Artículo
Baggio, R.; Garland, M.T.; Manzur, J.; Peña, O.; Perec, M.; Spodine, E.; Vega, A. "A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)" (1999) Inorganica Chimica Acta. 286(1):74-79
Consulte la política de Acceso Abierto del editor
Abstract:
The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A.
Registro:
| Documento: | Artículo |
| Título: | A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline) |
| Autor: | Baggio, R.; Garland, M.T.; Manzur, J.; Peña, O.; Perec, M.; Spodine, E.; Vega, A. |
| Filiación: | Departamento de Fisica, Comn. Nac. Ener. Atomica, Avda L., Buenos Aires, Argentina Fac. de Cie. Fisicas Y Matematicas, Univ. Chile, Avda Blanco E., Santiago, Chile UMR 6511, LCSIM CNRS, Univ. Rennes I, 35042, Rennes, France Depto. Quim. Inorg. Analitica Y Q., INQUIMAE, Univ. Buenos Aires, Cd. U., Buenos Aires, Argentina Fac. Cie. Quimicas Y Farmaceuticas, Universidad de Chile, Casilla 233, Santiago, Chile |
| Palabras clave: | Carboxylate complexes; Copper complexes; Crystal structures; Dinuclear complexes; Thioether complexes |
| Año: | 1999 |
| Volumen: | 286 |
| Número: | 1 |
| Página de inicio: | 74 |
| Página de fin: | 79 |
| DOI: | http://dx.doi.org/10.1016/S0020-1693(98)00374-0 |
| Título revista: | Inorganica Chimica Acta |
| Título revista abreviado: | Inorg. Chim. Acta |
| ISSN: | 00201693 |
| CODEN: | ICHAA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v286_n1_p74_Baggio |
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Citas:
---------- APA ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E. & Vega, A. (1999) . A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). Inorganica Chimica Acta, 286(1), 74-79.http://dx.doi.org/10.1016/S0020-1693(98)00374-0
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al. "A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)" . Inorganica Chimica Acta 286, no. 1 (1999) : 74-79.http://dx.doi.org/10.1016/S0020-1693(98)00374-0
---------- MLA ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al. "A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)" . Inorganica Chimica Acta, vol. 286, no. 1, 1999, pp. 74-79.http://dx.doi.org/10.1016/S0020-1693(98)00374-0
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., et al. A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline). Inorg. Chim. Acta. 1999;286(1):74-79.http://dx.doi.org/10.1016/S0020-1693(98)00374-0
