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Abstract:

The possible use of Raman spectroscopy for studies of anodic corrosion film formation on Fe-Cr and Fe-Cr-Mo single crystals has been elucidated. The study shows that Raman spectra from passive films (thickness range 5–6 nm) and from “transpassive films” or films grown during secondary passivity (thickness range 5–25 nm) can be detected and interpreted. The results from Raman spectroscopy have been obtained in 1M KOH and combined with complementary results from x-ray photoelectron spectroscopy and nuclear microanalysis. Identified phases in the passive film are a-(Fe, Cr) 2 0 3 and in the transpassive film a-(Fe, Cr) 2 O 3 Fe-Cr spinel, and amorphous FeOOH. © 1988, The Electrochemical Society, Inc. All rights reserved.

Registro:

Documento: Artículo
Título:In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals
Autor:Pallotta, C.; Persson, D.; Leygraf, C.
Filiación:Faculdad de Ciencas Exactas, Ciudad Universitaria, 1428 Nunez, Buenos Aires, Argentina
Swedish Corrosion Institute, S-114 86, Stockholm, Sweden
LP 15 “Physique des Liquides et Electrochimie”, associe à l'Université Pierre et Marie Curie, F-75230, Paris, France
Palabras clave:CORROSION - Thin Films; FILMS - Spectroscopic Analysis; MICROANALYSIS; SPECTROSCOPY, RAMAN - Applications; SPECTROSCOPY, X-RAY - Applications; ANODIZING; METALLIC STATES; NUCLEAR MICROANALYSIS; PASSIVE FILMS; PHOTOELECTRON ANALYZER; IRON CHROMIUM ALLOYS
Año:1988
Volumen:135
Número:2
Página de inicio:305
Página de fin:310
DOI: http://dx.doi.org/10.1149/1.2095605
Título revista:Journal of the Electrochemical Society
Título revista abreviado:J Electrochem Soc
ISSN:00134651
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v135_n2_p305_Pallotta

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Citas:

---------- APA ----------
Pallotta, C., Persson, D. & Leygraf, C. (1988) . In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals. Journal of the Electrochemical Society, 135(2), 305-310.
http://dx.doi.org/10.1149/1.2095605
---------- CHICAGO ----------
Pallotta, C., Persson, D., Leygraf, C. "In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals" . Journal of the Electrochemical Society 135, no. 2 (1988) : 305-310.
http://dx.doi.org/10.1149/1.2095605
---------- MLA ----------
Pallotta, C., Persson, D., Leygraf, C. "In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals" . Journal of the Electrochemical Society, vol. 135, no. 2, 1988, pp. 305-310.
http://dx.doi.org/10.1149/1.2095605
---------- VANCOUVER ----------
Pallotta, C., Persson, D., Leygraf, C. In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals. J Electrochem Soc. 1988;135(2):305-310.
http://dx.doi.org/10.1149/1.2095605