Artículo
Fascio, M.L.; Alvarez-Larena, A.; D'Accorso, N.B. "Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles" (2002) Carbohydrate Research. 337(24):2419-2425
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Abstract:
Three isoxazoline tetracycles were obtained enantiomerically pure by intramolecular 1,3-dipolar cycloaddition. The characterization of the new compounds was performed by high-resolution 1H and 13C NMR spectroscopy. The relative configuration of the new chiral centers was determined by NOESY experiments and confirmed by single-crystal X-ray structural analysis. © 2002 Elsevier Science Ltd. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles |
| Autor: | Fascio, M.L.; Alvarez-Larena, A.; D'Accorso, N.B. |
| Filiación: | CIHIDECAR, Departamento de Quimica Organica, Universidad de Buenos Aires, C.P. 1428, Buenos Aires, Argentina Unitat de Cristallografia, Universitat Autonoma de Barcelona, 08193 Bellaterra, Barcelona, Spain |
| Palabras clave: | Intramolecular 1,3-dipolar cycloaddition; Isoxazolines; Stereocontrol, NMR spectroscopy; X-Ray crystallography; Addition reactions; Nuclear magnetic resonance spectroscopy; Stereochemistry; Synthesis (chemical); X ray diffraction analysis; Chiral centers; Carbohydrates; isoxazoline derivative; fused heterocyclic rings; isoxazole derivative; article; carbon nuclear magnetic resonance; crystal structure; cycloaddition; drug synthesis; nuclear Overhauser effect; priority journal; proton nuclear magnetic resonance; X ray diffraction; chemistry; nuclear magnetic resonance; stereoisomerism; synthesis; X ray crystallography; Crystallography, X-Ray; Heterocyclic Compounds with 4 or More Rings; Isoxazoles; Nuclear Magnetic Resonance, Biomolecular; Stereoisomerism |
| Año: | 2002 |
| Volumen: | 337 |
| Número: | 24 |
| Página de inicio: | 2419 |
| Página de fin: | 2425 |
| DOI: | http://dx.doi.org/10.1016/S0008-6215(02)00258-6 |
| Título revista: | Carbohydrate Research |
| Título revista abreviado: | Carbohydr. Res. |
| ISSN: | 00086215 |
| CODEN: | CRBRA |
| CAS: | Heterocyclic Compounds with 4 or More Rings; Isoxazoles |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v337_n24_p2419_Fascio |
Referencias:
- Padwa, A., (1984) 1,3-Dipolar Cycloaddition Chemistry, 1. , New York: John Wiley & Sons. and references cited therein
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- Sheldrick, G.M., (1985) Crystallographic Computing 3, pp. 175-189. , G.M. Sheldrick, C. Kruger, & R. Goddard. Oxford: Oxford University Press
- Sheldrick, G.M., (1997) SHELX97. Program for Crystal Structure Analysis (Release 97-2), , University of Göttingen, Germany
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Citas:
---------- APA ----------
Fascio, M.L., Alvarez-Larena, A. & D'Accorso, N.B. (2002) . Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles. Carbohydrate Research, 337(24), 2419-2425.http://dx.doi.org/10.1016/S0008-6215(02)00258-6
---------- CHICAGO ----------
Fascio, M.L., Alvarez-Larena, A., D'Accorso, N.B. "Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles" . Carbohydrate Research 337, no. 24 (2002) : 2419-2425.http://dx.doi.org/10.1016/S0008-6215(02)00258-6
---------- MLA ----------
Fascio, M.L., Alvarez-Larena, A., D'Accorso, N.B. "Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles" . Carbohydrate Research, vol. 337, no. 24, 2002, pp. 2419-2425.http://dx.doi.org/10.1016/S0008-6215(02)00258-6
---------- VANCOUVER ----------
Fascio, M.L., Alvarez-Larena, A., D'Accorso, N.B. Synthesis, high-resolution NMR spectroscopic analysis, and single-crystal X-ray diffraction of isoxazoline tetracycles. Carbohydr. Res. 2002;337(24):2419-2425.http://dx.doi.org/10.1016/S0008-6215(02)00258-6
