Artículo
Doller, D.; Gros, E.G. "Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions" (1989) Helvetica Chimica Acta. 72(6):1241-1247
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Abstract:
The base‐catalysed rearrangement of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one diacetate (1) in (D6)benzene/CD3OD to 3β, 17β‐dihydroxy‐5α‐androstan‐16‐one (3) is followed by 13C‐NMR spectroscopy. By the same procedure, it is determined that in (D6)benzene/CD3OD, but under acid catalysis, 1 does not rearrange to 3 but yields the intermediate product 3β, 16α‐dihydroxy‐5α ‐androstan‐17‐one 17α ‐methyl hemiacetal (5). Copyright © 1989 Verlag GmbH & Co. KGaA, Weinheim
Registro:
| Documento: | Artículo |
| Título: | Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions |
| Autor: | Doller, D.; Gros, E.G. |
| Filiación: | Departamento de Quimica Orgánica, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1428, Argentina |
| Palabras clave: | 3beta,16alpha dihydroxy 5alpha androstan 17 one diacetate; unclassified drug; carbon nuclear magnetic resonance; drug stability; drug structure; nonhuman; nuclear magnetic resonance |
| Año: | 1989 |
| Volumen: | 72 |
| Número: | 6 |
| Página de inicio: | 1241 |
| Página de fin: | 1247 |
| DOI: | http://dx.doi.org/10.1002/hlca.19890720608 |
| Título revista: | Helvetica Chimica Acta |
| Título revista abreviado: | Helv. Chim. Acta |
| ISSN: | 0018019X |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v72_n6_p1241_Doller |
Referencias:
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Citas:
---------- APA ----------
Doller, D. & Gros, E.G. (1989) . Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions. Helvetica Chimica Acta, 72(6), 1241-1247.http://dx.doi.org/10.1002/hlca.19890720608
---------- CHICAGO ----------
Doller, D., Gros, E.G. "Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions" . Helvetica Chimica Acta 72, no. 6 (1989) : 1241-1247.http://dx.doi.org/10.1002/hlca.19890720608
---------- MLA ----------
Doller, D., Gros, E.G. "Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions" . Helvetica Chimica Acta, vol. 72, no. 6, 1989, pp. 1241-1247.http://dx.doi.org/10.1002/hlca.19890720608
---------- VANCOUVER ----------
Doller, D., Gros, E.G. Dissimilar behaviour of 3β, 16α‐dihydroxy‐5α‐androstan‐17‐one Diacetate under Basic and Acidic Conditions. Helv. Chim. Acta. 1989;72(6):1241-1247.http://dx.doi.org/10.1002/hlca.19890720608
