Artículo
Zayat, L.; Salierno, M.; Etchenique, R. "Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines" (2006) Inorganic Chemistry. 45(4):1728-1731
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Abstract:
The synthesis and characterization of a series of ruthenium bis(bipyridine) complexes where the inorganic moiety acts as a photolabile protecting group is described. Complexes of the type [Ru(bpy)2L2]+ where bpy = 2,2′-bipyridine and L = butylamine, γ-aminobutyric acid, tyramine, tryptamine, and serotonin were studied by nuclear magnetic resonance, cyclic voltammetry, and electronic absorption spectroscopy. In all cases, ligands are coordinated by the amine group. The complexes are stable in water for several days and deliver one molecule of ligand upon irradiation with visible light (450 nm). These properties make them suitable for their use as biological caged compounds. © 2006 American Chemical Society.
Registro:
| Documento: | Artículo |
| Título: | Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines |
| Autor: | Zayat, L.; Salierno, M.; Etchenique, R. |
| Filiación: | Departamento de Química Inorgánica, Analítica Y Química Física, INQUIMAE, Ciudad Universitaria Pabellón 2, AR1428EHA Buenos Aires, Argentina |
| Palabras clave: | 2,2' bipyridine; agents interacting with transmitter, hormone or drug receptors; biogenic amine; ruthenium derivative; article; chemistry; nuclear magnetic resonance spectroscopy; 2,2'-Dipyridyl; Biogenic Amines; Magnetic Resonance Spectroscopy; Neurotransmitter Agents; Ruthenium Compounds |
| Año: | 2006 |
| Volumen: | 45 |
| Número: | 4 |
| Página de inicio: | 1728 |
| Página de fin: | 1731 |
| DOI: | http://dx.doi.org/10.1021/ic0512983 |
| Título revista: | Inorganic Chemistry |
| Título revista abreviado: | Inorg. Chem. |
| ISSN: | 00201669 |
| CODEN: | INOCA |
| CAS: | 2,2' bipyridine, 366-18-7; 2,2'-Dipyridyl, 366-18-7; Biogenic Amines; Neurotransmitter Agents; Ruthenium Compounds |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v45_n4_p1728_Zayat |
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Citas:
---------- APA ----------
Zayat, L., Salierno, M. & Etchenique, R. (2006) . Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines. Inorganic Chemistry, 45(4), 1728-1731.http://dx.doi.org/10.1021/ic0512983
---------- CHICAGO ----------
Zayat, L., Salierno, M., Etchenique, R. "Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines" . Inorganic Chemistry 45, no. 4 (2006) : 1728-1731.http://dx.doi.org/10.1021/ic0512983
---------- MLA ----------
Zayat, L., Salierno, M., Etchenique, R. "Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines" . Inorganic Chemistry, vol. 45, no. 4, 2006, pp. 1728-1731.http://dx.doi.org/10.1021/ic0512983
---------- VANCOUVER ----------
Zayat, L., Salierno, M., Etchenique, R. Ruthenium(II) bipyridyl complexes as photolabile caging groups for amines. Inorg. Chem. 2006;45(4):1728-1731.http://dx.doi.org/10.1021/ic0512983
