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Abstract:

The Raman spectra of ceramic samples of the Pb(Ti1-xZrx,)O3 system in its room temperature tetragonal phase have been recorded. In the frequency region of the soft phonons, the spectra show the band of the q ~ 0 soft EfTO) mode and an additional band, absent forr = 0, centered in the 50–60 cm1. The line-shape of the soft E(TO) phonon changes from underdamped to overdamped for x > 0.40. The x-dependence of the frequency of this mode indicates that it becomes unstable in the vicinity of the morphotropic, tetragonal-rhombohedral, phase-boundary. A brief thermodynamical discussion of the behavior of the soft E(TO) mode is given. © 1974, Taylor & Francis Group, LLC. All rights reserved.

Registro:

Documento: Artículo
Título:Raman Scattering From Soft E(TO) Phonons Of The Pb(Ti1-xZrx,)O3 System
Autor:Merlin, R.
Filiación:Dpto. de Fisica, Fac. de Cs. Exactas v Naturales, Ciudad Universitaria, Buenos Aires, Argentina
Dpto. de Instrumentation, Com. Nac. de Energia Atdmica, Buenos Aires S29, Argentina
Año:1974
Volumen:7
Número:1
Página de inicio:275
Página de fin:277
DOI: http://dx.doi.org/10.1080/00150197408238019
Título revista:Ferroelectrics
Título revista abreviado:Ferroelectrics
ISSN:00150193
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00150193_v7_n1_p275_Merlin

Referencias:

  • Jaffe, B., Cook, W.R., Jaffe, H., Piezoelectric Ceramics ; Pinczuk, A., (1973) Solid State Commun., 12, p. 1035
  • Burns, G., Scott, B.A., (1970) Phys. Rev. Lett., 25, p. 1191
  • Haertling, G.H., (1971) J. Am. Ceram. Soc., 54, p. 6
  • Lucovsky, G., Brodsky, M.H., Burstein, E., Localized Excitations in Solids (1968), p. 582. , Edited by R. F. Wallis (Plenum Press, N.Y; Shirane, G., Axe, J.D., Harada, J., Remeika, J.P., (1970) Phys. Rev., B2, p. 155
  • Merlin, R., Pinczuk, A., work in progress; Brya, W.J., (1971) Phys. Rev. Lett., 26, p. 1114
  • Burns, G., Scott, B.A., (1973) Phys. Rev., B7, p. 3088
  • Carl, V., Hardtl, K.H., Phys. Stat. Solidi (a) (1971), 8, p. 87; Benguigui, L., (1972) Solid State Commun., 11, p. 825

Citas:

---------- APA ----------
(1974) . Raman Scattering From Soft E(TO) Phonons Of The Pb(Ti1-xZrx,)O3 System. Ferroelectrics, 7(1), 275-277.
http://dx.doi.org/10.1080/00150197408238019
---------- CHICAGO ----------
Merlin, R. "Raman Scattering From Soft E(TO) Phonons Of The Pb(Ti1-xZrx,)O3 System" . Ferroelectrics 7, no. 1 (1974) : 275-277.
http://dx.doi.org/10.1080/00150197408238019
---------- MLA ----------
Merlin, R. "Raman Scattering From Soft E(TO) Phonons Of The Pb(Ti1-xZrx,)O3 System" . Ferroelectrics, vol. 7, no. 1, 1974, pp. 275-277.
http://dx.doi.org/10.1080/00150197408238019
---------- VANCOUVER ----------
Merlin, R. Raman Scattering From Soft E(TO) Phonons Of The Pb(Ti1-xZrx,)O3 System. Ferroelectrics. 1974;7(1):275-277.
http://dx.doi.org/10.1080/00150197408238019