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Abstract:

Nickel catalysts were characterized for the hydrogen evolution reaction (HER) using rotating disk electrode (RDE) and electrochemical impedance spectroscopy (EIS). The theoretical Levich slope was calculated on the basis of the HER mechanism in alkaline solution. Kinetic and thermodynamic parameters of the reaction were obtained for fresh polished nickel electrode (Nif), and for nickel after a quick chronoamperometric aging procedure (Nipc). Koutecky-Levich analysis indicated that the rate determining step on Nif is the one-electron Volmer reaction, while for Nipc decreases from one to 0.68 and exhibits a strong temperature dependence. A loss of catalytic activity, corresponding to an increase of 0.3 V of the HER onset potential, was observed after aging. Furthermore, from the EIS-Tafel analysis we concluded that the H adsorption changes from a Langmuir type for Nif, to a Temkin type for Nipc. © 2015 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Kinetics of the hydrogen evolution on nickel in alkaline solution: New insight from rotating disk electrode and impedance spectroscopy analysis
Autor:Franceschini, E.A.; Lacconi, G.I.; Corti, H.R.
Filiación:Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499 (B1650KNA) San Martín, Buenos Aires, Argentina
Dto. de Fisicoquímica - Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba, 5000, Argentina
Departamento de Química Inorgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Buenos Aires, C1428EHA, Argentina
Palabras clave:Ageing; Electrode Electrochemical Impedance; Hydrogen Evolution; Nickel; Rotating Disk; Catalyst activity; Catalysts; Electrochemical electrodes; Electrochemical impedance spectroscopy; Electrodes; Hydrogen; Nickel; Spectroscopy; Temperature distribution; Ageing; Electrochemical impedance; Hydrogen evolution; Hydrogen evolution reactions; Impedance spectroscopy; Kinetic and thermodynamic parameters; Rotating disk electrodes; Temperature dependence; Rotating disks
Año:2015
Volumen:159
Página de inicio:210
Página de fin:218
DOI: http://dx.doi.org/10.1016/j.electacta.2015.01.110
Título revista:Electrochimica Acta
Título revista abreviado:Electrochim Acta
ISSN:00134686
CODEN:ELCAA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134686_v159_n_p210_Franceschini

Referencias:

