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In order to obtain new materials for energy storage as supercapacitors, Cobalt–Nitrogen doped mesoporous carbons were prepared from pyrolysis of two Cobalt Metal-Organic Frameworks (MOFs), one linear coordination polymer and one complex (not polymeric). The material derived from Cobalt 2,3-pyrazinedicarboxylate polymer (700 °C) exhibited a specific capacitance of 330 F g −1 (after acid leaching, in 6 M KOH, 1 A g −1 ). This material exhibited a reduction in its capacitance of only 2% after 3000 charge-discharge cycles. A specific capacitance of 430 F g −1 was reached after the addition of ferrocianide to the electrolyte. A correlation was found between the specific capacitance and both the specific surface area of mesopores and the Cobalt content. This correlation allowed discriminating between the pseudocapacitance and the double layer contributions to the total specific capacitance. Finally, a prototype symmetric capacitor was constructed which yielded a specific energy of 9.1 W h kg −1 (0.1 A g −1 ) and a specific power of 7 kW kg −1 (10 A g −1 ). A device constructed with two of these capacitors in series allowed to light a 1.5 V red LED. © 2019 Elsevier Ltd


Documento: Artículo
Título:Co,N-doped mesoporous carbons cobalt derived from coordination polymer as supercapacitors
Autor:Díaz-Duran, A.K.; Montiel, G.; Viva, F.A.; Roncaroli, F.
Filiación:Departamento de Física de la Materia Condensada, Instituto de Nanociencia y Nanotecnología, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica (CNEA), Avenida General Paz 1499, San Martín, Buenos Aires, 1650, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas-CONICET., Godoy Cruz 2290, Ciudad de Buenos Aires, 1425, Argentina
Palabras clave:Cobalt; Coordination polymer; Metal-organic framework; Pseudocapacitance; Supercapacitor; Capacitance; Cobalt; Coordination reactions; Crystalline materials; Doping (additives); Electrolytes; Mesoporous materials; Organic polymers; Organometallics; Potassium hydroxide; Charge-discharge cycle; Coordination Polymers; Metal organic framework; Metalorganic frameworks (MOFs); N-doped mesoporous carbons; Nitrogen-doped mesoporous carbons; Pseudocapacitance; Specific capacitance; Supercapacitor
Página de inicio:987
Página de fin:998
Título revista:Electrochimica Acta
Título revista abreviado:Electrochim Acta


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---------- APA ----------
Díaz-Duran, A.K., Montiel, G., Viva, F.A. & Roncaroli, F. (2019) . Co,N-doped mesoporous carbons cobalt derived from coordination polymer as supercapacitors. Electrochimica Acta, 299, 987-998.
---------- CHICAGO ----------
Díaz-Duran, A.K., Montiel, G., Viva, F.A., Roncaroli, F. "Co,N-doped mesoporous carbons cobalt derived from coordination polymer as supercapacitors" . Electrochimica Acta 299 (2019) : 987-998.
---------- MLA ----------
Díaz-Duran, A.K., Montiel, G., Viva, F.A., Roncaroli, F. "Co,N-doped mesoporous carbons cobalt derived from coordination polymer as supercapacitors" . Electrochimica Acta, vol. 299, 2019, pp. 987-998.
---------- VANCOUVER ----------
Díaz-Duran, A.K., Montiel, G., Viva, F.A., Roncaroli, F. Co,N-doped mesoporous carbons cobalt derived from coordination polymer as supercapacitors. Electrochim Acta. 2019;299:987-998.