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Abstract:

Cubic spinel LiMn2O4 has been studied for the reversible extraction of Li+ from natural brine after the application of suitable electrode potentials. In this work we report on the insertion/extraction of Li+ from natural brine of Olaroz salt flat (Jujuy, Argentina) and aqueous LiCl solutions into/from Li1-xMn2O4 (0 < x ≤ 1) to determine changes in the crystal structure and surface composition upon electrochemical polarization. In agreement with the behavior in organic electrolytes, we found that the insertion and extraction of Li+ proceeds via a two stage process and that the crystal structure undergoes two cubic phase transitions as the lattice is expanded or contracted. Contrary to the behavior in organic solvents, no decomposition layer is formed on the electrode surface and the surface composition can be controlled with the electrode potential. We also found that sodium cations present in natural brine are not inserted into the crystal lattice in the potential window explored, however they are adsorbed on the oxide surface blocking Li+ adsorption sites and decreasing the rate of Li+ exchange. © 2018 Elsevier Ltd

Registro:

Documento: Artículo
Título:Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions
Autor:Marchini, F.; Calvo, E.J.; Williams, F.J.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE-CONICET, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Palabras clave:Battery electrode; Extraction; LiMn2O4; Lithium; XPS; XRD; Chlorine compounds; Electrodes; Extraction; Lithium; Lithium batteries; Lithium compounds; Lithium-ion batteries; Manganese compounds; Solutions; X ray photoelectron spectroscopy; Battery electrode; Electrochemical polarization; Electrode potentials; Electrode surfaces; LiMn2O4; Organic electrolyte; Potential windows; Two-stage process; Crystal structure
Año:2018
Volumen:269
Página de inicio:706
Página de fin:713
DOI: http://dx.doi.org/10.1016/j.electacta.2018.02.108
Título revista:Electrochimica Acta
Título revista abreviado:Electrochim Acta
ISSN:00134686
CODEN:ELCAA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134686_v269_n_p706_Marchini

Referencias:

