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Abstract:

An alkali-soluble glucan, [α]D + 11° (M potassium hydroxide) having a degree of polymerization of 220, has been isolated from the fruit bodies of the tree fungus Cyttaria harioti Fischer. Periodate oxidation and methylation analysis show that it consists of a highly branched β-D-(1→3)-linked backbone. Hydrolysis of the methylated polysaccharide yielded 2,3,4,6-tetra-O-methyl- (24.5 mol%), 2,4,6-tri-O-methyl-(39.4 mol%), 2,3,4-tri-O-methyl- (8.6 mol%), and 2,4-di-O-methyl-D-glucose (27.5 mol%). Periodate-oxidation results substantiate the methylation studies. The general structural features of the glucan are discussed. © 1976.

Registro:

Documento: Artículo
Título:A gel-forming (1→3)-β-D-glucan isolated from cyttaria harioti fischer
Autor:Fernandez Cirelli, A.; de Lederkremer, R.M.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Año:1976
Volumen:48
Número:2
Página de inicio:217
Página de fin:223
DOI: http://dx.doi.org/10.1016/S0008-6215(00)83217-6
Título revista:Carbohydrate Research
Título revista abreviado:Carbohydr. Res.
ISSN:00086215
CODEN:CRBRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v48_n2_p217_FernandezCirelli

Referencias:

  • Fernández Cirelli, de Lederkremer, (1971) Chem. Ind. (London), pp. 1139-1139
  • Fernandez Cirelli, de Lederkremer, (1972) Anales Asoc. Quim. Argentina, 60, pp. 299-308
  • Fernández Cirelli, de Lederkremer, (1974) Anales Asoc. Quim. Argentina, 62, pp. 141-145
  • Gamundi, (1971) De Darwiniana, 16, pp. 461-510
  • Whistler, BeMiller, (1956) J. Am. Chem. Soc., 78, pp. 1163-1165
  • Barker, Bourne, Stacey, Whiffen, Infra-red spectra of carbohydrates. Part I. Some derivatives of D-glucopyranose (1954) Journal of the Chemical Society (Resumed), pp. 171-176
  • Weygand, Perkom, Kuhner, ÜberN-Glykoside, VII. Mitteil.:p-Nitranilin-glykoside und eine Synthese von Gentiobiose ausp-Nitranilin-N-glucosid (1951) Chemische Berichte, 84, pp. 594-602
  • Unrau, Smith, (1957) Chem. Ind. (London), pp. 330-331
  • Goldstein, Hay, Lewis, Smith, (1965) Methods Carbohydr. Chem., 5, pp. 361-370
  • Hakomori, (1964) J. Biochem. (Tokyo), 55, pp. 205-208
  • Purdie, Irvine, (1903) J. Chem. Soc., 83, pp. 1021-1037
  • Croon, Herrström, Kull, Lindberg, Demethylation and Degradation of Sugars in Acid Hydrolysis. (1960) Acta Chemica Scandinavica, 14, pp. 1338-1342
  • Gorin, Spencer, (1968) Advan. Carbohyd. Chem., 23, pp. 367-417
  • Axelsson, Björndal, Eriksson, An Extracellular Glucan Produced by the Rot Fungus Stereum sanguinolentum. (1968) Acta Chemica Scandinavica, 22, pp. 1363-1364
  • Singh, Whistler, Tokuzen, Nakahara, (1974) Carbohydr. Res., 37, pp. 245-247
  • Trevelyan, Procter, Harrison, (1950) Nature, 166, pp. 444-445
  • Wilson, (1959) Anal. Chem., 31, pp. 1199-1201
  • Hough, Jones, Wadman, 345. Quantitative analysis of mixtures of sugars by the method of partition chromatography. Part V. Improved methods for the separation and detection of the sugars and their methylated derivatives on the paper chromatogram (1950) Journal of the Chemical Society (Resumed), pp. 1702-1706
  • Sweeley, Bentley, Makita, Wells, (1963) Journal of the American Chemical Society, 85, pp. 2497-2507
  • MacFadyen, (1945) J. Biol. Chem., 158, pp. 107-133
  • Fleury, Lange, (1933) J. Pharm. Chim., 17, pp. 107-113
  • Sandford, Conrad, (1966) Biochemistry, 5, pp. 1508-1517

Citas:

---------- APA ----------
Fernandez Cirelli, A. & de Lederkremer, R.M. (1976) . A gel-forming (1→3)-β-D-glucan isolated from cyttaria harioti fischer. Carbohydrate Research, 48(2), 217-223.
http://dx.doi.org/10.1016/S0008-6215(00)83217-6
---------- CHICAGO ----------
Fernandez Cirelli, A., de Lederkremer, R.M. "A gel-forming (1→3)-β-D-glucan isolated from cyttaria harioti fischer" . Carbohydrate Research 48, no. 2 (1976) : 217-223.
http://dx.doi.org/10.1016/S0008-6215(00)83217-6
---------- MLA ----------
Fernandez Cirelli, A., de Lederkremer, R.M. "A gel-forming (1→3)-β-D-glucan isolated from cyttaria harioti fischer" . Carbohydrate Research, vol. 48, no. 2, 1976, pp. 217-223.
http://dx.doi.org/10.1016/S0008-6215(00)83217-6
---------- VANCOUVER ----------
Fernandez Cirelli, A., de Lederkremer, R.M. A gel-forming (1→3)-β-D-glucan isolated from cyttaria harioti fischer. Carbohydr. Res. 1976;48(2):217-223.
http://dx.doi.org/10.1016/S0008-6215(00)83217-6