Artículo
Greizerstein, W.; Brieux, J.A. "The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group" (1962) Journal of the American Chemical Society. 84(6):1032-1036
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Abstract:
The amount of substitution of the chlorine atoms of 2, 4-dichloronitrobenzene-4-Cl36 by piperidine in benzene and methanol has been determined by a radiochemical method. The results have been compared with the reactions of o- and p-chloronitrobenzene with piperidine in the same solvents and in ethanol. It is concluded that while the change from benzene to methanol lowers the over-all rate of substitution, it enhances selectively the reactivity of the chlorine atom para to the nitro group. Reaction kinetics are tentatively explained and Arrhenius parameters presented. © 1962, American Chemical Society. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group |
| Autor: | Greizerstein, W.; Brieux, J.A. |
| Filiación: | Laboratorio de Quimica Organica, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Buenos Aires, Buenos Aires, Argentina |
| Año: | 1962 |
| Volumen: | 84 |
| Número: | 6 |
| Página de inicio: | 1032 |
| Página de fin: | 1036 |
| DOI: | http://dx.doi.org/10.1021/ja00865a032 |
| Título revista: | Journal of the American Chemical Society |
| Título revista abreviado: | J. Am. Chem. Soc. |
| ISSN: | 00027863 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v84_n6_p1032_Greizerstein |
Citas:
---------- APA ----------
Greizerstein, W. & Brieux, J.A. (1962) . The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group. Journal of the American Chemical Society, 84(6), 1032-1036.http://dx.doi.org/10.1021/ja00865a032
---------- CHICAGO ----------
Greizerstein, W., Brieux, J.A. "The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group" . Journal of the American Chemical Society 84, no. 6 (1962) : 1032-1036.http://dx.doi.org/10.1021/ja00865a032
---------- MLA ----------
Greizerstein, W., Brieux, J.A. "The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group" . Journal of the American Chemical Society, vol. 84, no. 6, 1962, pp. 1032-1036.http://dx.doi.org/10.1021/ja00865a032
---------- VANCOUVER ----------
Greizerstein, W., Brieux, J.A. The ortho: Para Ratio in the Activation of the Nucleophilic Aromatic Substitution by the Nitro Group. J. Am. Chem. Soc. 1962;84(6):1032-1036.http://dx.doi.org/10.1021/ja00865a032
