Artículo
Nudelman, N.S.; Doctorovich, F.; Linares, G.G.; Schulz, H.; Mendiara, S. "The carbonylaiion of organolithium compounds: a polar or a radical mechanism?" (1996) Gazzetta Chimica Italiana. 126(1):19-24
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Abstract:
A variety of riethods were utilized to study the mechanism of carbonylation of organolithium compounds. Convincing evidence that the reaction of aryllithium compounds takes place by radical pathways, being the electron transfer from aryllithium to CO the first rate-determining step, is presented. On the other hand, in the rt actions of lithium dialkylamides no evidence for radical intermediates was found.
Registro:
| Documento: | Artículo |
| Título: | The carbonylaiion of organolithium compounds: a polar or a radical mechanism? |
| Autor: | Nudelman, N.S.; Doctorovich, F.; Linares, G.G.; Schulz, H.; Mendiara, S. |
| Filiación: | Depto. Quimica Orgänica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Pab. II, P. 3, Ciudad Universitaria, 1428 Buenos Aires, Argentina Depto. Quimica, Facultad de Ciencias Exactas, Universidad National de Mar Del Plata, Funes 3350, 7600 Mar del Plata, Argentina |
| Año: | 1996 |
| Volumen: | 126 |
| Número: | 1 |
| Página de inicio: | 19 |
| Página de fin: | 24 |
| Título revista: | Gazzetta Chimica Italiana |
| ISSN: | 00165603 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00165603_v126_n1_p19_Nudelman |
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Citas:
---------- APA ----------
Nudelman, N.S., Doctorovich, F., Linares, G.G., Schulz, H. & Mendiara, S. (1996) . The carbonylaiion of organolithium compounds: a polar or a radical mechanism?. Gazzetta Chimica Italiana, 126(1), 19-24.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00165603_v126_n1_p19_Nudelman [ ]
---------- CHICAGO ----------
Nudelman, N.S., Doctorovich, F., Linares, G.G., Schulz, H., Mendiara, S. "The carbonylaiion of organolithium compounds: a polar or a radical mechanism?" . Gazzetta Chimica Italiana 126, no. 1 (1996) : 19-24.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00165603_v126_n1_p19_Nudelman [ ]
---------- MLA ----------
Nudelman, N.S., Doctorovich, F., Linares, G.G., Schulz, H., Mendiara, S. "The carbonylaiion of organolithium compounds: a polar or a radical mechanism?" . Gazzetta Chimica Italiana, vol. 126, no. 1, 1996, pp. 19-24.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00165603_v126_n1_p19_Nudelman [ ]
---------- VANCOUVER ----------
Nudelman, N.S., Doctorovich, F., Linares, G.G., Schulz, H., Mendiara, S. The carbonylaiion of organolithium compounds: a polar or a radical mechanism?. 1996;126(1):19-24.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00165603_v126_n1_p19_Nudelman [ ]
