Artículo
Caram, J.A.; Martins, M.E.; Gros, E.G.; Marschoff, C.M. "On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes" (1990) Electrochimica Acta. 35(2):497-500
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Abstract:
Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is formed by homogeneous reaction. Other minor products, including the new molecule 8-acetamido-2,4,8-trimethyl-4-bromomethyl-3-aza-bicyclo |3.3.1| non-2-ene (4), were identified. © 1990.
Registro:
| Documento: | Artículo |
| Título: | On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes |
| Autor: | Caram, J.A.; Martins, M.E.; Gros, E.G.; Marschoff, C.M. |
| Filiación: | Instituto de Investigaciones Físico-Químicas Teóricas y Aplicadas, Casilla de Correo 16, Sucursal 4, 1900 La Plata, Argentina Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina Laboratorio de Electroquímica Aplicada, Departamento de Ingeniería Química, Facultad de Ingeniería, Pabellon Industrias, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| Año: | 1990 |
| Volumen: | 35 |
| Número: | 2 |
| Página de inicio: | 497 |
| Página de fin: | 500 |
| DOI: | http://dx.doi.org/10.1016/0013-4686(90)87035-Z |
| Título revista: | Electrochimica Acta |
| Título revista abreviado: | Electrochim Acta |
| ISSN: | 00134686 |
| CODEN: | ELCAA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134686_v35_n2_p497_Caram |
Referencias:
- Caram, Martins, Gros, Marschoff, Anodic behaviour of limonene in low aqueous acetonitrile solutions of Cl− (1988) Canadian Journal of Chemistry, 66, p. 1757
- Duarte, Landerreche, Marschoff, Martins, (1983) Electrochim. Acta, 28, p. 331
- Popov, Geske, (1958) J. Am. chem. Soc., 80, p. 5346
- Pouillen, Minko, Verniette, Martinet, (1979) Electrochim. Acta, 24, p. 1189
- Caram, Martins, Marschoff, Cafferata, Gros, (1984) Z. Natürforsch., 39 b, p. 972
- J. A. Caram, B. E. Rivero, O. E. Piro, E. G. Gros and C. M. Marschoff, Can J. Chem., in press; Caram, (1986) Doctoral Thesis, , Universidad de Buenos Aires
Citas:
---------- APA ----------
Caram, J.A., Martins, M.E., Gros, E.G. & Marschoff, C.M. (1990) . On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes. Electrochimica Acta, 35(2), 497-500.http://dx.doi.org/10.1016/0013-4686(90)87035-Z
---------- CHICAGO ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M. "On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes" . Electrochimica Acta 35, no. 2 (1990) : 497-500.http://dx.doi.org/10.1016/0013-4686(90)87035-Z
---------- MLA ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M. "On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes" . Electrochimica Acta, vol. 35, no. 2, 1990, pp. 497-500.http://dx.doi.org/10.1016/0013-4686(90)87035-Z
---------- VANCOUVER ----------
Caram, J.A., Martins, M.E., Gros, E.G., Marschoff, C.M. On the anodic polarization of limonene in Br- containing acetonitrile solutions on platinum electrodes. Electrochim Acta. 1990;35(2):497-500.http://dx.doi.org/10.1016/0013-4686(90)87035-Z
