Abstract:
Four new lanthanide oxydiacetates [{Y(Hoda)3} · H2oda · H2O] (1), [{Y2(oda)3 (H2O)4 · 2H2O}n] (2), [{LaGd(oda)3(H2O)3 · 6H2O}n] (3) and [{LaY (oda)3(H2O)3 · 6H2O}n] (4) (oda = -O2CCH2OCH2CO2 -) have been synthesized and their structures determined by single-crystal X-ray methods. Compound 1 is monometallic with distorted YO9 units formed via coordination of three tridentate Hoda ligands. Compound 2 consists of polymeric sheets of YO9 units formed via coordination of three tridentate oda ligands bridged through carboxylate groups to YO8 units. Compounds 3 and 4 are isomorphous heterobimetallic three-dimensional networks of LnO9 units (Ln = Gd or Y) formed via coordination of three tridentate oda ligands bridged to the larger radius La(III) in LaO9 units through carboxylate groups. © 1998 Elsevier Science S.A. All rights reserved.
Registro:
Documento: |
Artículo
|
Título: | Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes |
Autor: | Baggio, R.; Garland, M.T.; Perec, M. |
Filiación: | Departamento de Física, Comn. Nac. de Ener. Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Física, Fac. de Cie. Fis. y Matemat., Universidad de Chile, Ave. B. Encalada 2008, Casilla 487-3, Santiago, Chile Depto. Quim. Inorg., Analitica Quim., Universidad de Buenos Aires, Pabellón II, 1428 Buenos Aires, Argentina
|
Palabras clave: | Carboxylate complexes; Crystal structures; Heterobimetallic complexes; Lanthanide complexes |
Año: | 1998
|
Volumen: | 281
|
Número: | 1
|
Página de inicio: | 18
|
Página de fin: | 24
|
DOI: |
http://dx.doi.org/10.1016/S0020-1693(98)00131-5 |
Título revista: | Inorganica Chimica Acta
|
Título revista abreviado: | Inorg. Chim. Acta
|
ISSN: | 00201693
|
CODEN: | ICHAA
|
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v281_n1_p18_Baggio |
Referencias:
- Segal, D., (1989) Chemical Synthesis of Advanced Ceramic Material, , Cambridge University Press, UK
- Chanaud, P., Julbe, A., Vaija, P., Persin, M., Cot, L., (1994) J. Mater. Sci., 29, p. 4224
- Wang, S., Pang, Z., Smith, K.D.L., Wagner, M.J., (1994) J. Chem. Soc., Dalton Trans., p. 955
- Chu, C.T., Dunn, B., (1987) J. Am. Ceram. Soc., 70, pp. C-375
- Wang, N.H., Wang, C.M., Kao, H.C.I., Ling, D.C., Ku, H.C., Lu, K.H., (1989) Jpn. J. Appl. Phys., 28, pp. L1505
- Courty, P., Ajot, H., Marcilly, C., Delmon, B., (1973) Powder Technol., 7, p. 21
- Parker, D., Williams, J.A.G., (1996) J. Chem. Soc., Dalton Trans., p. 3613
- Albertsson, J., Elding, I., (1976) Acta Crystallogr., Sect. B, 32, p. 3066
- Elding, I., (1976) Acta Chem. Scand., Ser. A, 30, p. 649
- Albertsson, J., Elding, I., (1977) Acta Chem. Scand., Ser. A, 31, p. 21
- Albertsson, J., (1970) Acta Chem. Scand., 24, p. 3527
- Fronczek, R., Banerjee, A.K., Watkins, S.F., Schwartz, R.W., (1981) Inorg. Chem., 20, p. 2745
- Albin, M., Whittle, R.R., Horrocks W.R., Jr., (1985) Inorg. Chem., 24, p. 4591
- Albertsson, J., (1968) Acta Chem. Scand., 22, p. 1563
- Elding, I., (1977) Acta Chem. Scand., Ser. A, 31, p. 75
- Baggio, R., Garland, M.T., Perec, M., (1996) Inorg. Chem., 35, p. 2396
- Baggio, R., Garland, M.T., Perec, M., (1997) Inorg. Chem., 36, p. 950
- Chen, X.-M., Tong, M.-L., Wu, Y.-L., Luo, Y.-J., (1966) J. Chem. Soc., Dalton Trans., p. 2181
- Zhou, D., Huang, C., Wang, K., Xu, G., (1994) Polyhedron, 13, p. 987
- Sheldrick, G.M., (1993) SHELXL93, Program for the Refinement of Crystal Structures, , University of Göttingen, Germany
- Sheldrick, G.M., (1991) SHELXTL-PC, Version 4.2, Siemens Analytical X-ray Instruments, , Madison, WI
- Nardelli, M., (1983) Comput. Chem., 7, p. 95
- Allen, F.H., Kennard, O., Taylor, R., (1983) Acc. Chem. Res., 16, p. 146
- Nakamoto, K., (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, , Wiley-Interscience, New York, 4th edn
- Deacon, G.B., Phillips, R.J., (1980) Coord. Chem. Rev., 33, p. 227
- Powder Diffraction File No. 41-1105 (yttria), JCPDS International Center for Diffraction Data, Swarthmore, PA, 1992; Huheey, J.E., (1978) Principles of Structure and Reactivity, , Harper and Row, New York, 2nd edn
- Cotton, F.A., Wilkinson, G., (1988) Advanced Inorganic Chemistry, p. 483. , Wiley-Interscience, New York, 5th edn
Citas:
---------- APA ----------
Baggio, R., Garland, M.T. & Perec, M.
(1998)
. Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes. Inorganica Chimica Acta, 281(1), 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M.
"Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes"
. Inorganica Chimica Acta 281, no. 1
(1998) : 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M.
"Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes"
. Inorganica Chimica Acta, vol. 281, no. 1, 1998, pp. 18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M. Synthesis and X-ray crystal determination of four novel lanthanide(III) oxydiacetate complexes. Inorg. Chim. Acta. 1998;281(1):18-24.
http://dx.doi.org/10.1016/S0020-1693(98)00131-5