Artículo
Greizerstein, W.; Bonelli, R.A.; Brieux, J.A. "Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene" (1962) Journal of the American Chemical Society. 84(6):1026-1032
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Abstract:
The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation energies. © 1962, American Chemical Society. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
| Autor: | Greizerstein, W.; Bonelli, R.A.; Brieux, J.A. |
| Filiación: | Laboratorio de Quimica Organica, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Buenos Aires, Buenos Aires, Argentina |
| Año: | 1962 |
| Volumen: | 84 |
| Número: | 6 |
| Página de inicio: | 1026 |
| Página de fin: | 1032 |
| DOI: | http://dx.doi.org/10.1021/ja00865a031 |
| Título revista: | Journal of the American Chemical Society |
| Título revista abreviado: | J. Am. Chem. Soc. |
| ISSN: | 00027863 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v84_n6_p1026_Greizerstein |
Citas:
---------- APA ----------
Greizerstein, W., Bonelli, R.A. & Brieux, J.A. (1962) . Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene. Journal of the American Chemical Society, 84(6), 1026-1032.http://dx.doi.org/10.1021/ja00865a031
---------- CHICAGO ----------
Greizerstein, W., Bonelli, R.A., Brieux, J.A. "Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene" . Journal of the American Chemical Society 84, no. 6 (1962) : 1026-1032.http://dx.doi.org/10.1021/ja00865a031
---------- MLA ----------
Greizerstein, W., Bonelli, R.A., Brieux, J.A. "Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene" . Journal of the American Chemical Society, vol. 84, no. 6, 1962, pp. 1026-1032.http://dx.doi.org/10.1021/ja00865a031
---------- VANCOUVER ----------
Greizerstein, W., Bonelli, R.A., Brieux, J.A. Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene. J. Am. Chem. Soc. 1962;84(6):1026-1032.http://dx.doi.org/10.1021/ja00865a031