  • Whittingham, M.S., Lithium batteries and cathode materials (2004) Chem. Rev., 104, pp. 4271-4301
  • Makhonina, E.V., Pervov, V.S., Dubasova, V.S., Oxide materials as positive electrodes of lithium-ion batteries (2007) Russ. Chem. Rev., 73, pp. 991-1001
  • Thackeray, M.M., Johnson, P.J., de Picciotto, L.A., Bruce, P.G., Goodenough, J.B., Electrochemical extraction of lithium from LiMn2O4 (1984) Mater. Res. Bull., 19 (2), pp. 179-187
  • Thackeray, M.M., David, W.I.F., Bruce, P.G., Goodenough, J.B., Lithium insertion into manganese spinels (1983) Mater. Res. Bull., 18, pp. 461-472
  • Tarascon, J.M., Li metal-free rechargeable batteries based on Li(1+x)Mn2O4 cathodes (0 ≤ x ≤ 1) and carbon anodes (1991) J. Electrochem. Soc., 138, p. 2864
  • Rossouw, M., de Kock, A., de Picciotto, L., Thackeray, M., David, W., Ibberson, R., Structural aspects of lithium-manganese-oxide electrodes for rechargeable lithium batteries (1990) Mater. Res. Bull., 25, pp. 173-182
  • Ooi, K., Miyai, Y., Katoh, S., Maeda, H., Abe, M., Topotactic Li+ insertion to λLi1-XMm2O4 (x → 0)in the aqueous phase (1989) Langmuir, 5, pp. 150-157
  • Kanoh, H., Ooi, K., Miyai, Y., Katoh, S., Selective electroinsertion of lithium ions into a Pt/λLi1-XMm2O4 (x → 0)electrode in the aqueous phase (1991) Langmuir, 7, pp. 1841-1842
  • Mishra, S., Ceder, G., Structural stability of lithium manganese oxides (1999) Phys. Rev. B, 59, pp. 6120-6130
  • Berg, H., Go, K., Nola, B., Thomas, J.O., (1999) Electronic Structure and Stability of the Li, 4, pp. 2813-2820
  • Dong H, J., Shin, Y.J., Oh, S.M., Dissolution of spinel oxides and capacily losses in 4 V (1996) J. Electrochem. Soc., 143, pp. 2204-2211
  • Arora, P., Capacity fade mechanisms and side reactions in lithium-ion batteries (1998) J. Electrochem. Soc., 145, p. 3647
  • Xia, Y., Yoshio, M., An investigation of lithium ion insertion into spinel structure Li-Mn-O compounds (1996) J. Electrochem. Soc., 143, p. 825
  • Hoshino, T., Development of technology for recovering lithium from seawater by electrodialysis using ionic liquid membrane (2013) Fusion Eng. Des., 88, pp. 2956-2959
  • Intaranont, N., Garcia-Araez, N., Hector, A.L., Milton, J.A., Owen, J.R., Selective lithium extraction from brines by chemical reaction with battery materials (2014) J. Mater. Chem. A, 2, pp. 6374-6377
  • Lee, J., Yu, S.-H., Kim, C., Sung, Y.-E., Yoon, J., Highly selective lithium recovery from brine using a λ-MnO2–Ag battery (2013) Phys. Chem. Chem. Phys., 15, p. 7690
  • Trocoli, R., Bidhendi, G.K., La Mantia, F., Lithium recovery by means of electrochemical ion pumping: a comparison between salt capturing and selective exchange (2016) J. Phys. Condens. Matter, 28, p. 114005
  • Kanoh, H., Ooi, K., Miyai, Y., Katoh, S., Electrochemical recovery of lithium ions in the aqueous phase (1993) Separ. Sci. Technol., 28, pp. 643-651
  • Trócoli, R., Battistel, A., La Mantia, F., Selectivity of a lithium-recovery process based on LiFePO 4 (2014) Chem. A Eur J., 20, pp. 9888-9891
  • Kanoh, H., AC impedance analysis for Li+ insertion of a Pt∕λLi1-XMm2O4 (x 0)Electrode in an aqueous phase (1996) J. Electrochem. Soc., 143, p. 2610
  • Aurbach, D., Gamolsky, K., Markovsky, B., Salitra, G., Gofer, Y., Heider, U., Oesten, R., Schmidt, M., The study of surface phenomena related to electrochemical lithium intercalation into LixMOy host materials (M = Ni, Mn) (2000) J. Electrochem. Soc., 147, p. 1322
  • Edström, K., Gustafsson, T., Thomas, J.O., The cathode-electrolyte interface in the Li-ion battery (2004) Electrochim. Acta, 50, pp. 397-403
  • Missoni, L.L., Marchini, F., del Pozo, M., Calvo, E.J., A LiMn2O4 -polypyrrole system for the extraction of LiCl from natural brine (2016) J. Electrochem. Soc., 163, pp. A1898-A1902
  • Marchini, F., Calvo, E.J., Method and Electrochemial Device for Low Environmental Impact Lithium Reovery from Aqueous Solutions (2014), US 2014/0076734 A1; Parant, J.P., Olazcuaga, R., Devalette, M., Fouassier, C., Hagenmuller, P., Sur quelques nouvelles phases de formule NaxMnO2 (x ≤ 1) (1971) J. Solid State Chem., 3, pp. 1-11
