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Abstract:

In this report we provide a theoretical support for the existence of nonclassical 3-center bonding recently invoked to explain the structure of protonated phosphorus and arsenic X 4 H + clusters.For this purpose the electron structure of these clusters was analysed using the formalism of the generalized population analysis, in terms of which the eventual presence of multicenter bonds in a molecule can be directly detected and localized. Our results confirm the presence of 3-center bonding involving X-H-X fragments in these clusters.

Registro:

Documento: Artículo
Título:Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis
Autor:Bochicchio, R.; Lain, L.; Torre, A.; Ponec, R.
Filiación:Departamento de Fisica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Departamento de Quimica Fisica, Facultad de Ciencias, Universidad del Pais Vasco, Apdo. 644, E-48080, Bilbao, Spain
Inst. of Chem. Process Fundamentals, Czech Academy of Sciences, Prague 6- Suchdol, Czech Republic
Palabras clave:3-center bonding; Arsenic clusters; Phosphorus clusters
Año:2000
Volumen:73
Número:4
Página de inicio:1039
Página de fin:1046
Título revista:Croatica Chemica Acta
Título revista abreviado:Croat. Chem. Acta
ISSN:00111643
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00111643_v73_n4_p1039_Bochicchio

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Citas:

---------- APA ----------
Bochicchio, R., Lain, L., Torre, A. & Ponec, R. (2000) . Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis. Croatica Chemica Acta, 73(4), 1039-1046.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00111643_v73_n4_p1039_Bochicchio [ ]
---------- CHICAGO ----------
Bochicchio, R., Lain, L., Torre, A., Ponec, R. "Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis" . Croatica Chemica Acta 73, no. 4 (2000) : 1039-1046.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00111643_v73_n4_p1039_Bochicchio [ ]
---------- MLA ----------
Bochicchio, R., Lain, L., Torre, A., Ponec, R. "Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis" . Croatica Chemica Acta, vol. 73, no. 4, 2000, pp. 1039-1046.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00111643_v73_n4_p1039_Bochicchio [ ]
---------- VANCOUVER ----------
Bochicchio, R., Lain, L., Torre, A., Ponec, R. Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis. Croat. Chem. Acta. 2000;73(4):1039-1046.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00111643_v73_n4_p1039_Bochicchio [ ]