Artículo
Rizzi, A.C.; Calvo, R.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. "Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate)" (2002) Inorganic Chemistry. 41(21):5609-5614
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Abstract:
The hydrothermal reaction of Ln2O3 (Ln = Dy and Ho), Cu(OAC)2.2H2O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu3Ln2(oda)6 (H2O)6}·12H2O]n, crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu-Dy 1, Cu-Ho 2, Cu-Er 3, and Cu-Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.
Registro:
| Documento: | Artículo |
| Título: | Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate) |
| Autor: | Rizzi, A.C.; Calvo, R.; Baggio, R.; Garland, M.T.; Peña, O.; Perec, M. |
| Filiación: | Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina Departamento de Física, Comisión Nacional de Energía Atómica, Avda. del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Avda. Blanco Encalada 2008, Casilla 487-3, Santiago, Chile U.M.R. 6511, L.C.S.I.M. CNRS, Universite Rennes I, 35042 Rennes, France Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina |
| Palabras clave: | acetoacetic acid derivative; carboxylic acid; copper complex; dysprosium; erbium; holmium; lanthanide; water; article; chemical reaction; crystallization; electron spin resonance; electronics; ion exchange; magnetism; stoichiometry; temperature dependence |
| Año: | 2002 |
| Volumen: | 41 |
| Número: | 21 |
| Página de inicio: | 5609 |
| Página de fin: | 5614 |
| DOI: | http://dx.doi.org/10.1021/ic025754o |
| Título revista: | Inorganic Chemistry |
| Título revista abreviado: | Inorg. Chem. |
| ISSN: | 00201669 |
| CODEN: | INOCA |
| CAS: | dysprosium, 7429-91-6; erbium, 7440-52-0; holmium, 7440-60-0; water, 7732-18-5 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v41_n21_p5609_Rizzi |
Referencias:
- Segal, D., (1989) Chemical Synthesis of Advanced Ceramic Material, , Cambridge University Press: Cambridge, U.K
- Chanaud, P., Julve, A., Vaija, P., Persin, M., Cot, L., (1994) J. Mater. Sci., 29, p. 4224
- Wang, S., Pang, Z., Smith, K.D.L., Wagner, M.J., (1994) J. Chem. Soc., Dalton Trans., p. 955
- Kahn, O., Guillou, O., (1993) New Frontiers in Magnetochemistry, , O'Connor, C.J., Ed., World Scientific, Singapore
- Kahn, O., (1995) Adv. Inorg. Chem., 43, p. 179
- Kahn, O., (1993) Molecular Magnetism, , VCH: Weinheim
- Kahn, M.L., Mathoniere, C., Kahn, O., (1999) Inorg. Chem., 38, p. 3692
- Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M., Spodine, E., (2000) J. Chem. Soc., Dalton Trans., p. 2061
- Mao, J.-G., Song, L., Huang, X.-Y., Huang, J.-S., (1997) Polyhedron, 16, p. 963
- Mao, J.-G., Huang, J.-S., Ma, J.F., Ni, J.-Z., (1997) Transition Met. Chem. (London), 22, p. 277
- Mao, J.-G., Song, L., Huang, J.-S., (1997) Jiegou Huaxue, 16, p. 228
- Liu, Q.-D., Li, J.-R., Gao, S., Ma, B.-Q., Liao, F.-H., Zhou, Q.-Z., Yu, K.-B., (2001) Inorg. Chem. Commun., 4, p. 301
- Kutlu, I., Meyer, G., Oczko, G., Legendziewicz, J., (1997) Eur. J. Solid State Inorg. Chem., 34, p. 231
- Legendziewicz, J., Borzechowska, M., Oczko, G., Meyer, G., (2000) New J. Chem., 24, p. 53
- Voronkova, V.K., Yablokov, Yu.V., Legendziewicz, J., Borzechowska, M., (1999) Phys. Solid State, 41, p. 1976
- Liang, Y., Cao, R., Su, W., Hong, M., Zhang, W., (2000) Angew. Chem., Int. Ed., 39, p. 3304
- Liang, Y., Hong, M., Su, W., Cao, R., Zhang, W., (2001) Inorg. Chem., 40, p. 4574
- Liang, Y., Cao, R., Hong, M., Sun, D., Zhao, Y., Weng, J., Wang, R., (2002) Inorg. Chem. Commun., 5, p. 366
- Sheldrick, G.M., (1997) SHELXL-97: Program for the Refinement of Crystal Structures from Diffraction Data, , University of Gottingen: Gottingen, Germany
- Sheldrick, G.M., (1991) SHELXTL-PC Version 4.2, Siemens, , Analytical X-ray Instruments Inc.: Madison. WI
- Albertsson, J., (1968) Acta Chem. Scand., 22, p. 1563
- Calvo, R., Mesa, M.A., (1983) Phys. Rev. B, 28, p. 1244
Citas:
---------- APA ----------
Rizzi, A.C., Calvo, R., Baggio, R., Garland, M.T., Peña, O. & Perec, M. (2002) . Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate). Inorganic Chemistry, 41(21), 5609-5614.http://dx.doi.org/10.1021/ic025754o
---------- CHICAGO ----------
Rizzi, A.C., Calvo, R., Baggio, R., Garland, M.T., Peña, O., Perec, M. "Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate)" . Inorganic Chemistry 41, no. 21 (2002) : 5609-5614.http://dx.doi.org/10.1021/ic025754o
---------- MLA ----------
Rizzi, A.C., Calvo, R., Baggio, R., Garland, M.T., Peña, O., Perec, M. "Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate)" . Inorganic Chemistry, vol. 41, no. 21, 2002, pp. 5609-5614.http://dx.doi.org/10.1021/ic025754o
---------- VANCOUVER ----------
Rizzi, A.C., Calvo, R., Baggio, R., Garland, M.T., Peña, O., Perec, M. Carboxylate-bridged copper(II)-lanthanide(III) complexes [{Cu3Ln2(oda)6 (H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate). Inorg. Chem. 2002;41(21):5609-5614.http://dx.doi.org/10.1021/ic025754o
