Artículo
Rizzi, A.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. "New homobinuclear carboxylate-bridged gadolinium(III) complexes" (2003) Inorganica Chimica Acta. 353:315-319
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Abstract:
Two novel gadolinium(III) trans-2-butenoate dimeric compounds [Gd 2(O2CCH=CHCH3)6(H2O) 4]·2H2O (1) and [Gd2(O 2CCH=CHCH3)6(phen)2]·2H 2O (2) have been synthesized via hydrothermal routes. Compound 1 consists of two independent dimers in the unit cell, one is doubly bridged (η2:η1:μ2) and the other quadruply bridged (two η1:η1:μ2 and two η2:η1:μ2). Compound 2 is dimeric with a quadruply bridged core (two η1:η1:μ 2 and two η2:η1:μ2). Magnetic measurements for 2 show that there is a weak antiferromagnetic intramolecular Gd⋯Gd interaction. © 2003 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| Autor: | Rizzi, A.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. |
| Filiación: | Departamento de Física, Fac. de Bioquím. y Cie. Biol., Universidad Nacional del Litoral, C.C. 242, 3000 Santa Fe, Argentina Departamento de Física, Comn. Nac. de Ener. Atómica, Avda. del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Física, Fac. de Cie. Fis. y Matemát., Universidad de Chile, Avda. Blanco Encalada 2008, Santiago, Chile U.M.R. 6511, L.C.S.I.M. CNRS, Université de Rennes I, 35042 Rennes, France Depto. Quim. Inorg. Analitica Q., Fac. de Ciencias Exactas y Naturales, Pabellón II, 1428 Buenos Aires, Argentina |
| Palabras clave: | Carboxylate complexes; Gadolinium dimers; Magnetism; Structural chemistry; bridged compound; carboxylic acid derivative; dimer; gadolinium; article; crystal structure; magnetism; molecular interaction; synthesis; trans isomer; X ray crystallography |
| Año: | 2003 |
| Volumen: | 353 |
| Página de inicio: | 315 |
| Página de fin: | 319 |
| DOI: | http://dx.doi.org/10.1016/S0020-1693(03)00255-X |
| Título revista: | Inorganica Chimica Acta |
| Título revista abreviado: | Inorg. Chim. Acta |
| ISSN: | 00201693 |
| CODEN: | ICHAA |
| CAS: | gadolinium, 7440-54-2 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v353_n_p315_Rizzi |
Referencias:
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Citas:
---------- APA ----------
Rizzi, A., Baggio, R., Garland, M.T., Peña, O. & Perec, M. (2003) . New homobinuclear carboxylate-bridged gadolinium(III) complexes. Inorganica Chimica Acta, 353, 315-319.http://dx.doi.org/10.1016/S0020-1693(03)00255-X
---------- CHICAGO ----------
Rizzi, A., Baggio, R., Garland, M.T., Peña, O., Perec, M. "New homobinuclear carboxylate-bridged gadolinium(III) complexes" . Inorganica Chimica Acta 353 (2003) : 315-319.http://dx.doi.org/10.1016/S0020-1693(03)00255-X
---------- MLA ----------
Rizzi, A., Baggio, R., Garland, M.T., Peña, O., Perec, M. "New homobinuclear carboxylate-bridged gadolinium(III) complexes" . Inorganica Chimica Acta, vol. 353, 2003, pp. 315-319.http://dx.doi.org/10.1016/S0020-1693(03)00255-X
---------- VANCOUVER ----------
Rizzi, A., Baggio, R., Garland, M.T., Peña, O., Perec, M. New homobinuclear carboxylate-bridged gadolinium(III) complexes. Inorg. Chim. Acta. 2003;353:315-319.http://dx.doi.org/10.1016/S0020-1693(03)00255-X
