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Abstract:

It is found that, when correctly formulated, the steady-state hypothesis can be applied to reactions involving volume changes. In particular, it is demonstrated that it can be applied to depolymerization reactions even if they are not first-order with respect to the weight of the sample. © 1974.

Registro:

Documento: Artículo
Título:The application of the steady-state hypothesis in the analysis of reactions with significant volume change
Autor:Lissi, E.A.
Filiación:Departamento de Química, Facultad de Ciencias, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina
Año:1974
Volumen:10
Número:11
Página de inicio:1051
Página de fin:1052
DOI: http://dx.doi.org/10.1016/0014-3057(74)90069-X
Título revista:European Polymer Journal
Título revista abreviado:Eur Polym J
ISSN:00143057
CODEN:EUPJA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00143057_v10_n11_p1051_Lissi

Referencias:

  • MacCallum, (1971) Europ. Polym. J., 7, p. 1237
  • Canagaratna, (1973) J. chem. Educ., 50, p. 200
  • Hutchison, Lehre, Robb, Suggate, Rational definition of rate of reaction. General method of expressing rate which leads to no anomalies in systems of changing volume (1973) Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1, p. 426
  • Hutchison, Lehre, Robb, Suggate, (1973) J. chem. Soc. Faraday, 69, p. 426
  • Ham, (1967) Vinyl Polymerization, p. 11. , Marcel Dekker, New York
  • Bamford, Barb, Jenkins, Onyon, (1958) The Kinetics of Vinyl Polymerization by Radical Mechanism, p. 10. , Marcel Dekker, London

Citas:

---------- APA ----------
(1974) . The application of the steady-state hypothesis in the analysis of reactions with significant volume change. European Polymer Journal, 10(11), 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X
---------- CHICAGO ----------
Lissi, E.A. "The application of the steady-state hypothesis in the analysis of reactions with significant volume change" . European Polymer Journal 10, no. 11 (1974) : 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X
---------- MLA ----------
Lissi, E.A. "The application of the steady-state hypothesis in the analysis of reactions with significant volume change" . European Polymer Journal, vol. 10, no. 11, 1974, pp. 1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X
---------- VANCOUVER ----------
Lissi, E.A. The application of the steady-state hypothesis in the analysis of reactions with significant volume change. Eur Polym J. 1974;10(11):1051-1052.
http://dx.doi.org/10.1016/0014-3057(74)90069-X