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Abstract:

In this work, we present a complete and detailed experimental characterization and theoretical study of a variety of coordinated S-nitrosothiols (RSNOs), such as cysteine derivatives, mercaptosuccinic acid, benzyl thiol, and phenyl thiol. Some of them are extremely unstable and sensitive in free form. Strikingly, in contrast with free S-nitrosothiols, we found that, upon coordination to iridium, they become very stable even in aqueous solutions. The study of these coordinated complexes provides further insight on the elucidation of structural aspects dealing with the nature of the S-N bond in RSNOs, a fact which still remains a matter of controversy. © 2008 American Chemical Society.

Registro:

Documento: Artículo
Título:A unique family of stable and water-soluble S-nitrosothiol complexes
Autor:Perissinotti, L.L.; Leitus, G.; Shimon, L.; Estrin, D.; Doctorovich, F.
Filiación:Departamento de Quimica Inorganica, Analitica Y Quimica Fisica/INQUIMAE, Facultad de Ciencias Exactas Y Naturales, Pabellón II, (C1428EHA) Buenos Aires, Argentina
Department of Chemical Services, Weizmann Institute of Science, Rehovot 76100, Israel
Palabras clave:2 thiomalic acid; 2-thiomalic acid; cysteine; ester; potassium derivative; s nitrosothiol; thiomalic acid; water; article; chemistry; electrospray mass spectrometry; infrared spectroscopy; nuclear magnetic resonance spectroscopy; solubility; ultraviolet spectrophotometry; X ray crystallography; Crystallography, X-Ray; Cysteine; Esters; Magnetic Resonance Spectroscopy; Potassium Compounds; S-Nitrosothiols; Solubility; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Ultraviolet; Spectroscopy, Fourier Transform Infrared; Thiomalates; Water
Año:2008
Volumen:47
Número:11
Página de inicio:4723
Página de fin:4733
DOI: http://dx.doi.org/10.1021/ic7024999
Título revista:Inorganic Chemistry
Título revista abreviado:Inorg. Chem.
ISSN:00201669
CODEN:INOCA
CAS:cysteine, 4371-52-2, 52-89-1, 52-90-4; thiomalic acid, 70-49-5; water, 7732-18-5; 2-thiomalic acid, 70-49-5; Cysteine, 52-90-4; Esters; Potassium Compounds; S-Nitrosothiols; Thiomalates; Water, 7732-18-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v47_n11_p4723_Perissinotti

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Citas:

---------- APA ----------
Perissinotti, L.L., Leitus, G., Shimon, L., Estrin, D. & Doctorovich, F. (2008) . A unique family of stable and water-soluble S-nitrosothiol complexes. Inorganic Chemistry, 47(11), 4723-4733.
http://dx.doi.org/10.1021/ic7024999
---------- CHICAGO ----------
Perissinotti, L.L., Leitus, G., Shimon, L., Estrin, D., Doctorovich, F. "A unique family of stable and water-soluble S-nitrosothiol complexes" . Inorganic Chemistry 47, no. 11 (2008) : 4723-4733.
http://dx.doi.org/10.1021/ic7024999
---------- MLA ----------
Perissinotti, L.L., Leitus, G., Shimon, L., Estrin, D., Doctorovich, F. "A unique family of stable and water-soluble S-nitrosothiol complexes" . Inorganic Chemistry, vol. 47, no. 11, 2008, pp. 4723-4733.
http://dx.doi.org/10.1021/ic7024999
---------- VANCOUVER ----------
Perissinotti, L.L., Leitus, G., Shimon, L., Estrin, D., Doctorovich, F. A unique family of stable and water-soluble S-nitrosothiol complexes. Inorg. Chem. 2008;47(11):4723-4733.
http://dx.doi.org/10.1021/ic7024999