The stereospecific synthesis of 6-deoxy-4-O-methyl-d-galactose has been accomplished by using somewhat different intermediates in two related ways. The synthetic sugar is shown to be identical with d-curacose, a constituent of the antibiotic curamycin. Some of the known compounds used in the syntheses have been prepared by improved methods. © 1966.
Documento: | Artículo |
Título: | Synthesis of 6-deoxy-4-O-methyl-d-galactose (d-curacose) |
Autor: | Gros, E.G. |
Filiación: | Departamento de Quimica Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Perú, 222 Buenos Aires, Argentina |
Año: | 1966 |
Volumen: | 2 |
Número: | 1 |
Página de inicio: | 56 |
Página de fin: | 62 |
DOI: | http://dx.doi.org/10.1016/S0008-6215(00)81777-2 |
Título revista: | Carbohydrate Research |
Título revista abreviado: | Carbohydr. Res. |
ISSN: | 00086215 |
CODEN: | CRBRA |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v2_n1_p56_Gros |