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Abstract:

The crystal and molecular structures of sodium pentacyanoammineferrate(II) heptahydrate have been determined by X-ray diffraction. The Fe-N distance is longer than in the analogous iron(III) complex by 0.06 Å; the Fe-C and C-N distances are similar to those for the hexacyanoferrate(II) species, although with a significant relative shortening of the trans Fe-C bonds. The anions display a chain-like arrangement, with interlinking sodium ions and water molecules H-bonded to cyanide N atoms. By comparing with related structures of pentacyano-L-ferrate(II) ions (L = NO+, CN-), it results that the binding mode of the L ligand influences strongly both the first- and second-sphere metal-ligand interactions. © 2001 Elsevier Science B.V.

Registro:

Documento: Artículo
Título:The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions
Autor:Parise, A.R.; Piro, O.E.; Castellano, E.E.; Olabe, J.A.
Filiación:Departamento de Química Inorgánica, Analitica y Quim. Fis., INQUIMAE , Fac. de Cie. Exact. y Nat., Univ. de Buenos Aires, Pabellon 2, 1428 Buenos Aires, Argentina
Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de la Plata and IFLP (CONICET), C.C. 67, 1900 La Plata, Argentina
Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, 13560 São Carlos (SP), Brazil
Corresponding Authors. Tel.:+54-11-45763358, Argentina
Palabras clave:Amine complexes; Crystal structures; Cyanoferrate complexes; Iron complexes; anion; cyanide; ferrocyanide; hydrogen; ligand; metal ion; sodium derivative; sodium ion; sodium pentacyanoammineferrate; unclassified drug; water; analytic method; article; atom; chemical analysis; chemical structure; crystal structure; crystallization; hydrogen bond; molecular interaction; molecule; species; structure activity relation; synthesis
Año:2001
Volumen:319
Número:1-2
Página de inicio:199
Página de fin:202
DOI: http://dx.doi.org/10.1016/S0020-1693(01)00435-2
Título revista:Inorganica Chimica Acta
Título revista abreviado:Inorg. Chim. Acta
ISSN:00201693
CODEN:ICHAA
CAS:cyanide, 57-12-5; ferrocyanide, 13408-63-4, 13601-19-9; hydrogen, 12385-13-6, 1333-74-0; sodium ion, 17341-25-2; water, 7732-18-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v319_n1-2_p199_Parise

Referencias:

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Citas:

---------- APA ----------
Parise, A.R., Piro, O.E., Castellano, E.E. & Olabe, J.A. (2001) . The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions. Inorganica Chimica Acta, 319(1-2), 199-202.
http://dx.doi.org/10.1016/S0020-1693(01)00435-2
---------- CHICAGO ----------
Parise, A.R., Piro, O.E., Castellano, E.E., Olabe, J.A. "The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions" . Inorganica Chimica Acta 319, no. 1-2 (2001) : 199-202.
http://dx.doi.org/10.1016/S0020-1693(01)00435-2
---------- MLA ----------
Parise, A.R., Piro, O.E., Castellano, E.E., Olabe, J.A. "The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions" . Inorganica Chimica Acta, vol. 319, no. 1-2, 2001, pp. 199-202.
http://dx.doi.org/10.1016/S0020-1693(01)00435-2
---------- VANCOUVER ----------
Parise, A.R., Piro, O.E., Castellano, E.E., Olabe, J.A. The crystal and molecular structure of sodium pentacyanoammineferrate(II) heptahydrate. Role of intermolecular hydrogen-bond interactions. Inorg. Chim. Acta. 2001;319(1-2):199-202.
http://dx.doi.org/10.1016/S0020-1693(01)00435-2