Abstract:
It is found that, when correctly formulated, the steady-state hypothesis can be applied to reactions involving volume changes. In particular, it is demonstrated that it can be applied to depolymerization reactions even if they are not first-order with respect to the weight of the sample. © 1974.
Referencias:
- MacCallum, (1971) Europ. Polym. J., 7, p. 1237
- Canagaratna, (1973) J. chem. Educ., 50, p. 200
- Hutchison, Lehre, Robb, Suggate, Rational definition of rate of reaction. General method of expressing rate which leads to no anomalies in systems of changing volume (1973) Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1, p. 426
- Hutchison, Lehre, Robb, Suggate, (1973) J. chem. Soc. Faraday, 69, p. 426
- Ham, (1967) Vinyl Polymerization, p. 11. , Marcel Dekker, New York
- Bamford, Barb, Jenkins, Onyon, (1958) The Kinetics of Vinyl Polymerization by Radical Mechanism, p. 10. , Marcel Dekker, London
Citas:
---------- APA ----------
(1974)
. The application of the steady-state hypothesis in the analysis of reactions with significant volume change. European Polymer Journal, 10(11), 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X---------- CHICAGO ----------
Lissi, E.A.
"The application of the steady-state hypothesis in the analysis of reactions with significant volume change"
. European Polymer Journal 10, no. 11
(1974) : 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X---------- MLA ----------
Lissi, E.A.
"The application of the steady-state hypothesis in the analysis of reactions with significant volume change"
. European Polymer Journal, vol. 10, no. 11, 1974, pp. 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X---------- VANCOUVER ----------
Lissi, E.A. The application of the steady-state hypothesis in the analysis of reactions with significant volume change. Eur Polym J. 1974;10(11):1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X