction. The coordination polymers 1 and 2 adopt different carboxylate-bridged infinite chain structures. While the europium compound 1 shows three independent europium centers linked to each other by three different types and number of carboxylate bridges, the terbium polymer 2 shows one independent metal center bridged by the same type of double carboxylates along the chains. Compounds 3 and 4 are isomorphous dinuclear structures with quadruply bridged carboxylate groups, two in the η1:η1:μ2 and two in the η 2:η1:μ2 modes. The magnetic and photophysical behaviors of the four compounds are reported in the solid state. © 2003 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties |
| Autor: | Barja, B.; Aramendia, P.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. |
| Filiación: | Depto. Quim. Inorg., Analitica Q., Fac. de Ciencias Exactas y Naturales, C1428EHA, Buenos Aires, Argentina Departamento de Fisica, Comision Nacional de Energia Atomica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Fisica, Fac. de Cie. Fisicas y Matematicas, Universidad de Chile, Avda B. Encalada 2008, Casilla 487-3, Santiago, Chile U.M.R. 6511, L.C.S.I.M. CNRS, Université Rennes I, 35042 Rennes, France |
| Palabras clave: | Crystal structures; Europium(III) complexes; Luminescence; Terbium(III) complexes; bridged compound; carboxylic acid derivative; coordination compound; europium; europium 2 butenoate; metal complex; terbium; terbium 2 butenoate; unclassified drug; article; crystal; crystal structure; magnetism; physical chemistry; solid state; synthesis; X ray diffraction |
| Año: | 2003 |
| Volumen: | 355 |
| Página de inicio: | 183 |
| Página de fin: | 190 |
| DOI: | http://dx.doi.org/10.1016/S0020-1693(03)00250-0 |
| Título revista: | Inorganica Chimica Acta |
| Título revista abreviado: | Inorg. Chim. Acta |
| ISSN: | 00201693 |
| CODEN: | ICHAA |
| CAS: | europium, 7440-53-1; terbium, 7440-27-9 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v355_n_p183_Barja |
Referencias:
- Bünzli, J.-C.G., (1989) Lanthanide Probes in Life, Chemical and Earth Sciences, Theory and Practice, p. 219. , J.-C.G. Bünzli, & G.R. Choppin. Amsterdam: Elsevier
- De Silva, A.P., Gunaratne, H.Q.N., Rice, T.E., (1996) Angew. Chem., Int. Ed. Engl., 35, p. 2116
- Mortellaro, A., Nocera, D.G., (1996) J. Am. Chem. Soc., 118, p. 7414
- Ma, L., Evans, O.R., Foxman, B.M., Lin, W., (1999) Inorg. Chem., 38, p. 5837
- Seward, C., Hu, N.-X., Wag, S., (2000) J. Chem. Soc., Dalton Trans., p. 134
- Wu, C.-D., Lu, C.-Z., Yang, W.-B., Lu, S.-F., Zhuang, H.-H., Huang, J.-S., (2002) Eur. J. Inorg. Chem., p. 797
- Reineke, T.M., Eddaoudi, M., Fehr, M., Kelley, D., Yaghi, O.M., (1999) J. Am. Chem. Soc., 121, p. 1651
- Yansheng, Y., Lubin, L., Mak, T.C.W., (1988) Chin. J. Struct. Chem. (Jiegou Huaxue), 7, p. 1
- (1984) Gmelin Handbook of Inorganic Chemistry, Sc, Y, La-Lu, Carboxylates, D5
- Nabar, M.A., Barve, S.D., (1984) J. Appl. Crystallogr., 17, p. 39. , Chem. Abstr. 100, 59895g
- The Diffraction Pattern Was Matched with That of Eu2O 3: The JCPDS International Center for Diffraction Data, , Swarthmore, PA, 1992, Powder Diffraction File No.340072
- Sheldrick, G.M., (1997) SHELXS-97 and SHELXL-97, Software for Crystal Structure Analysis, , Madison, WI: Siemens Analytical X-ray Instruments
- Van Vleck, J.H., (1965) The Theory of Electric and Magnetic Susceptibilities, , London: Oxford University Press
- Herpin, A., (1968) Theorie de Magnetisme, , Paris: Presses Universitaires de France
- Murov, S.L., Carmichael, I., Hug, G., (1993) Handbook of Photochemistry, p. 37. , New York: Marcel Dekker
- Parker, D., Gareth Williams, J.A., (1996) J. Chem. Soc., Dalton Trans., p. 3613
- Parker, D., Dickins, R.S., Puschmann, H., Crossland, C., Howard, J.A.K., (2002) Chem. Rev., 102, p. 1977
- Quici, S., Marzanni, G., Cavazzini, M., Anelli, P.L., Botta, M., Gianolio, E., Accorsi, G., Barigelletti, F., (2002) Inorg. Chem., 41, p. 2777
- Alpha, B., Ballardini, R., Balzani, V., Lehn, J.M., Perathoner, S., Sabbatini, N., (1990) Photochem. Photobiol., 52, p. 299
Citas:
---------- APA ----------
Barja, B., Aramendia, P., Baggio, R., Garland, M.T., Peña, O. & Perec, M. (2003) . Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties. Inorganica Chimica Acta, 355, 183-190.http://dx.doi.org/10.1016/S0020-1693(03)00250-0
---------- CHICAGO ----------
Barja, B., Aramendia, P., Baggio, R., Garland, M.T., Peña, O., Perec, M. "Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties" . Inorganica Chimica Acta 355 (2003) : 183-190.http://dx.doi.org/10.1016/S0020-1693(03)00250-0
---------- MLA ----------
Barja, B., Aramendia, P., Baggio, R., Garland, M.T., Peña, O., Perec, M. "Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties" . Inorganica Chimica Acta, vol. 355, 2003, pp. 183-190.http://dx.doi.org/10.1016/S0020-1693(03)00250-0
---------- VANCOUVER ----------
Barja, B., Aramendia, P., Baggio, R., Garland, M.T., Peña, O., Perec, M. Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties. Inorg. Chim. Acta. 2003;355:183-190.http://dx.doi.org/10.1016/S0020-1693(03)00250-0