  • Miao, Y., Ouyang, L., Zhou, S., Xu, L., Yang, Z., Xiao, M., Ouyang, R., Electrocatalysis and electroanalysis of nickel, its oxides, hydroxides and oxyhydroxides toward small molecules (2014) Biosens. Bioelectron., 53, pp. 428-439
  • Quaino, P.M., Gennero De Chialvo, M.R., Chialvo, A.C., Hydrogen electrode reaction: A complete kinetic description (2007) Electrochim. Acta, 52, pp. 7396-7403
  • Petrov, Y., Schosger, J.-P., Stoynov, Z., De Bruijn, F., Hydrogen evolution on nickel electrode in synthetic tap water-alkaline solution (2011) Int. J. Hydrogen Energ., 36, pp. 12715-12724
  • Lacnjevac, U.C., Jovic, B.M., Jovic, V.D., Krstajic, N.V., Determination of kinetic parameters for the hydrogen evolution reaction on the electrodeposited Ni-MoO2 composite coating in alkaline solution (2012) J. Electroanal. Chem., 31, pp. 677-680
  • Bai, L., Harrington, D.A., Conway, B.E., Behavior of overpotential - Deposited species in Faradaic reactions - II. Ac Impedance measurements on H2 evolution kinetics at activated and unactivated Pt cathodes (1987) Electrochim. Acta, 32, pp. 1713-1731
  • Hall, D.E., Porous Nickel-Coated Steel Anodes for Alkaline Water Electrolysis: Corrosion Resistance (1982) J. Electrochem. Soc.: Electrochem. Sci. Technol., 129, pp. 310-315
  • Graves, C., Ebbesen, S.D., Mogensen, M., Lackner, K.S., Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy (2011) Renew. Sustain. Energy Rev., 15, pp. 1-23
  • Gahleitner, G., Hydrogen from renewable electricity: An international review of power-to-gas pilot plants for stationary applications (2013) Int. J. Hydrogen Energ., 38, pp. 2039-2061
  • Losiewicz, B., Budniok, A., Rowinski, E., Lagiewka, E., Lasia, A., The structure, morphology and electrochemical impedance study of the hydrogen evolution reaction on the modified nickel electrodes (2004) Int. J. Hydrogen Energ., 29, pp. 145-157
  • Harrington, D.A., Conway, B.E., A.C. Impedance of Faradaic Reactions Involving Electrosorbed Intermediates; Part I: Kinetic Theory (1987) Electrochim. Acta, 3212, pp. 1703-1712
  • Kreysa, G., Hakansson, B., Ekdunge, P., Kinetic and thermodynamic analysis of hydrogen evolution at nickel electrodes (1988) Electrochim. Acta, 33, pp. 1351-1357
  • Wendt, V., Plzak, H., Electrocatalytic and thermal activation of anodic oxygen- and cathodic hydrogen-evolution in alkaline water electrolysis (1983) Electrochim. Acta, 28, pp. 27-34
  • Appleby, A.J., Chemla, M., Kita, H., Bronoel, G., (1982) Encyclopedia of Electrochemistry of the Elements, , N.Y. Bard, Marcel Dekker NY, USA
  • Jacquelin, J., Appleby, A.J., Nouvelles perspectives dansl'électrolyse de l'eau (1976) Rev. Generalel'Electricite, 85, pp. 551-554
  • Kreysa, G., Hakansson, B., Electrocatalysis by amorphous metals of hydrogen and oxygen evolution in alkaline solution (1986) J. Electroanal. Chem., 201, pp. 61-83
  • Lacnjevac, U.C., Jovic, B.M., Jovic, V.D., Radmilovic, V.R., Krstajic, N.V., Kinetics of the hydrogen evolution reaction on Ni-(Ebonex-supported Ru) composite coatings in alkaline solution (2013) Int. J. Hydrogen Energ., 38, pp. 10178-10190
  • Vázquez-Gómez, L., Cattarin, S., Guerriero, P., Musiani, M., Influence of deposition current density on the composition and properties of electrodeposited Ni + RuO2 and Ni + IrO2 composites (2009) J. Electroanal. Chem., 634, pp. 42-48
  • Vázquez-Gómez, L., Cattarin, S., Guerriero, P., Musiani, M., Hydrogen evolution on porous Ni cathodes modified by spontaneous deposition of Ru or Ir (2008) Electrochim. Acta, 53, pp. 8310-8318
  • Dominguez-Crespo, M.A., Ramírez-Meneses, E., Torres-Huerta, A.M., Garibay-Febles, V., Philippot, K., Kinetics of hydrogen evolution reaction on stabilized Ni, Pt and Ni-Pt nanoparticles obtained by an organometallic approach (2012) Int. J. Hydrogen Energ., 37, pp. 4798-4811
  • Abouatallah, R.M., Kirk, D.W., Thorpe, S.J., Graydon, J.W., Reactivation of nickel cathodes by dissolved vanadium species during hydrogen evolution in alkaline media (2001) Electrochim. Acta, 47, pp. 613-621
  • Machado, S.A.S., Tiengo, J., De Lima Neto, P., Avaca, L.A., The influence of H-absorption on the cathodic response of high area nickel electrodes in alkaline solutions (1994) Electrochim. Acta, 39, pp. 1757-1761
  • Rommal, H.E.G., Morgan, P.J., The role of absorbed hydrogen on the voltage-time behavior of nickel cathodes in hydrogen evolution (1988) J. Electrochem. Soc., 135, pp. 343-346
