Abstract:
Solutions of limonene and tetraethylammonium bromide in methanol were electrochemically oxidized at Pt anodes. Three main products were obtained, namely, 6-methoxylimonene (1), 1-methoxy-2-bromomenth-8-ene (2) and 1,8-dimethoxy-2,9-dibromo-p-menthane (3). Reaction routes leading to these compounds are proposed. © 1990.
Registro:
Documento: |
Artículo
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Título: | Anodic oxidation of limonene in Br- containing methanolic solutions |
Autor: | Caram, J.A.; Martins, M.E.; Gros, E.G.; Marschoff, C.M. |
Filiación: | Instituto de Investigaciones Físico, Químicas Teóricas y Aplicadas, C.C. 16, Sucursal 4, 1900 La Plata, Argentina Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina Laboratorio de Electroquímica Aplicada, Departamento de Ingeniería Química, Facultad de Ingeniería, Pabellon Industrias, Ciudad Universitaria, 1428 Buenos Aires, Argentina
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Año: | 1990
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Volumen: | 35
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Número: | 7
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Página de inicio: | 1163
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Página de fin: | 1165
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DOI: |
http://dx.doi.org/10.1016/0013-4686(90)80033-K |
Título revista: | Electrochimica Acta
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Título revista abreviado: | Electrochim Acta
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ISSN: | 00134686
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CODEN: | ELCAA
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134686_v35_n7_p1163_Caram |
Referencias:
- Fichter, Schetty, Die elektrochemische Oxydation des Pinen's (1937) Helvetica Chimica Acta, 20, p. 1304
- Glasstone, Stanley, The Electrolytic Oxidation of α-Pinene, Terpinolene and Dipentene (1947) Transactions of The Electrochemical Society, 97, p. 327
- Reed, Hawkins, Reactions of β-Pinene (1950) Journal of The Electrochemical Society, 99, p. 178
- Shono, Ikeda, (1972) J. Am. chem. Soc., 94, p. 7892
- Shono, Ikeda, Hayashi, Hakozaki, (1975) J. Am. chem. Soc., 97, p. 4261
- Montiel, López Segura, Aldaz, (1984) Electrochim. Acta, 29, p. 1123
- Duarte, Landerreche, Marschoff, Martins, (1983) Electrochim. Acta, 28, p. 331
- Caram, Martins, Gros, Marschoff, Anodic behaviour of limonene in low aqueous acetonitrile solutions of Cl− (1988) Canadian Journal of Chemistry, 66, p. 1757
- J. A. Caram, M. E. Martins, E. G. Gros and C. M. Marschoff, Electrochim. Acta, in press
Citas:
---------- APA ----------
Caram, J.A., Martins, M.E., Gros, E.G. & Marschoff, C.M.
(1990)
. Anodic oxidation of limonene in Br- containing methanolic solutions. Electrochimica Acta, 35(7), 1163-1165.
http://dx.doi.org/10.1016/0013-4686(90)80033-K---------- CHICAGO ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M.
"Anodic oxidation of limonene in Br- containing methanolic solutions"
. Electrochimica Acta 35, no. 7
(1990) : 1163-1165.
http://dx.doi.org/10.1016/0013-4686(90)80033-K---------- MLA ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M.
"Anodic oxidation of limonene in Br- containing methanolic solutions"
. Electrochimica Acta, vol. 35, no. 7, 1990, pp. 1163-1165.
http://dx.doi.org/10.1016/0013-4686(90)80033-K---------- VANCOUVER ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M. Anodic oxidation of limonene in Br- containing methanolic solutions. Electrochim Acta. 1990;35(7):1163-1165.
http://dx.doi.org/10.1016/0013-4686(90)80033-K