We discuss the infrared reflectivity of strontium rutenate, SrRuO3, measured from 40 cm-1 to 10000 cm-1. The relative high reflectance at low frequencies and the semimetallic behavior at values between 300 cm-1 and 1900 cm-1 found in this compound is in accordance with a system with relatively free carriers. Two weak absorptions at about 450 cm-1 and 800 cm-1 are assigned to the interaction between electrons and longitudinal phonons . The reflectivity decays rather sharply up to about 3900 cm-1 and then decreases asymptotically at higher energies. From Kramers-Kronig and multioscillator analyses we obtain the effective carrier number N* = 7.07 1018 cm-3, the effective mobility μ* = 142.6 cm2V-1sec-1 and the optical conductivity σo = 175.6 Ω-1cm-1.
Documento: | Artículo |
Título: | Infrared reflectivity of SrRuO3 |
Autor: | De La Cruz, F.P.; Massa, N.E.; Cuffini, S.L.; Carbonio, R.E. |
Filiación: | CNEA, División Radioquímica, Av. del Libertador 8250, 1429 Buenos Aires, Argentina Depto. de Física, Universidad de Buenos Aires, Ciudad Universitaria, Pab. 1, Buenos Aires, Argentina LANAIS en Espectroscopia Optica, Prog. QUINOR, Universidad Nacional de La Plata, C.C. 962, 1900, La Plata, Argentina Depto. de Física, Universidad Nacional de La Plata, C.C. 962, 1900, La Plata, Argentina INFIQC, Depto. de Fisicoquímica, Univ. Nacional de Córdoba, Suc. 16, C.C. 61, 5016 Córdoba, Argentina |
Palabras clave: | Electrons; Infrared spectroscopy; Light absorption; Light reflection; Mathematical transformations; Numerical analysis; Phonons; Photoconductivity; Kramers-Kronig analysis; Multioscillator analyses; Optical conductivity; Orthorhombic structure; Reflectivity decays; Semimetallic behavior; Solid state synthesis; Strontium rutenate; Strontium compounds |
Año: | 1996 |
Volumen: | 185 |
Número: | 1-4 |
Página de inicio: | 277 |
Página de fin: | 280 |
DOI: | http://dx.doi.org/10.1080/00150199608210532 |
Título revista: | Ferroelectrics |
Título revista abreviado: | Ferroelectrics |
ISSN: | 00150193 |
CODEN: | FEROA |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00150193_v185_n1-4_p277_DeLaCruz |