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Abstract:

Four new lanthanide oxydiacetates [{Y(Hoda)3} · H2oda · H2O] (1), [{Y2(oda)3 (H2O)4 · 2H2O}n] (2), [{LaGd(oda)3(H2O)3 · 6H2O}n] (3) and [{LaY (oda)3(H2O)3 · 6H2O}n] (4) (oda = -O2CCH2OCH2CO2 -) have been synthesized and their structures determined by single-crystal X-ray methods. Compound 1 is monometallic with distorted YO9 units formed via coordination of three tridentate Hoda ligands. Compound 2 consists of polymeric sheets of YO9 units formed via coordination of three tridentate oda ligands bridged through carboxylate groups to YO8 units. Compounds 3 and 4 are isomorphous heterobimetallic three-dimensional networks of LnO9 units (Ln = Gd or Y) formed via coordination of three tridentate oda ligands bridged to the larger radius La(III) in LaO9 units through carboxylate groups. © 1998 Elsevier Science S.A. All rights reserved.

Registro:

Documento: Artículo
Título:Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes
Autor:Baggio, R.; Garland, M.T.; Perec, M.
Filiación:Departamento de Física, Comn. Nac. de Ener. Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina
Departamento de Física, Fac. de Cie. Fis. y Matemat., Universidad de Chile, Ave. B. Encalada 2008, Casilla 487-3, Santiago, Chile
Depto. Quim. Inorg., Analitica Quim., Universidad de Buenos Aires, Pabellón II, 1428 Buenos Aires, Argentina
Palabras clave:Carboxylate complexes; Crystal structures; Heterobimetallic complexes; Lanthanide complexes
Año:1998
Volumen:281
Número:1
Página de inicio:18
Página de fin:24
DOI: http://dx.doi.org/10.1016/S0020-1693(98)00131-5
Título revista:Inorganica Chimica Acta
Título revista abreviado:Inorg. Chim. Acta
ISSN:00201693
CODEN:ICHAA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v281_n1_p18_Baggio

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Citas:

---------- APA ----------
Baggio, R., Garland, M.T. & Perec, M. (1998) . Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes. Inorganica Chimica Acta, 281(1), 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M. "Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes" . Inorganica Chimica Acta 281, no. 1 (1998) : 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5
---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M. "Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes" . Inorganica Chimica Acta, vol. 281, no. 1, 1998, pp. 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M. Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes. Inorg. Chim. Acta. 1998;281(1):18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5