Artículo
Mozhzhukhina, N.; Calvo, E.J. "The correct assessment of standard potentials of reference electrodes in non-aqueous solution" (2017) Journal of the Electrochemical Society. 164(12):A2295-A2297
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Abstract:
The challenges facing metal-air batteries have prompted fundamental studies of non-aqueous electrochemistry. However it appears that contributors in the field are not aware that the potentials of Li/Li+, Na/Na+, K/K+, and Mg/Mg2+ electrodes depend on the nature of solvent due to the cation solvation. Therefore, it is imperative to define a clear potential scale that can be correlated in different solvents. Here we report on the strong effect of the solvent on the Li/Li+ redox potential and discuss the use of the ferrocene/ferrocenium couple as internal or external standard for the measurements in non-aqueous solvents in lithium-ion and lithium-02 battery systems. © The Author(s) 2017. Published by ECS. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | The correct assessment of standard potentials of reference electrodes in non-aqueous solution |
| Autor: | Mozhzhukhina, N.; Calvo, E.J. |
| Filiación: | INQUIMAE-CONICET-Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires, 1428, Argentina |
| Palabras clave: | Electric batteries; Electrodes; Iron compounds; Lithium; Lithium-ion batteries; Organometallics; Redox reactions; Secondary batteries; Solutions; Different solvents; External standards; Fundamental studies; Metal-air battery; Non-aqueous solvents; Nonaqueous solutions; Reference electrodes; Standard potential; Solvents |
| Año: | 2017 |
| Volumen: | 164 |
| Número: | 12 |
| Página de inicio: | A2295 |
| Página de fin: | A2297 |
| DOI: | http://dx.doi.org/10.1149/2.0341712jes |
| Título revista: | Journal of the Electrochemical Society |
| Título revista abreviado: | J Electrochem Soc |
| ISSN: | 00134651 |
| CODEN: | JESOA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v164_n12_pA2295_Mozhzhukhina |
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Citas:
---------- APA ----------
Mozhzhukhina, N. & Calvo, E.J. (2017) . The correct assessment of standard potentials of reference electrodes in non-aqueous solution. Journal of the Electrochemical Society, 164(12), A2295-A2297.http://dx.doi.org/10.1149/2.0341712jes
---------- CHICAGO ----------
Mozhzhukhina, N., Calvo, E.J. "The correct assessment of standard potentials of reference electrodes in non-aqueous solution" . Journal of the Electrochemical Society 164, no. 12 (2017) : A2295-A2297.http://dx.doi.org/10.1149/2.0341712jes
---------- MLA ----------
Mozhzhukhina, N., Calvo, E.J. "The correct assessment of standard potentials of reference electrodes in non-aqueous solution" . Journal of the Electrochemical Society, vol. 164, no. 12, 2017, pp. A2295-A2297.http://dx.doi.org/10.1149/2.0341712jes
---------- VANCOUVER ----------
Mozhzhukhina, N., Calvo, E.J. The correct assessment of standard potentials of reference electrodes in non-aqueous solution. J Electrochem Soc. 2017;164(12):A2295-A2297.http://dx.doi.org/10.1149/2.0341712jes
