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Abstract:

The two new compounds [Zn(Him)2(oda)]n (1) and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (2) (Him=imidazol, oda=oxydiacetate) have been prepared and their structures determined by single-crystal X-ray diffraction studies. Compound 1 consists of polymeric chains formed by ZnN2O2 tetrahedral units bridged by the carboxylate groups of extended oda ligands; 2 is tetranuclear with the cadmium atoms in pentagonal bipyramidal CdN2O5 coordination geometry. The extended structures and the hydrogen-bonding patterns displayed by both the compounds were examined.

Registro:

Documento: Artículo
Título:Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)
Autor:Baggio, R.; Garland, M.T.; Perec, M.; Vega, D.
Filiación:Departamento de Física, Comn. Nac. Ener. Atomica, Avda L., 1429 Buenos Aires, Argentina
Departamento de Física, Fac. Cie. Fis. Y Matemat., Univ. C., Santiago, Chile
Depto. de Quim. Inorgánica, Analitica Y Quim. Fis., INQUIMAE, U., 1428 Buenos Aires, Argentina
Palabras clave:Cadmium complexes; Crystal structures; Oxydiacetate complexes; Zinc complexes
Año:1999
Volumen:284
Número:1
Página de inicio:49
Página de fin:54
DOI: http://dx.doi.org/10.1016/S0020-1693(98)00274-6
Título revista:Inorganica Chimica Acta
Título revista abreviado:Inorg. Chim. Acta
ISSN:00201693
CODEN:ICHAA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v284_n1_p49_Baggio

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Citas:

---------- APA ----------
Baggio, R., Garland, M.T., Perec, M. & Vega, D. (1999) . Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate). Inorganica Chimica Acta, 284(1), 49-54.
http://dx.doi.org/10.1016/S0020-1693(98)00274-6
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M., Vega, D. "Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)" . Inorganica Chimica Acta 284, no. 1 (1999) : 49-54.
http://dx.doi.org/10.1016/S0020-1693(98)00274-6
---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M., Vega, D. "Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate)" . Inorganica Chimica Acta, vol. 284, no. 1, 1999, pp. 49-54.
http://dx.doi.org/10.1016/S0020-1693(98)00274-6
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M., Vega, D. Adduct formation between zinc and cadmium oxydiacetates and imidazol. Crystal structures of [Zn(Him)2(oda)]n and [Cd2(Him)4(oda)2(H2O)] 2·6H2O (Him=imidazol, oda=oxydiacetate). Inorg. Chim. Acta. 1999;284(1):49-54.
http://dx.doi.org/10.1016/S0020-1693(98)00274-6