Abstract:
The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A.
Registro:
Documento: |
Artículo
|
Título: | A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline) |
Autor: | Baggio, R.; Garland, M.T.; Manzur, J.; Peña, O.; Perec, M.; Spodine, E.; Vega, A. |
Filiación: | Departamento de Fisica, Comn. Nac. Ener. Atomica, Avda L., Buenos Aires, Argentina Fac. de Cie. Fisicas Y Matematicas, Univ. Chile, Avda Blanco E., Santiago, Chile UMR 6511, LCSIM CNRS, Univ. Rennes I, 35042, Rennes, France Depto. Quim. Inorg. Analitica Y Q., INQUIMAE, Univ. Buenos Aires, Cd. U., Buenos Aires, Argentina Fac. Cie. Quimicas Y Farmaceuticas, Universidad de Chile, Casilla 233, Santiago, Chile
|
Palabras clave: | Carboxylate complexes; Copper complexes; Crystal structures; Dinuclear complexes; Thioether complexes |
Año: | 1999
|
Volumen: | 286
|
Número: | 1
|
Página de inicio: | 74
|
Página de fin: | 79
|
DOI: |
http://dx.doi.org/10.1016/S0020-1693(98)00374-0 |
Título revista: | Inorganica Chimica Acta
|
Título revista abreviado: | Inorg. Chim. Acta
|
ISSN: | 00201693
|
CODEN: | ICHAA
|
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v286_n1_p74_Baggio |
Referencias:
- Bleaney, B., Bowers, K.D., (1952) Proc. R. Soc. Lond. a, 214, p. 451
- Melnik, M., (1982) Coord. Chem. Rev., 42, p. 259
- Kato, M., Muto, Y., (1988) Coord. Chem. Rev., 92, p. 45
- Tokü, T., Watanabe, N., Nakashima, M., Muto, Y., Murooka, M., Ohba, S., Saito, Y., (1990) Bull. Chem. Soc. Jpn., 63, p. 364
- Perlepes, S.P., Huffmann, J.C., Christon, G., (1992) Polyhedron, 11, p. 1471
- Meenakuri, S., Chakravarty, A.R., (1993) Polyhedron, 12, p. 347
- Dubler, E., Häring, V.K., Scheller, K.H., Baltzer, P., Sigel, H., (1984) Inorg. Chem., 23, p. 3785
- Corvan, P.J., Estes, W.E., Weller, R.R., Hatfield, W.E., (1980) Inorg. Chem., 19, p. 1297
- Carling, R.L., Kopinga, K., Kahn, O., Verdaguer, M., (1986) Inorg. Chem., 25, p. 786
- Towle, D.K., Hoffman, S.K., Hatfield, W.E., Singh, P., Chaudhuri, P., (1988) Inorg. Chem., 27, p. 394
- Levstin, P.R., Calvo, R., (1990) Inorg. Chem., 29, p. 1581
- Colacio, E., Costes, J.P., Kivekas, R., Laurent, J.P., Ruiz, J., (1990) Inorg. Chem., 29, p. 4240
- Costes, J.P., Dahan, F., Laurent, J.P., (1985) Inorg. Chem., 24, p. 1018
- Chiari, B., Helms, J.H., Piovesana, O., Tarantelli, T., Zanazzi, P.F., (1986) Inorg. Chem., 25, p. 2408
- Greenway, A.M., O'Connor, C.J., Overman, J.W., Sinn, E., (1981) Inorg. Chem., 20, p. 1508
- Christon, G., Perlepes, S.P., Libby, E., Folting, K., Huffman, J.C., Webb, R.J., Hendrickson, D., (1990) Inorg. Chem., 29, p. 3657
- Solomon, E.I., (1981) Copper Proteins, , T.G. Spiro. New York: Wiley
- Lippard, S.J., Berg, J.M., (1994) Principles of Bioinorganic Chemistry, , Mill Valley, CA: University Science Books
- Reedijk, J., Driessen, W.L., Van Rijn, J., (1986) Biological and Inorganic Copper Chemistry, 2, p. 143. , K.D. Karlin, Zubieta J. Guilderland, NY: Adenine Press
- Freeman, H.C., (1983) Copper Coordination Chemistry: Biochemical and Inorganic Perspectives, , K.D. Karlin, & J.A. Zubieta. Guilderland, NY: Adenine Press
- Bonomo, R.P., Rizzarelli, E., Bresciani Pahor, N., Nardin, G., (1982) J. Chem. Soc., Dalton Trans., p. 681
- Sheldrick, G.M., (1997) SHELXL97, Program for Structure Refinement, , University of Göttingen, Germany
- Nardelli, M., (1983) Comput. Chem., 7, p. 95
- Sheldrick, G.M., (1991) SHELXTL-PC. Version 4.2, , Siemens Analytical X-ray Instruments Inc., Madison, WI
- Allen, F.H., Kennard, O., Taylor, R., (1983) Acc. Chem. Res., 16, p. 146
- Cotton, F.A., Wilkinson, G., (1988) Advances Inorganic Chemistry 5th Edition, , New York: Wiley
- Baggio, R., Perec, M., Garland, M.T., (1996) Acta Crystallogr., Sect. C, 52, p. 2457
- Bonomo, R.P., Rizzarelli, E., Bresciani Pahor, N., Nardin, G., (1981) Inorg. Chim. Acta, 54, p. 17
- Bresciani Pahor, N., Nardin, G., Bonomo, R.P., Rizzarelli, E., (1983) J. Chem. Soc., Dalton Trans., p. 1797
- Braithwaite, A.C., Richard, C.E.F., Waters, T.N., (1975) J. Chem. Soc., Dalton Trans., p. 1975
- Prochaska, M.J., Schwundinger, W.F., Schwartz, M., Burk, M.J., Bernarducci, E., Lalancette, R.A., Potenza, J.A., Schugar, H.J., (1981) J. Am. Chem. Soc., 103, p. 3446
- Huheey, J.E., (1978) Principles of Structure and Reactivity, , New York: Harper & Row
- Paul, S., (1967) Acta Crystallogr., 23, p. 490
Citas:
---------- APA ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E. & Vega, A.
(1999)
. A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). Inorganica Chimica Acta, 286(1), 74-79.
http://dx.doi.org/10.1016/S0020-1693(98)00374-0---------- CHICAGO ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al.
"A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)"
. Inorganica Chimica Acta 286, no. 1
(1999) : 74-79.
http://dx.doi.org/10.1016/S0020-1693(98)00374-0---------- MLA ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al.
"A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)"
. Inorganica Chimica Acta, vol. 286, no. 1, 1999, pp. 74-79.
http://dx.doi.org/10.1016/S0020-1693(98)00374-0---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al. A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). Inorg. Chim. Acta. 1999;286(1):74-79.
http://dx.doi.org/10.1016/S0020-1693(98)00374-0