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Abstract:

Matrix-assisted ultraviolet laser desorption/ionization time-of-flight mass spectrometry (UV-MALDI-TOF-MS) has shown to be a very useful technique for the study of the non-volatile and thermally non-stable N-acylated glycopyranosyl- and glycofuranosyl-amines. Of the several matrices tested, 2,5-dihydroxybenzoic acid (DHB) was the most effective giving good spectra in the positive-ion mode. In the linear and reflectron modes, the [M+Na]+ ions appeared with high intensity. Their fragmentation patterns were investigated by post-source decay (PSD) UV-MALDI-TOF-MS showing mainly cross-ring cleavages. In addition, N,O-acylated glycopyranosyl- and glycofuranosyl-amines were also analyzed by this technique. PSD UV-MALDI-TOF-MS gave significant signals for several primary fragment ions, which were proposed but not detected, or observed with very low abundance, in electron ionization mass spectrometry (EI-MS) experiments. © 2007 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines
Autor:Sato, Y.; Fukuyama, Y.; Nonami, H.; Erra-Balsells, R.; Stortz, C.A.; Cerezo, A.S.; Matulewicz, M.C.
Filiación:The United Graduate School of Agricultural Sciences, Ehime University, 3-5-7 Tarumi, Matsuyama, 790-8566, Japan
Plant Biophysics/Biochemistry Research Laboratory, Faculty of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama, 790-8566, Japan
CIHIDECAR-CONICET, Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Pabellon 2 - Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:N,O-Acylated glycosylamines; N-Acylated glycosylamines; PSD UV-MALDI-TOF-MS; UV-MALDI-TOF-MS; Fragment ions; N,O-Acylated glycosylamines; N-Acylated glycosylamines; Amines; Ionization; Mass spectrometers; Mass spectrometry; aminoglycoside derivative; gentisic acid; monosaccharide; n acylated glycosylamine; n o acylated glycosylamine; unclassified drug; article; carbohydrate analysis; electron ionization mass spectrometry; fragmentation reaction; mass fragmentography; matrix assisted ultraviolet laser desorption ionization time of flight mass spectrometry; post source decay; priority journal; time of flight mass spectrometry; Acetylation; Amines; Calibration; Chemistry, Organic; Gentisates; Models, Chemical; Nitrogen; Oligosaccharides; Oxygen; Solvents; Spectrometry, Mass, Electrospray Ionization; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Spectrophotometry, Ultraviolet; Ultraviolet Rays
Año:2007
Volumen:342
Número:17
Página de inicio:2567
Página de fin:2574
DOI: http://dx.doi.org/10.1016/j.carres.2007.08.002
Título revista:Carbohydrate Research
Título revista abreviado:Carbohydr. Res.
ISSN:00086215
CODEN:CRBRA
CAS:gentisic acid, 490-79-9; 2,5-dihydroxybenzoic acid, 490-79-9; Amines; Gentisates; Nitrogen, 7727-37-9; Oligosaccharides; Oxygen, 7782-44-7; Solvents
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v342_n17_p2567_Sato

Referencias:

  • Mock, K.K., Davey, M., Cottrell, J.S., (1991) Biochem. Biophys. Res. Commun., 177, pp. 644-651
  • Harvey, D.J., (2006) Mass Spectrom. Rev., 25, pp. 595-662
  • Harvey, D.J., (1999) Mass Spectrom. Rev., 18, pp. 349-451
  • Cristoni, S., Rossi Bernardi, L., (2003) Mass Spectrom. Rev., 22, pp. 369-406
  • Harvey, D.J., (2003) Int. J. Mass Spectrom., 226, pp. 1-35
  • Zaia, Z., (2004) Mass Spectrom. Rev., 23, pp. 161-227
  • Cheng, H.L., Her, G.R., (2002) J. Am. Soc. Mass Spectrom., 13, pp. 1322-1330
  • Stortz, C.A., Matulewicz, M.C., Cerezo, A.S., (1983) Carbohydr. Res., 117, pp. 39-53
  • Stortz, C.A., Matulewicz, M.C., Cerezo, A.S., (1983) Carbohydr. Res., 122, pp. 49-57
  • Nonami, H., Fukui, S., Erra-Balsells, R., (1997) J. Mass Spectrom., 32, pp. 287-296
  • Nonami, H., Tanaka, K., Fukuyama, Y., Erra-Balsells, R., (1998) Rapid Commun. Mass Spectrom., 12, pp. 285-296
  • Nonami, H., Orcoyen, M., Fukuyama, Y., Biondic, M.C., Erra-Balsells, R., (1998) An. Asoc. Quim. Argent., 85, pp. 81-89
  • Nonami, H., Wu, F., Thummel, R.P., Fukuyama, Y., Yamaoka, H., Erra-Balsells, R., (2001) Rapid Commun. Mass Spectrom., 15, pp. 2354-2373
  • Erra-Balsells, R., Kolender, A.A., Matulewicz, M.C., Nonami, H., Cerezo, A.S., (2000) Carbohydr. Res., 329, pp. 157-167
  • Fukuyama, Y., Kolender, A.A., Nishioka, M., Matulewicz, M.C., Erra-Balsells, R., Nonami, H., Cerezo, A.S., (2005) Rapid Commun. Mass Spectrom., 19, pp. 349-358
  • Hofmeister, G.E., Zhou, Z., Leary, J.A., (1991) J. Am. Chem. Soc., 113, pp. 5964-5970
  • Domon, B., Costello, C.E., (1988) Glycoconjugate J., 5, pp. 397-409
  • Wyatt, M.F., Stein, B.K., Brenton, A.G., (2006) J. Am. Soc. Mass Spectrom., 17, pp. 672-675
  • Cancilla, M.T., Penn, S.G., Carroll, J.A., Lebrilla, C.B., (1996) J. Am. Chem. Soc., 118, pp. 6736-6745

Citas:

---------- APA ----------
Sato, Y., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Stortz, C.A., Cerezo, A.S. & Matulewicz, M.C. (2007) . Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines. Carbohydrate Research, 342(17), 2567-2574.
http://dx.doi.org/10.1016/j.carres.2007.08.002
---------- CHICAGO ----------
Sato, Y., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Stortz, C.A., Cerezo, A.S., et al. "Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines" . Carbohydrate Research 342, no. 17 (2007) : 2567-2574.
http://dx.doi.org/10.1016/j.carres.2007.08.002
---------- MLA ----------
Sato, Y., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Stortz, C.A., Cerezo, A.S., et al. "Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines" . Carbohydrate Research, vol. 342, no. 17, 2007, pp. 2567-2574.
http://dx.doi.org/10.1016/j.carres.2007.08.002
---------- VANCOUVER ----------
Sato, Y., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Stortz, C.A., Cerezo, A.S., et al. Matrix-assisted ultraviolet laser desorption/ionization time-of-flight (UV-MALDI-TOF) mass spectra of N-acylated and N,O-acylated glycosylamines. Carbohydr. Res. 2007;342(17):2567-2574.
http://dx.doi.org/10.1016/j.carres.2007.08.002