Abstract:
We report a modified simulation procedure to calculate partial molar quantities of dilute solutions in supercritical fluids through the Krichevskii function. This procedure circumvents the difficulties posed by the very large solvent compressibility and expansivity in the near-critical region of the solutions where other simulation procedures cannot be used. © 2003 Elsevier B.V. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Standard thermodynamic properties of solutes in supercritical solvents: Simulation and theory |
Autor: | Alvarez, J.L.; Fernández-Prini, R.; Marceca, E. |
Filiación: | Unidad Actividad Química, Comn. Nac. Ener. Atómica, Av. Libertador 8250, Buenos Aires, Argentina INQUIMAE, Fac. Ciencias Exactas y Naturales, Pabellón II, Buenos Aires, Argentina Dto. Ing. Química, FRBA, Univ. Tecnológica Nacional, Medrano 951, Buenos Aires, Argentina
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Palabras clave: | solvent; aqueous solution; article; calculation; physical chemistry; simulation; solute; standard; supercritical fluid; theory; thermodynamics |
Año: | 2003
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Volumen: | 381
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Número: | 5-6
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Página de inicio: | 771
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Página de fin: | 776
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DOI: |
http://dx.doi.org/10.1016/j.cplett.2003.10.050 |
Título revista: | Chemical Physics Letters
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Título revista abreviado: | Chem. Phys. Lett.
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ISSN: | 00092614
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CODEN: | CHPLB
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v381_n5-6_p771_Alvarez |
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Citas:
---------- APA ----------
Alvarez, J.L., Fernández-Prini, R. & Marceca, E.
(2003)
. Standard thermodynamic properties of solutes in supercritical solvents: Simulation and theory. Chemical Physics Letters, 381(5-6), 771-776.
http://dx.doi.org/10.1016/j.cplett.2003.10.050---------- CHICAGO ----------
Alvarez, J.L., Fernández-Prini, R., Marceca, E.
"Standard thermodynamic properties of solutes in supercritical solvents: Simulation and theory"
. Chemical Physics Letters 381, no. 5-6
(2003) : 771-776.
http://dx.doi.org/10.1016/j.cplett.2003.10.050---------- MLA ----------
Alvarez, J.L., Fernández-Prini, R., Marceca, E.
"Standard thermodynamic properties of solutes in supercritical solvents: Simulation and theory"
. Chemical Physics Letters, vol. 381, no. 5-6, 2003, pp. 771-776.
http://dx.doi.org/10.1016/j.cplett.2003.10.050---------- VANCOUVER ----------
Alvarez, J.L., Fernández-Prini, R., Marceca, E. Standard thermodynamic properties of solutes in supercritical solvents: Simulation and theory. Chem. Phys. Lett. 2003;381(5-6):771-776.
http://dx.doi.org/10.1016/j.cplett.2003.10.050