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Abstract:

The main water-soluble polysaccharide from Chaetangium fastigiatum, a red seaweed of the order Nemalionales, is a xylan which appears from methylation analysis to contain (1 → 4)- and (1 → 3)-linked β-d-xylopyranose residues in the approximate ratio 3:1. There is evidence that this polysaccharide is branched to a small degree, is polydisperse, and has a random-coil conformation in aqueous solution. © 1971.

Registro:

Documento: Artículo
Título:A xylan from the red seaweed chaetangium fastigiatum
Autor:Cerezo, A.S.; Lezerovich, A.; Labriola, R.; Rees, D.A.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina
Chemistry Department, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom
Año:1971
Volumen:19
Número:3
Página de inicio:289
Página de fin:296
DOI: http://dx.doi.org/10.1016/S0008-6215(00)86159-5
Título revista:Carbohydrate Research
Título revista abreviado:Carbohydr. Res.
ISSN:00086215
CODEN:CRBRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v19_n3_p289_Cerezo

Referencias:

  • Rees, (1969) Advan. Carbohyd. Chem. Biochem., 24, p. 267
  • Anderson, Dolan, Rees, (1965) Nature, 205, p. 1060
  • Rees, Conformational analysis of polysaccharides. Part II. Alternating copolymers of the agar?carrageenan?chondroitin type by model building in the computer with calculation of helical parameters (1969) Journal of the Chemical Society B: Physical Organic, p. 217
  • Barry, Dillon, (1940) Nature, 146, p. 620
  • Percival, Chanda, (1960) Nature, 166, p. 787
  • Björndal, Eriksson, Garegg, Lindberg, Swan, Studies on the Xylan from the Red Seaweed Rhodymenia palmata. (1965) Acta Chemica Scandinavica, 19, p. 2309
  • Timell, (1964) Advan. Carbohyd. Chem., 19, p. 247
  • Mackie, Percival, 227. The constitution of xylan from the green seaweed caulerpa filiformis (1959) Journal of the Chemical Society (Resumed), p. 1151
  • Turvey, Williams, (1970) Phytochemistry, 9, p. 2383
  • Rees, (1970) J. Chem. Soc., p. 877
  • Rees, Scott, Williamson, (1970) Nature, 227, p. 390
  • Rees, Scott, Polysaccharide conformation. Part VI. Computer model-building for linear and branched pyranoglycans. Correlations with biological function. Preliminary assessment of inter-residue forces in aqueous solution. Further interpretation of optical rotation in terms of chain conformation (1971) Journal of the Chemical Society B: Physical Organic, p. 469
  • Micheel, (1956) Chemie der Zücker und Polysaccharide, , Geest und Portig K.-G., Leipzig
  • Marchessault, Timell, Four polymer-homologous series of oligosaccharides from a 4-O-methylglucuronoxylan (1963) Journal of Polymer Science Part C: Polymer Symposia, 2, p. 49. , Part C
  • Peat, Whelan, Lawley, 141. The structure of laminarin. Part I. The main polymeric linkage (1958) Journal of the Chemical Society (Resumed), p. 724
  • Manners, (1966) Ann. Rept. Progr. Chem. (Chem. Soc. London), 63, p. 590
  • A.A. Mckinnon and D.A. Rees, in preparation; Atkins, Parker, The helical structure of a β-D-1,3-xylan (1969) Journal of Polymer Science Part C: Polymer Symposia, 28, p. 69. , Part C
  • Zinbo, Timell, (1965) Svensk. Papperstid., 68, p. 647
  • Aspinall, Ferrier, (1957) Chem. Ind. (London), p. 1216
  • Unrau, Smith, (1957) Chem. Ind. (London), p. 330
  • Laidlaw, Percival, 101. Studies of seed mucilages. Part V. Examination of a polysaccharide extracted from the seeds of Plantago ovata forsk by hot water (1950) Journal of the Chemical Society (Resumed), p. 528
  • Barker, Hirst, Jones, 162. Methylation of ?-methylglucopyranoside and ??-methylxylopyranosides by thallous hydroxide and methyl iodide (1946) Journal of the Chemical Society (Resumed), p. 783
  • Robertson, Speedie, 177. New derivatives of xylose (1934) Journal of the Chemical Society (Resumed), p. 824
  • Ehrenthal, Montgomery, Smith, (1954) J. Amer. Chem. Soc., 76, p. 5509

Citas:

---------- APA ----------
Cerezo, A.S., Lezerovich, A., Labriola, R. & Rees, D.A. (1971) . A xylan from the red seaweed chaetangium fastigiatum. Carbohydrate Research, 19(3), 289-296.
http://dx.doi.org/10.1016/S0008-6215(00)86159-5
---------- CHICAGO ----------
Cerezo, A.S., Lezerovich, A., Labriola, R., Rees, D.A. "A xylan from the red seaweed chaetangium fastigiatum" . Carbohydrate Research 19, no. 3 (1971) : 289-296.
http://dx.doi.org/10.1016/S0008-6215(00)86159-5
---------- MLA ----------
Cerezo, A.S., Lezerovich, A., Labriola, R., Rees, D.A. "A xylan from the red seaweed chaetangium fastigiatum" . Carbohydrate Research, vol. 19, no. 3, 1971, pp. 289-296.
http://dx.doi.org/10.1016/S0008-6215(00)86159-5
---------- VANCOUVER ----------
Cerezo, A.S., Lezerovich, A., Labriola, R., Rees, D.A. A xylan from the red seaweed chaetangium fastigiatum. Carbohydr. Res. 1971;19(3):289-296.
http://dx.doi.org/10.1016/S0008-6215(00)86159-5