X-ray single crystal analysis sheds further light on the structure of this new iminium salt. ATABNEP crystallizes in the monoclinic system, space group P21 and shows a very short value for the C-N distance in the iminium group, thus suggesting that the contribution of the carbonium ion form in this particular case is much lower than usual, a fact that can be considered a rationale for the reluctance of ATABNEP to undergo hydrolysis.
| Documento: | Artículo |
| Título: | Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| Autor: | Viturro, H.R.; Rivero, B.E.; Piro, O.E.; Caram, J.A.; Martins, M.E.; Marschoff, C.M. |
| Filiación: | Laboratorio de Cristalografia, Departamento de FIsica, Universidad Nacional de la Plata, CC. 67, La Plata, 1900, Argentina Instituto de Investigaciones FIsico Qulmicas Teóricas y Aplicadas, C.C. 16, Sue. 4, La Plata, 1900, Argentina Departamento de IngenierIa QuImica, Facultad de LngenierIa, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| Palabras clave: | Single crystals; Crystal and molecular structure; Iminium; Iminium salts; Monoclinic systems; Space Groups; X-ray single-crystal analysis; Crystal structure |
| Año: | 1987 |
| Volumen: | 65 |
| Número: | 9 |
| Página de inicio: | 2000 |
| Página de fin: | 2003 |
| DOI: | http://dx.doi.org/10.1139/v87-331 |
| Título revista: | Canadian Journal of Chemistry |
| Título revista abreviado: | Can. J. Chem. |
| ISSN: | 00084042 |
| CODEN: | CJCHA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00084042_v65_n9_p2000_Viturro |