  • Rommal, H.E.G., Moran, P.J., Time-dependent energy efficiency losses at nickel cathodes in alkaline water electrolysis systems (1985) J. Electrochem.Soc., 132, pp. 325-329
  • Soares, D.M., Teschke, O., Torriani, I., Hydride effect on the kinetics of the hydrogen evolution reaction on nickel cathodes in alkaline media (1992) J. Electrochem. Soc., 139, pp. 98-105
  • Makrides, A.C., Hydrogen overpotential on nickel in alkaline solution (1962) J. Electrochem. Soc., 109, pp. 977-984
  • Machado, S.A.S., Avaca, L.A., The hydrogen evolution reaction on nickel surfaces stabilized by H-absorption (1994) Electrochim. Acta, 39, pp. 1385-1391
  • Hall, D.S., Bock, C., Macdougall, B.R., The electrochemistry of metallic nickel: Oxides, hydroxides, hydrides and alkaline hydrogen evolution (2013) J. Electrochem. Soc., 160, pp. F235-F243
  • Rodríguez-Carvajal, J., Recent Advances in Magnetic Structure Determination by Neutron Powder Diffraction (1993) Physica B, 192, pp. 55-69
  • Franceschini, E.A., Bruno, M.M., Viva, F.A., Williams, F.J., Jobbágy, M., Corti, H.R., Mesoporous Pt electrocatalyst for methanol tolerant cathodes of DMFC (2012) Electrochim. Acta, 71, pp. 173-180
  • Haynes, W.M., (2013) CRC Handbook of Chemistry and Physics, , 94th Edition CRC Press
  • Damjanovic, A., Temperature dependence of symmetry factors and the significance of experimental activation energies (1993) J. Electroanal. Chem., 355, pp. 57-77
  • Suarez-Alcantara, K., Solorza-Feria, O., Kinetics and PEMFC performance of RuxMoySez nanoparticles as a cathode catalyst (2008) Electrochim. Acta, 53, pp. 4981-4989
  • Bianchi, I., Guerrini, E., Trasatti, S., Electrocatalytic activation of Ni for H2 evolution by spontaneous deposition of Ru (2005) Chemical Physics, 319, pp. 192-199
  • Ukic, A., Alar, V., Firak, M., Jakovljevic, S., A significant improvement in material of foam (2013) J. Alloy. Compd., 573, pp. 128-132
  • Krstajic, N., Popovic, M., Grgur, B., Vojnovic, M., Sepa, D., On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution - Part I. The mechanism (2001) J. Electroanal. Chem., 512, pp. 16-26
  • Sotelo-Mazón, P., González-Huerta, R.G., Cabañas-Moreno, J.G., Solorza-Feria, O., Mechanically milled RuxFey Electrocatalyst for Oxygen Reduction in acid media (2007) Int. J. Electrochem. Sci., 2, pp. 523-533
  • Krstajic, N., Popovic, M., Grgur, B., Vojnovic, M., Sepa, D., On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution - Part II. Effect of temperature (2001) J. Electroanal. Chem., 512, pp. 27-35
  • Suarez-Alcantara, K., Solorza-Feria, O., Evaluation of RuxWySez Catalyst as a Cathode Electrode in a Polymer Electrolyte Membrane Fuel Cell (2010) Fuel Cells, 10, pp. 84-92
  • Conway, B.E., Tessier, D.F., Wilkinson, D.P., Temperature dependence of the Tafel slope and electrochemical barrier symmetry factor beta, in electrode kinetics (1989) J. Electroanal. Chem., 136, pp. 2486-2492
  • Armstrong, R.D., Henderson, M., Impedance plane display of a reaction with an adsorbed intermediate (1972) J. Electroanal. Chem., 39, pp. 81-90
  • Bai, L., Harrington, D.A., Conway, B.E., Behaviour of Overpotential-Deposited Species in Faradaic Reactions - Part II.A.C. Impedance Measurements on H2 Evolution Kinetics at Activated and Unactivated Pt Cathodes (1987) Electrochim. Acta, 32, pp. 1713-1731

Citas:

---------- APA ----------
Franceschini, E.A., Lacconi, G.I. & Corti, H.R. (2015) . Kinetics of the hydrogen evolution on nickel in alkaline solution: New insight from rotating disk electrode and impedance spectroscopy analysis. Electrochimica Acta, 159, 210-218.
http://dx.doi.org/10.1016/j.electacta.2015.01.110
---------- CHICAGO ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of the hydrogen evolution on nickel in alkaline solution: New insight from rotating disk electrode and impedance spectroscopy analysis" . Electrochimica Acta 159 (2015) : 210-218.
http://dx.doi.org/10.1016/j.electacta.2015.01.110
---------- MLA ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of the hydrogen evolution on nickel in alkaline solution: New insight from rotating disk electrode and impedance spectroscopy analysis" . Electrochimica Acta, vol. 159, 2015, pp. 210-218.
http://dx.doi.org/10.1016/j.electacta.2015.01.110
---------- VANCOUVER ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. Kinetics of the hydrogen evolution on nickel in alkaline solution: New insight from rotating disk electrode and impedance spectroscopy analysis. Electrochim Acta. 2015;159:210-218.
http://dx.doi.org/10.1016/j.electacta.2015.01.110