Artículo
Sileo, E.E.; Vega, D.; Baggio, R.; Garland, M.T.; Blesa, M.A. "Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate" (1999) Australian Journal of Chemistry. 52(3):205-212
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Abstract:
The crystal structures of Na2Cu(2,3-pydc)2.8H2O (1) and Cu(3,4-pydc).3.5H2O (2) (pydc = pyridinedicarboxylato) are presented. Compound (1) is monoclinic; space group (72/c, with a 21.274(1), b 6.114(1), c 17.136(1) Å, β 101.62(1)°, Z 4, Dc 1.776 g cm-3; compound (2) is also monoclinic, space group P21/c, with a 7.272(2), b 11.319(3), c 25.453(9) Å, β 90.58(1)°, Z 4, Dc 1.850 g cm-3. Their stereochemistries are analysed, and compared with other copper(n) pyridine-2,6-dicarboxylates. Ligand constraints are shown to determine the crystal structures and the magnetic properties. Thermal dependence of magnetic susceptibility data and t.g., d.t.g. and d.t.a. measurements are also presented.
Registro:
| Documento: | Artículo |
| Título: | Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate |
| Autor: | Sileo, E.E.; Vega, D.; Baggio, R.; Garland, M.T.; Blesa, M.A. |
| Filiación: | Depto. de Quim. Inorgánica, Inst. de Quim. Fis. de Los Mat., Pabellón II, Piso 3, 1428 Buenos Aires, Argentina Departamento de Física, Comn. Nac. de Ener. Atómica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Física, Fac. de Cie. Fis./Matematicas, Universidad de Chile, Avda Blanco Encalada 2008, Santiago, Chile Unidad de Actividad Química, Comn. Nac. de Ener. Atómica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina |
| Año: | 1999 |
| Volumen: | 52 |
| Número: | 3 |
| Página de inicio: | 205 |
| Página de fin: | 212 |
| DOI: | http://dx.doi.org/10.1071/C98120 |
| Título revista: | Australian Journal of Chemistry |
| Título revista abreviado: | Aust. J. Chem. |
| ISSN: | 00049425 |
| CODEN: | AJCHA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00049425_v52_n3_p205_Sileo |
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Citas:
---------- APA ----------
Sileo, E.E., Vega, D., Baggio, R., Garland, M.T. & Blesa, M.A. (1999) . Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate. Australian Journal of Chemistry, 52(3), 205-212.http://dx.doi.org/10.1071/C98120
---------- CHICAGO ----------
Sileo, E.E., Vega, D., Baggio, R., Garland, M.T., Blesa, M.A. "Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate" . Australian Journal of Chemistry 52, no. 3 (1999) : 205-212.http://dx.doi.org/10.1071/C98120
---------- MLA ----------
Sileo, E.E., Vega, D., Baggio, R., Garland, M.T., Blesa, M.A. "Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate" . Australian Journal of Chemistry, vol. 52, no. 3, 1999, pp. 205-212.http://dx.doi.org/10.1071/C98120
---------- VANCOUVER ----------
Sileo, E.E., Vega, D., Baggio, R., Garland, M.T., Blesa, M.A. Solid state coordination chemistry of pyridinedicarboxylic acid isomers. I copper(II) disodium bis(pyridine-2,3-dicarboxylate) octahydrate and copper(n) pyridine-3,4-dicarboxylate 3-5 hydrate. Aust. J. Chem. 1999;52(3):205-212.http://dx.doi.org/10.1071/C98120
