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Abstract:

We report the occurrence of dawsonite, NaAlCO3(OH)2, in volcaniclastic rocks of the Albian hydrocarbon reservoir Castillo Formation, Golfo San Jorge Basin, neighboring the Cañadón Asfalto Basin in Patagonia; this is the first known occurrence in Argentina. Dawsonite replaces crystals pseudomorphically, and can also be found as a cement together with other carbonates, which induced a loss in the porosity of the host rock. Previous studies reported incomplete chemical reactions which suggested that oligoclase and analcime were dawsonite precursors. In the present work we document either totally achieved or incomplete chemical reactions which led to the transformation of analcime into kaolinite and dawsonite into kaolinite, respectively. These facts allowed us to deduce that the transformation of analcime into kaolinite was via dawsonite, minerals formed during different stages under a telogenetic regime. Dawsonite values of δ13C PDB (-0.1 to 1.5‰) are consistent with a magmatic source of CO2 provided by hypabyssal, basic alkaline igneous rocks of regional importance starting in the Eocene. We identify both internal and external sources of Na and Al used in the formation of dawsonite.

Registro:

Documento: Artículo
Título:The role of telogenetic injection of magmatically derived CO2in the formation of dawsonite from the Castillo Formation, Chubut Group, Patagonia, Argentina
Autor:Comerio, M.; Morosi, M.E.; Tunik, M.; Paredes, J.M.; Zalba, P.E.
Filiación:Instituto de Estudios Andinos Don Pablo Groeber, Departamento de Ciencias Geológicas, FCEN-UBA, Buenos Aires, 1428, Argentina
Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC-CIC-CONICET), C. C. 49, Manuel B. Gonnet, B1897ZCA, Argentina
Instituto de Investigación en Paleobiología y Geología, Sede Alto Valle, Universidad Nacional de Río Negro, Isidro Lobo 516, General Roca, Argentina
Departamento de Geología, Universidad Nacional de la Patagonia San Juan Bosco, Ruta Provincial No 1 s/n, km.4 (9005), Comodoro Rivadavia, Argentina
School of Geosciences, Monash University, Melbourne, VIC, Australia
Palabras clave:Argentina; Dawsonite; Magmatic CO2; Patagonia; Telogenesis; Volcaniclastic rocks; Alkalinity; Chemical reactions; Igneous rocks; Kaolinite; Rocks; Zeolites; Argentina; Dawsonite; Magmatic CO2; Patagonia; Telogenesis; Volcaniclastics; Carbon dioxide; carbon dioxide; clastic rock; dawsonite; igneous rock; porosity; Argentina; Patagonia
Año:2014
Volumen:52
Número:3
Página de inicio:513
Página de fin:531
DOI: http://dx.doi.org/10.3749/canmin.52.3.513
Título revista:Canadian Mineralogist
Título revista abreviado:Can. Mineral.
ISSN:00084476
CODEN:CAMIA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00084476_v52_n3_p513_Comerio

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Citas:

---------- APA ----------
Comerio, M., Morosi, M.E., Tunik, M., Paredes, J.M. & Zalba, P.E. (2014) . The role of telogenetic injection of magmatically derived CO2in the formation of dawsonite from the Castillo Formation, Chubut Group, Patagonia, Argentina. Canadian Mineralogist, 52(3), 513-531.
http://dx.doi.org/10.3749/canmin.52.3.513
---------- CHICAGO ----------
Comerio, M., Morosi, M.E., Tunik, M., Paredes, J.M., Zalba, P.E. "The role of telogenetic injection of magmatically derived CO2in the formation of dawsonite from the Castillo Formation, Chubut Group, Patagonia, Argentina" . Canadian Mineralogist 52, no. 3 (2014) : 513-531.
http://dx.doi.org/10.3749/canmin.52.3.513
---------- MLA ----------
Comerio, M., Morosi, M.E., Tunik, M., Paredes, J.M., Zalba, P.E. "The role of telogenetic injection of magmatically derived CO2in the formation of dawsonite from the Castillo Formation, Chubut Group, Patagonia, Argentina" . Canadian Mineralogist, vol. 52, no. 3, 2014, pp. 513-531.
http://dx.doi.org/10.3749/canmin.52.3.513
---------- VANCOUVER ----------
Comerio, M., Morosi, M.E., Tunik, M., Paredes, J.M., Zalba, P.E. The role of telogenetic injection of magmatically derived CO2in the formation of dawsonite from the Castillo Formation, Chubut Group, Patagonia, Argentina. Can. Mineral. 2014;52(3):513-531.
http://dx.doi.org/10.3749/canmin.52.3.513