Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

A highly selective LiMn2 O4 -Polypyrrole electrochemical cell for the extraction of LiCl from natural brine is described. Reproducible intercalation of Li+ in Lix Mn2 O4 (0 ≤ x ≤ 1) and Cl- in oxidized polypyrrole (PPy+) is achieved with an overall cell voltage of less 1 V over more than 200 cycles with 50% charge efficiency and 5-10 Wh.mol-1 energy consumption. No insertion of Na+ has been observed. © 2016 The Electrochemical Society.

Registro:

Documento: Artículo
Título:A LiMn2 O4 -Polypyrrole system for the extraction of LiCl from natural brine
Autor:Missoni, L.L.; Marchini, F.; Pozo, M.D.; Calvo, E.J.
Filiación:INQUIMAE, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, AR-1428, Argentina
Palabras clave:Energy utilization; Extraction; Manganese; Cell voltages; Charge efficiency; Polypyrroles
Año:2016
Volumen:163
Número:9
Página de inicio:A1898
Página de fin:A1902
DOI: http://dx.doi.org/10.1149/2.0591609jes
Título revista:Journal of the Electrochemical Society
Título revista abreviado:J Electrochem Soc
ISSN:00134651
CODEN:JESOA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v163_n9_pA1898_Missoni

Referencias:

  • Kanoh, H., Ooi, K., Miyai, Y., Katoh, S., (1991) Langmuir, 7, p. 1841
  • Kanoh, H., Ooi, K., Miyai, Y., Katoh, S., (1993) Separation Science and Technology, 28, p. 643
  • Kanoh, H., Feng, Q., Hirotsu, T., Ooi, K., (1996) Journal of the Electrochemical Society, 143, p. 2610
  • Kanoh, H., Feng, Q., Miyai, Y., Ooi, K., (1995) Journal of the Electrochemical Society, 142, p. 702
  • Pasta, M., Battistel, A., La, F., Mantia, (2012) Energy and Environmental Science, 5, p. 9487
  • Trocoli, R., Battistel, A., Mantia, F.L., (2014) Chemistry-a European Journal, 20, p. 9888
  • Mantia, F.L., Pasta, M., Battistel, A., Recovering lithium salts from salt solutions, comprises immerisng a lithium-intercalating positive electrode and an anion capturing electrode in a lilthium-containing salt solution, and replacding the salt solution by a recovery solution, in, Ruhr Universitaet Bochum (2014) Germany
  • Lee, J., Kim, S., Kim, C., Yoon, J., (2014) Energy & Environmental Science, 7, p. 3683
  • Kim, S., Lee, J., Kang, J.S., Jo, K., Kim, S., Sung, Y.-E., Yoon, J., (2015) Chemosphere, 125, p. 50
  • Kim, J.S., Lee, Y.H., Choi, S., Shin, J., Dinh, H.C., Choi, J.W., (2015) Environmental Science and Technology, 49, p. 9415
  • Hoshino, T., (2013) Fusion Engineering and Design, 88, p. 2956
  • Hoshino, T., (2013) ECS Transactions, p. 173
  • Intaranont, N., Garcia-Araez, N., Hector, A.L., Milton, J.A., Owen, J.R., (2014) Journal of Materials Chemistry A, 2, p. 6374
  • Liu, X., Chen, X., Zhao, Z., Liang, X., (2014) Hydrometallurgy, 146, p. 24
  • Marchini, F., Rubi, D., Pozo, M.D., Williams, F.J., Calvo, E.J., (2016) Journal of Physical Chemistry c, 31 (33), p. 9236
  • Guyomard, D., Tarascon, J.M., (1993) Journal of the Electrochemical Society, 140, p. 3071
  • Tarascon, J.M., Guyomard, D., (1991) Journal of the Electrochemical Society, 138, p. 2864
  • Rossouw, M., De Kock, A., De Picciotto, L., Thackeray, M., David, W., Ibberson, R., (1990) Materials Research Bulletin, 25, p. 173
  • Ooi, K., Miyai, Y., Katoh, S., Maeda, H., Abe, M., (1989) Langmuir, 5, p. 150
  • Doblhofer, K., Rajeshwar, K., (1998) Handbook of Conducting Polymers, p. 5. , T. A. Skotheim, R. l. Elsenbaumer, and J. R. Reynolds Editors Marcel Dekker, New York
  • Feldberg, S.W., (1984) Journal of the American Chemical Society, 106, p. 4671
  • Rougier, A., Striebel, K.A., Wen, S.J., Cairns, E.J., (1998) Journal of the Electrochemical Society, 145, p. 2975
  • Shokoohi, F.K., Tarascon, J.M., Wilkens, B.J., Guyomard, D., Chang, C.C., (1992) Journal of the Electrochemical Society, 139, p. 1845
  • Marchini, F., Herrera, S., Torres, W., Tesio, A.Y., Williams, F.J., Calvo, E.J., (2015) Langmuir, 31, p. 9236
  • Guyomard, D., Tarascon, J.M., (1994) Advanced Materials, 6, p. 408
  • Weidlich, C., Mangold, K.M., Jüttner, K., (2005) Electrochimica Acta, 50, p. 1547
  • Bruckenstein, S., Chen, J., Jureviciute, I., Hillman, A.R., (2009) Electrochimica Acta, 54, p. 3516
  • Yang, L., Frith, J.T., Garcia-Araez, N., Owen, J.R., (2015) Chemical Communications, 51, p. 1705
  • Lee, J., Yu, S.H., Kim, C., Sung, Y.E., Yoon, J., (2013) Physical Chemistry Chemical Physics, 15, p. 7690
  • Yang, X.Q., Sun, X., Lee, S.J., McBreen, J., Mukerjee, S., Daroux, M.L., Xing, X.K., (1999) Electrochemical and Solid State Letters, 2, p. 157

Citas:

---------- APA ----------
Missoni, L.L., Marchini, F., Pozo, M.D. & Calvo, E.J. (2016) . A LiMn2 O4 -Polypyrrole system for the extraction of LiCl from natural brine. Journal of the Electrochemical Society, 163(9), A1898-A1902.
http://dx.doi.org/10.1149/2.0591609jes
---------- CHICAGO ----------
Missoni, L.L., Marchini, F., Pozo, M.D., Calvo, E.J. "A LiMn2 O4 -Polypyrrole system for the extraction of LiCl from natural brine" . Journal of the Electrochemical Society 163, no. 9 (2016) : A1898-A1902.
http://dx.doi.org/10.1149/2.0591609jes
---------- MLA ----------
Missoni, L.L., Marchini, F., Pozo, M.D., Calvo, E.J. "A LiMn2 O4 -Polypyrrole system for the extraction of LiCl from natural brine" . Journal of the Electrochemical Society, vol. 163, no. 9, 2016, pp. A1898-A1902.
http://dx.doi.org/10.1149/2.0591609jes
---------- VANCOUVER ----------
Missoni, L.L., Marchini, F., Pozo, M.D., Calvo, E.J. A LiMn2 O4 -Polypyrrole system for the extraction of LiCl from natural brine. J Electrochem Soc. 2016;163(9):A1898-A1902.
http://dx.doi.org/10.1149/2.0591609jes