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Abstract:

Inner projections of the polarization propagator were used to study the indirect through-space transmission of the Fermi contact term of CF couplings via a CX (X = F, H) intermediate bond. When X = H a large capability for transmitting this component is observed. But for X = F a notable inhibition of this transmission mechanism is observed. The role of the fluorine lone pairs in this behaviour is discussed. © 1984.

Registro:

Documento: Artículo
Título:The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
Autor:Natiello, M.A.; Contreras, R.H.
Filiación:Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon 1, 1428 Buenos Aires, Argentina
Año:1984
Volumen:104
Número:6
Página de inicio:568
Página de fin:571
DOI: http://dx.doi.org/10.1016/0009-2614(84)80028-7
Título revista:Chemical Physics Letters
Título revista abreviado:Chem. Phys. Lett.
ISSN:00092614
CODEN:CHPLB
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v104_n6_p568_Natiello

Referencias:

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Citas:

---------- APA ----------
Natiello, M.A. & Contreras, R.H. (1984) . The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis. Chemical Physics Letters, 104(6), 568-571.
http://dx.doi.org/10.1016/0009-2614(84)80028-7
---------- CHICAGO ----------
Natiello, M.A., Contreras, R.H. "The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis" . Chemical Physics Letters 104, no. 6 (1984) : 568-571.
http://dx.doi.org/10.1016/0009-2614(84)80028-7
---------- MLA ----------
Natiello, M.A., Contreras, R.H. "The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis" . Chemical Physics Letters, vol. 104, no. 6, 1984, pp. 568-571.
http://dx.doi.org/10.1016/0009-2614(84)80028-7
---------- VANCOUVER ----------
Natiello, M.A., Contreras, R.H. The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis. Chem. Phys. Lett. 1984;104(6):568-571.
http://dx.doi.org/10.1016/0009-2614(84)80028-7