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Abstract:

Electronic nose methodology was used for discriminating between samples of n-primary alcohols and phenol in water. An electronic nose device developed at our laboratory was applied to detect the vapors from the samples. The device consists of 10 nonspecific gas sensors based on tin-dioxide, whose electrical conductivity change when exposed to the vapors. The whole set of responses constitutes a fingerprint associated with the sample for the particular array of sensors. Using this method, we could differentiate among n-primary alcohols, pure phenol, and aqueous dilutions of phenol. Dilutions of primary alcohols and phenol of 1, 3, 5, and 10% (v/v) were assayed. The fingerprints of the dilutions are similar to that of the respective pure (not diluted) alcohol, but with lower signal intensities. Principal component analysis and cluster analysis were performed in order to explore the feasibility of discriminating among the samples. Dilutions of phenol were successfully discriminated from those of primary alcohols. Discrimination of n-octanol and n-decanol from the other alcohols, including phenol, was also achieved. The results suggest that it is possible to discriminate among dilutions of phenol in water and to give an approximate gross estimation of phenol concentration in water. © 2006 American Chemical Society.

Registro:

Documento: Artículo
Título:Detection and discrimination of phenol and primary alcohols in water using electronic noses
Autor:Diz, V.; Cassanello, M.; Negri, R.M.
Filiación:Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Buenos Aires, Argentina
PINMATE-Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Aqueous dilutions; Cluster analysis; Fingerprints; Alcohols; Concentration (process); Phenols; Principal component analysis; Water pollution; Water analysis; alcohol; butanol; decanol; octanol; oxide; phenol; tin; water; Alcohols; Concentration (process); Phenols; Principal component analysis; Water analysis; Water pollution; alcohol; cluster analysis; electronic equipment; laboratory method; phenol; principal component analysis; water quality; article; cluster analysis; dilution; electric conductivity; electronic sensor; principal component analysis; signal noise ratio; vapor; vapor pressure; volatilization; Alcohols; Cluster Analysis; Electronics; Phenol; Principal Component Analysis; Waste Disposal, Fluid; Water Pollutants, Chemical
Año:2006
Volumen:40
Número:19
Página de inicio:6058
Página de fin:6063
DOI: http://dx.doi.org/10.1021/es052322e
Título revista:Environmental Science and Technology
Título revista abreviado:Environ. Sci. Technol.
ISSN:0013936X
CODEN:ESTHA
CAS:alcohol, 64-17-5; butanol, 35296-72-1, 71-36-3; decanol, 112-30-1, 36729-58-5; octanol, 111-87-5, 29063-28-3; oxide, 16833-27-5; phenol, 108-95-2, 3229-70-7; tin, 14314-35-3, 7440-31-5; water, 7732-18-5; Alcohols; Phenol, 108-95-2; Water Pollutants, Chemical
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0013936X_v40_n19_p6058_Diz

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Citas:

---------- APA ----------
Diz, V., Cassanello, M. & Negri, R.M. (2006) . Detection and discrimination of phenol and primary alcohols in water using electronic noses. Environmental Science and Technology, 40(19), 6058-6063.
http://dx.doi.org/10.1021/es052322e
---------- CHICAGO ----------
Diz, V., Cassanello, M., Negri, R.M. "Detection and discrimination of phenol and primary alcohols in water using electronic noses" . Environmental Science and Technology 40, no. 19 (2006) : 6058-6063.
http://dx.doi.org/10.1021/es052322e
---------- MLA ----------
Diz, V., Cassanello, M., Negri, R.M. "Detection and discrimination of phenol and primary alcohols in water using electronic noses" . Environmental Science and Technology, vol. 40, no. 19, 2006, pp. 6058-6063.
http://dx.doi.org/10.1021/es052322e
---------- VANCOUVER ----------
Diz, V., Cassanello, M., Negri, R.M. Detection and discrimination of phenol and primary alcohols in water using electronic noses. Environ. Sci. Technol. 2006;40(19):6058-6063.
http://dx.doi.org/10.1021/es052322e