Artículo
Martins Alho, M.A.; D'Accorso, N.B. "Behavior of free sugar thiosemicarbazones toward heterocyclization reactions" (2000) Carbohydrate Research. 328(4):481-488
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Abstract:
The heterocyclization reaction on thiosemicarbazones having the D-galacto, D-gluco and D-manno configuration was studied. We applied two different acetylating conditions, and the reaction products obtained were identified, spectroscopically characterized, and conformationally analyzed. Using experimental data, we discuss a possible mechanistic pathway for heterocyclization and evaluate the influence of several factors, including starting material configuration, pH of reaction medium, and reaction time. (C) 2000 Elsevier Science Ltd.
Registro:
| Documento: | Artículo |
| Título: | Behavior of free sugar thiosemicarbazones toward heterocyclization reactions |
| Autor: | Martins Alho, M.A.; D'Accorso, N.B. |
| Filiación: | CIHIDECAR (CONICET)-Departamento De Química Orgánica, Facultad De Ciencias Exactas Y Naturales, Universidad De Buenos Aires, CP 1428, Buenos Aires, Argentina |
| Palabras clave: | Acetylation; Heterocyclization; pH influence; Sugar thiadiazolines; Sugar thiosemicarbazones; carbohydrate derivative; thiosemicarbazone derivative; acetylation; article; cyclization; pH; priority journal; reaction analysis; reaction time; structure activity relation; structure analysis; Acetylation; Antitubercular Agents; Carbon Isotopes; Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Molecular Conformation; Protons; Stereoisomerism; Support, Non-U.S. Gov't; Thiosemicarbazones |
| Año: | 2000 |
| Volumen: | 328 |
| Número: | 4 |
| Página de inicio: | 481 |
| Página de fin: | 488 |
| DOI: | http://dx.doi.org/10.1016/S0008-6215(00)00127-0 |
| Título revista: | Carbohydrate Research |
| Título revista abreviado: | Carbohydr. Res. |
| ISSN: | 00086215 |
| CODEN: | CRBRA |
| CAS: | Antitubercular Agents; Carbon Isotopes; Heterocyclic Compounds; Protons; Thiosemicarbazones |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v328_n4_p481_MartinsAlho |
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Citas:
---------- APA ----------
Martins Alho, M.A. & D'Accorso, N.B. (2000) . Behavior of free sugar thiosemicarbazones toward heterocyclization reactions. Carbohydrate Research, 328(4), 481-488.http://dx.doi.org/10.1016/S0008-6215(00)00127-0
---------- CHICAGO ----------
Martins Alho, M.A., D'Accorso, N.B. "Behavior of free sugar thiosemicarbazones toward heterocyclization reactions" . Carbohydrate Research 328, no. 4 (2000) : 481-488.http://dx.doi.org/10.1016/S0008-6215(00)00127-0
---------- MLA ----------
Martins Alho, M.A., D'Accorso, N.B. "Behavior of free sugar thiosemicarbazones toward heterocyclization reactions" . Carbohydrate Research, vol. 328, no. 4, 2000, pp. 481-488.http://dx.doi.org/10.1016/S0008-6215(00)00127-0
---------- VANCOUVER ----------
Martins Alho, M.A., D'Accorso, N.B. Behavior of free sugar thiosemicarbazones toward heterocyclization reactions. Carbohydr. Res. 2000;328(4):481-488.http://dx.doi.org/10.1016/S0008-6215(00)00127-0
