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Abstract:

Soluble iron phtalocyanine (FePc) has been studied as a bifunctional catalyst for the oxygen reduction reaction (ORR) and oxygen evolution (OER) in lithium air cathodes by means of electrogravimetry with shear wave dissipation, cyclic voltammetry (CV) and rotating ring disk electrode (RRDE). The oxygen reduction reaction (ORR) has been studied on Au in oxygen saturated TBA-PF6 in DMSO and LiTFSI-DMSO electrolyte for increasing concentration of Fe-phtalocyanine as redox mediator for the two-electron ORR at 2.2 V and the oxidation of the surface Li2O2 product below 3.6 V vs. Li/Li+ where the solvent is stable. The soluble FePc catalyst promotes the ORR solution phase mechanism. © 2017 The Electrochemical Society. All rights reserved.

Registro:

Documento: Artículo
Título:EQCM and RDE/RRDE study of soluble iron phthalocyanine bifunctional catalyst for the lithium-oxygen battery
Autor:Torres, W.R.; Davia, F.; Del Pozo, M.; Tesio, A.Y.; Calvoz, E.J.
Filiación:INQUIMAE-CONICET-Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:Catalysts; Cyclic voltammetry; Electric batteries; Electrodes; Electrolytes; Electrolytic reduction; Lithium; Lithium batteries; Lithium compounds; Shear flow; Shear waves; Bi-functional catalysts; Concentration of fe; Lithium-oxygen batteries; Oxygen evolution; Oxygen reduction reaction; Redox mediators; Rotating ring-disk electrode; Wave dissipation; Oxygen
Año:2017
Volumen:164
Número:14
Página de inicio:A3785
Página de fin:A3792
DOI: http://dx.doi.org/10.1149/2.1441714jes
Título revista:Journal of the Electrochemical Society
Título revista abreviado:J Electrochem Soc
ISSN:00134651
CODEN:JESOA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v164_n14_pA3785_Torres

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Citas:

---------- APA ----------
Torres, W.R., Davia, F., Del Pozo, M., Tesio, A.Y. & Calvoz, E.J. (2017) . EQCM and RDE/RRDE study of soluble iron phthalocyanine bifunctional catalyst for the lithium-oxygen battery. Journal of the Electrochemical Society, 164(14), A3785-A3792.
http://dx.doi.org/10.1149/2.1441714jes
---------- CHICAGO ----------
Torres, W.R., Davia, F., Del Pozo, M., Tesio, A.Y., Calvoz, E.J. "EQCM and RDE/RRDE study of soluble iron phthalocyanine bifunctional catalyst for the lithium-oxygen battery" . Journal of the Electrochemical Society 164, no. 14 (2017) : A3785-A3792.
http://dx.doi.org/10.1149/2.1441714jes
---------- MLA ----------
Torres, W.R., Davia, F., Del Pozo, M., Tesio, A.Y., Calvoz, E.J. "EQCM and RDE/RRDE study of soluble iron phthalocyanine bifunctional catalyst for the lithium-oxygen battery" . Journal of the Electrochemical Society, vol. 164, no. 14, 2017, pp. A3785-A3792.
http://dx.doi.org/10.1149/2.1441714jes
---------- VANCOUVER ----------
Torres, W.R., Davia, F., Del Pozo, M., Tesio, A.Y., Calvoz, E.J. EQCM and RDE/RRDE study of soluble iron phthalocyanine bifunctional catalyst for the lithium-oxygen battery. J Electrochem Soc. 2017;164(14):A3785-A3792.
http://dx.doi.org/10.1149/2.1441714jes