  • Tarascon, J.M., Guyomard, D.G., Wilkens, B., Mc Kinnon, W.R., Barboux, P., Chemical and electrochemical insertion of Na into the spinel λLi1-XMm2O4 (x 0)phase (1992) Solid State Ionics, 57, pp. 113-120
  • Tang, D., Ben, L., Sun, Y., Chen, B., Yang, Z., Gu, L., Huang, X., Electrochemical behavior and surface structural change of LiMn 2 O 4 charged to 5.1 V (2014) J. Mater. Chem. A, 2, pp. 14519-14527
  • Marchini, F., Rubi, D., Del Pozo, M., Williams, F.J., Calvo, E.J., Surface chemistry and lithium-ion exchange in LiMn2O4 for the electrochemical selective extraction of LiCl from natural salt lake brines (2016) J. Phys. Chem. C, 120
  • Marchini, F., Williams, F.J., Calvo, E.J., Electrochemical impedance spectroscopy study of the Li1-xMn2O4 interface with natural brine (2017) Electroanal. Chem., , (In press)
  • Björk, H., Gustafsson, T., Thomas, J.O., Lidin, S., Petříček, V., Long-range ordering during delithiation of LiMn2O4 cathode material (2003) J. Mater. Chem., 13, pp. 585-589
  • Cerrato, J.M., Hochella, M.F., Knocke, W.R., Dietrich, A.M., Cromer, T.F., Use of XPS to identify the oxidation state of Mn in solid surfaces of filtration media oxide samples from drinking water treatment plants (2010) Environ. Sci. Technol., 44, pp. 5881-5886
  • Kochur, A.G., Kozakov, A.T., Nikolskii, A.V., Googlev, K.A., Pavlenko, A.V., Verbenko, I.A., Reznichenko, L.A., Krasnenko, T.I., Valence state of the manganese ions in mixed-valence La1−αBiβMn1+δO3±γ ceramics by Mn 2p and Mn 3s X-ray photoelectron spectra (2012) J. Electron. Spectrosc. Relat. Phenom., 185, pp. 175-183
  • Eriksson, T., Andersson, A.M., Bishop, A.G., Gejke, C., Gustafsson, T., Thomas, J.O., Surface analysis of LiMn2O4 electrodes in carbonate-based electrolytes (2002) J. Electrochem. Soc., 149, p. A69
  • Oku, M., Hirokawa, K., Ikeda, S., X-ray photoelectron spectroscopy of manganese-oxygen systems (1975) J. Electron. Spectrosc. Relat. Phenom., 7, pp. 465-473
  • David, W.I.F., Thackeray, M.M., De Picciotto, L.A., Goodenough, J.B., Structure refinement of the spinel-related phases Li2Mn2O4 and Li0.2Mn2O4 (1987) J. Solid State Chem., 67, pp. 316-323
  • Rougier, E.C.A., Striebel, K.A., Wen, S.J., Cyclic voltammetry of pulsed laser deposited LixMn2O4 thin films (1998) J. Electrochem. Soc., 145, p. 2975
  • Shokoohi, F.K., Low temperature LiMn2O4 spinel films for secondary lithium batteries (1992) J. Electrochem. Soc., 139, p. 1845
  • Ohzuku, T., Kitagawa, M., Hirai, T., Electrochemistry of manganese dioxide in lithium nonaqueous cell (1990) J. Electrochem. Soc., 137, p. 769
  • Yang, X.Q., Sun, X., Lee, S.J., McBreen, J., Mukerjee, S., Daroux, M.L., Xing, X.K., In situ synchrotron X-ray diffraction studies of the phase transitions in LixMn2O4 cathode materials (1999) Electrochem. Solid State Lett., 2, p. 157
  • Kanamura, K., Naito, H., Yao, T., Takehara, Z., Structural change of the LiMn2O4 spinel structure induced by extraction of lithium (1996) J. Mater. Chem., 6, p. 33
  • Björk, H., Gustafsson, T., Thomas, J.O., Single-crystal studies of electrochemically delithiated LiMn2O4 (2001) Electrochem. Commun., 3, pp. 187-190
  • Hunter, J.C., Preparation of a new crystal form of manganese dioxide: λ-MnO2 (1981) J. Solid State Chem., 39, pp. 142-147

Citas:

---------- APA ----------
Marchini, F., Calvo, E.J. & Williams, F.J. (2018) . Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions. Electrochimica Acta, 269, 706-713.
http://dx.doi.org/10.1016/j.electacta.2018.02.108
---------- CHICAGO ----------
Marchini, F., Calvo, E.J., Williams, F.J. "Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions" . Electrochimica Acta 269 (2018) : 706-713.
http://dx.doi.org/10.1016/j.electacta.2018.02.108
---------- MLA ----------
Marchini, F., Calvo, E.J., Williams, F.J. "Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions" . Electrochimica Acta, vol. 269, 2018, pp. 706-713.
http://dx.doi.org/10.1016/j.electacta.2018.02.108
---------- VANCOUVER ----------
Marchini, F., Calvo, E.J., Williams, F.J. Effect of the electrode potential on the surface composition and crystal structure of LiMn2O4 in aqueous solutions. Electrochim Acta. 2018;269:706-713.
http://dx.doi.org/10.1016/j.electacta.2018.02.108